• Bulletin of the Korean Chemical Society
• /
• v.31 no.3
• /
• pp.624-629
• /
• 2010

The synthesis and evaluation of a novel calix[4]arene-based fluorescent chemosensor 1 for the detection of I. is described. The fluorescent changes observed upon addition of various anions show that 1 is selective for I. over other anions. Addition of I. results in ratiometric measurements with 1 : 1 complex ratio.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.12
• /
• pp.3611-3616
• /
• 2010

Five new 4- or 8-substituted-7-hydroxycoumarin derivatives (1-5) were synthesized as fluorescent sensors for metal ions. Fluorescent changes and selectivity for metal ions were compared based on the introduction of different ligands and/or testing with different substitution positions of 7-hydroxycoumarin in aqueous solution. Especially, probes 2, 3 and 5 displayed large fluorescence enhancements with $Zn^{2+}$ and $Cd^{2+}$. Probes 2 and 3 showed moderate selectivity for $Zn^{2+}$ over $Cd^{2+}$. On the other hand, probe 4 showed large fluorescence quenching effects upon the addition of $Ag^+$ and $Hg^{2+}$.

• Journal of Sensor Science and Technology
• /
• v.33 no.2
• /
• pp.70-77
• /
• 2024

In this study, a fluorescent ethanol sensor is developed to determine the ethanol concentration in the liquid phase. The sensor is developed using a complex of resazurin (RA)/resorufin (RO) and a hydrotalcite (HT) catalyst in a sol-gel matrix of methyltrimethoxysilane (MTMS) to produce a fluorescent ethanol-sensing membrane (RA/RO^*HT membrane). The operation mechanism of the RA/RO^*HT membrane is based on (i) the oxidation of ethanol to acetaldehyde and (ii) the reduction of RA to RO, through electron flows followed by EtOH ↔ HT ↔ RA/RO ↔ EtOH interactions. These possible redox reactions can lead to an increased fluorescence intensity of the RA/RO^*HT membrane as the ethanol concentration increases. The RA/RO^*HT membrane shows a linear detection range of 1-20 vol.% EtOH with limit of detection (LOD) of 0.178%. Additionally, the RA/RO^*HT membrane has high sensitivity and accuracy for determining the alcohol content in several Korean alcoholic beverages.

• The Journal of the Korea Contents Association
• /
• v.13 no.12
• /
• pp.19-26
• /
• 2013

In this paper, we present a novel illumination system for parking lots constructed underground. We design and implement this system using microwave sensors and dimming control of LED fluorescent lamps so that we can obtain lighting efficiency of the illumination scheme. We construct an effective illumination system in the aspects of performance and cost, resulting in energy-saving and electricity reduction. Recently conventional energy-saving method applied to old underground parking lots mainly relies upon turning off the half of total number of lamps installed in the parking lot. Sometimes there are some lots that have infrared sensor to be used to turn on/off the fluorescent lamps to realize these operations smoothing. The other schemes utilize timer to control lighting time of the fluorescent lamps. These conventional schemes are forcing to turn off a part of lamps installed so that we cannot apply them in a systematic way. Moreover they will be most inefficient when we leave them alone to be continuous consumers. The lighting control system proposed in this paper can recognize objects through microwave sensors and inform the appropriate lighting time, furthermore we can adjust brightness of LED lamps following the surroundings using dimming control scheme so that we can epochally improve the illumination system for underground parking lots. According to our sophisticated test experiments, we can maximally obtain 81.9% of energy-saving effectiveness using the system proposed in this paper.

• Journal of Microbiology and Biotechnology
• /
• v.26 no.3
• /
• pp.530-539
• /
• 2016

Bacterial light-oxygen-voltage-sensing photoreceptor-derived flavin mononucleotide (FMN)-based fluorescent proteins act as a promising distinct class of fluorescent proteins utilized for various biomedical and biotechnological applications. The key property of its independency towards oxygen for its chromophore maturation has greatly helped this protein to outperform the other fluorescent proteins such as GFP and DsRed for anaerobic applications. Here, we describe the feasibility of FMN-containing fluorescent protein FbFP as a metal-sensing probe by measuring the fluorescence emission changes of a protein with respect to the concentration of metal ions. In the present study, we demonstrated the mercury-sensing ability of FbFP protein and the possible amino acids responsible for metal binding. A ratiometric approach was employed here in order to exploit the fluorescence changes observed at two different emission maxima with respect to Hg²⁺ at micromolar concentration. The engineered variant FbFP_C56I showed high sensitivity towards Hg²⁺ and followed a good linear relationship from 0.1 to 3 μM of Hg²⁺. Thus, further engineering with a rational approach would enable the FbFP to be developed as a novel and highly selective and sensitive biosensor for other toxic heavy metal ions as well.

• Journal of Sensor Science and Technology
• /
• v.7 no.6
• /
• pp.409-417
• /
• 1998

Originally, the reference white of the NTSC system used to be CIE illuminant C of 6774K. However, that of color television receiver has been adjusted to 9300K as a result of consumer preference for a very bluish white for monochrome television. Recent studies have revealed that the preferred color temperature of display white should be 3000K or 4000K higher than that of surround illuminant. Therefore it is required to classify ambient lighting source. In this paper, a efficient method that can distinguish the ambient incandescent lamp from fluorescent lamp under television viewing condition is developed using only two color sensors, yellow and cyan. Experimental results show that the proposed method is very useful for the discrimination of ambient lighting source, fluorescent of 6000K and incandescent lamp of 3000K. The system was also tested for mixture of these light sources.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.11
• /
• pp.3625-3628
• /
• 2012

Fluorescent organic molecules that respond to changes in the $Fe^{2+}$ concentration with selectivity to other abundant di-valent metal ions will offer the ability to understand the dynamic fluctuations of the $Fe^{2+}$ ion in interesting media. The use of 6-Br-ppmbi, derived from 2-pyridin-2-yl-benzimidazole, for metal ion-selective fluorescence recognition was investigated. Screening of the main group and transition metal ions showed exclusive selectivity for $Fe^{2+}$ ions even in the presence of competing metal ions. In addition, the requirement for low concentrations of probe molecules to detect certain amounts of $Fe^{2+}$ ions make this sensor unique compared to previously reported $Fe^{2+}$ ion sensors.

• Textile Coloration and Finishing
• /
• v.26 no.3
• /
• pp.272-276
• /
• 2014

The functional materials have been developed as a promising research topic toward the end uses for organic materials and applications. In this study, fluorescein based dye was synthesized by three step reaction. We have designed and synthesized the colorimetric dye through the reactions of fluorescein and methoxy group and ethylene diamine and squaric acid. The structure of the non-fluorescent spirolactam was elucidated by $^1H$-NMR, LC-Mass and FT-IR analyzes. Further studies are in progress to understand the effects of various substituent during the recognition process and to develop fluorescein based sensors for cations or anions.

• Journal of Integrative Natural Science
• /
• v.9 no.2
• /
• pp.81-85
• /
• 2016

Detection of DMNB by chemo sensors has been proved difficult because of their high lying LUMO level. Recently reported 4 different types of sensory materials for detection of DMNB were discussed. The focus of this review mainly lied on the sensitivity and feasibility for field use. Different strategies and approaches from different platforms for sensing DMNB is studied.

• Polymer Science and Technology
• /
• v.26 no.4
• /
• pp.282-289
• /
• 2015