• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.5
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• pp.254-259
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• 2012

The mechanical property enhancement was studied using fly ash produced from fluidized bed type boiler in power plant, which contains a lot of Ca component being used to carbonate for $CO_2$ fixation in the lightweight aggregates made of cement and some portion of fly ash as a cement substitution under the supercritical condition. Specimens having various fly ash substitution rates and curing periods were carbonated under the supercritical condition at $40^{\circ}C$. The weight change rate, carbonation rate by TG/DTA analysis, 1% Phenolphthalein test, specific gravity and mechanical compression strength test were performed to observe the mechanical property enhancement of the cemented materials after carbonation under the supercritical condition and to make sure those could be classified as lightweight aggregates having specific gravity under 2.0.

• Journal of the Korea Institute of Building Construction
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• v.20 no.1
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• pp.27-34
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• 2020

In the industry, due to the carbon dioxide gas produced during cement production is increasing, research on recycling by-products has been actively conducted. In the industrial by-products, the high calcium fly ash(HCFA) produced by the blast-furnace in the circulating fluidized bed combustion method has a high ratio of CaO and CaSO4. In view of this, the purpose of this is to use high calcium fly ash(HCFA) as a stimulant in blast furnace slag powder and use it as a cement substitute. As a result, it is judged that the substitution ratio of HCFA should be 15% or less. In addition, although durability and strength are relatively lower than of OPC, it is considered that it can be utilized as an environmentally building material.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.207-213
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• 2018

Nowadays, circulating fluidized bed combustor(CFBC) boilers system that can reduce environmental pollution particles are widely used in electric power plants. But the fly ash generated from CFBC boilers has lower $SiO_2$ and higher MgO and $SO_3$ contents and also has free CaO inducing expansion and abrupt initial setting of concrete. Therefore, revised KSL5405 for CFBC fly-ash as well as pulverized coal combustion(PCC) is introduced in the concrete field. In this study, the chemical properties and mechanical properties of blended cements with PCC and CFBC fly-ash produced in Korea are analyzed. The blended cement with only CFBC fly ash shows a lower length change than OPC but a higher flow change ratio. The compressive strength of blended cement paste with PCC and CFBC fly ash is slightly greater than that of cement paste with only PCC fly-ash. Based on the results, CFBC flyash blended cement products should be used with PCC flyash to ensure the material stability and material properties.

• Resources Recycling
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• v.27 no.3
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• pp.39-47
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• 2018

According to Vietnam government establishes additional coal-fired power plants to secure generation capacity, emission of ashes is accelerating and processing them is urgent issue. This study targeted utilize fly ashes that occurred in circulating fluidized bed combusion (CFBC) power plant to use ground solidification materials. CFBC fly ashes are used to make solidification with ground granulated blast furnace slag (GGBFS), gypsum and cement. Then produced specimens by mixing with soft ground soil to confirm mixing effect of fly ash in solidification. As a result it was possible to find mixture design that is satisfied 3 MPa compressive strength in age 28 days and reduce weight loss rate over 50% in acid immersion test than plain specimens that using only ordinary portland cement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.1
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• pp.49-57
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• 2013

Recently, recycling of industrial by-products and CO2 reduction have been important issues in the world. In this reason, applications and reuse of Fly ash as a binder for concrete, which is generated in thermoelectric power plant, have been one of the effective recycle methods. In order for Fly ash to be applied to concrete, Korean Standard(KS) has selected and managed quality such as $SiO_2$, fineness, specific gravity, ignition loss and activity index. However, there is a limits for activity index, whose test period required is at least 28 days or 91 days. Activity index is the critical indication standard to determine mechanical strength of concrete that contained Fly ash. To complement the disadvantage of test method, this research provided "API test method", which quickly measure Pozzolanic reaction of Fly ash can be considered as a alternative of activity index. Then, the adaptable API test method need to be investigated through comparative analysis with the test result of API, activity index and K-value. The test method can make evaluation of Fly ash quality faster and more accurate. As a result, most Fly ash produced in Korea has not been satisfied in the KS quality standard except water content and specific gravity, and especially fluidized bed boiler ash has its characteristics. Also, API, activity index and K-value have superior interrelationship. The interrelationship between API and activity index and K-value gets increased as the material age gets higher, so API test can be considered as very useful test method for Pozzolanic reaction evaluation of Fly ash.

• Journal of the Korean Society of Combustion
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• v.8 no.2
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• pp.34-40
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• 2003

Analyses for concentration, surface phenomena, and crystal structure were performed to identify the causes of clinker formation in three type of pulverized coal fired boilers. Some clinkers had partially molten surface and more CaO and $Fe_2O_3$ as compared with fly ash, and the major crystalline phases identified in the clinker were mullite and quartz. Clinkers were formed in high temperature zone of the boiler according to the identification of mullite by XRD. Free $SiO_2$ in sand combined with K, Na and Ca in limestone served as a fluxing agent to form clinkers in a circulating bed boiler.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.3
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• pp.147-151
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• 2012

Carbon dioxide ($CO_2$) could be stored in the form of Ca and Mg compounds including alkaline earth metal by carbonation. The possibility of $CO_2$ storage was tested by using desulfurized ash from fluidized bed type boiler as raw material. Autoclave was used for maintaining the reaction pressure and temperature for the carbonation. The analysis of weight change rate, XRD, and TG/DTA proved that more than 15 % of carbonation rate was obtained under 10 $kgf/cm^2$ and $120^{\circ}C$-10 min.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.152-160
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• 2013

The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

• Journal of the Korea Institute of Building Construction
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• v.22 no.6
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• pp.641-649
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• 2022

This study aims to completely develop a non sintered cement mortar using industrial by-products. To replace Portland cement, blast furnace slag, circulating fluidized bed fly ash, and pulverized coal fly ash were used, and natural aggregates were substituted with ferronickel slag. To understand the characteristics of the non sintered cement mortar to which ferronickel slag is applied, an experiment was conducted by classifying the particle size. Fluidity and workability were confirmed through the flow test, and bending and compressive strength tests were conducted at 3, 7, and 28 days of age. In addition, durability was identified through a chloride ion penetration test. Through the study, it is judged that the binder, which completely replaced cement and aggregate, has high potential of being used as a construction material. Notably, it was confirmed to be advantageous for strength and durability.

• Clean Technology
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• v.24 no.4
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• pp.323-331
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• 2018

The results of an experimental investigation on the co-firing characteristics and slagging behavior of dried and hydrothermal carbonization sewage sludge, sub-bituminous coal, and wood pellet in a fluidized bed were presented. Combustion tests were conducted in a lab-scale bubbling fluidized bed system at the uniform fuel-air equivalence ratio, air flow rate, and initial bed temperature to measure bed temperature distribution and combustion gas composition. 4 different fuel blending cases were prepared by mixing sewage sludge fuels with coal and wood pellet with the ratio of 50 : 50 by the heating value. $NO_x$ was mostly NO than $NO_2$ and measured in the range of 400 to 600 ppm in all cases. $SO_2$ was considered to be affected mostly by the sulfur content of the sewage sludge fuels. The cases of hydrothermal carbonization sewage sludge mixture showed slightly less $SO_2$ emission but higher fuel-N conversion than the dried sewage sludge mixing cases. The result of fly ash composition analysis implied that the sewage sludge fuels would increase the possibility of slagging/fouling considering the contents of alkali species, such as Na, K, P. Between the two different sewage sludge fuels, dried sewage sludge fuel was expected to have the more severe impact on slagging/fouling behavior than hydrothermal carbonization sewage sludge fuel.