• Title/Summary/Keyword: Fluidized Material

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Carbonation of coal fly ash for construction materials (탄산화 건자재 제조를 위한 석탄 비산회의 탄산화)

  • Park, Jun-Young;Kim, Yoo-Taek;Kim, Hyun-Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.147-151
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    • 2012
  • Carbon dioxide ($CO_2$) could be stored in the form of Ca and Mg compounds including alkaline earth metal by carbonation. The possibility of $CO_2$ storage was tested by using desulfurized ash from fluidized bed type boiler as raw material. Autoclave was used for maintaining the reaction pressure and temperature for the carbonation. The analysis of weight change rate, XRD, and TG/DTA proved that more than 15 % of carbonation rate was obtained under 10 $kgf/cm^2$ and $120^{\circ}C$-10 min.

Properties of Ground Solidification Materials using Vietnam CFBC Fly Ash (베트남 CFBC 플라이애시를 사용한 지반고화재의 특성)

  • Kim, Keeseok;Lee, Jaewon;Lee, Dongwon;Yu, Jihyung;Hoang, Truong Xuan;Minh, Ha;Min, Kyongnam
    • Resources Recycling
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    • v.27 no.3
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    • pp.39-47
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    • 2018
  • According to Vietnam government establishes additional coal-fired power plants to secure generation capacity, emission of ashes is accelerating and processing them is urgent issue. This study targeted utilize fly ashes that occurred in circulating fluidized bed combusion (CFBC) power plant to use ground solidification materials. CFBC fly ashes are used to make solidification with ground granulated blast furnace slag (GGBFS), gypsum and cement. Then produced specimens by mixing with soft ground soil to confirm mixing effect of fly ash in solidification. As a result it was possible to find mixture design that is satisfied 3 MPa compressive strength in age 28 days and reduce weight loss rate over 50% in acid immersion test than plain specimens that using only ordinary portland cement.

A Model for Vertical Transport of Fine Sediment and Bed Erodibility in a Wave-Dominated Environment (파랑지배환경에서의 미세퇴적물 수직이동에 관한 모형)

  • Hwang, Kyu-Nam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.7 no.3
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    • pp.277-288
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    • 1995
  • Prediction of turbidity due to fine-grained bed material load under wave action is critical to any assessment of anthropogenic impart on the coastal or lacustrine environment Waves tend to loosen mud deposits and generate steep suspension concentration gradients, such that the sediment load near the bottom is typically orders of magnitude higher than that near the surface. In a physically realistic but simplified manner, a simple mass conservation principle has been used to simulate the evolution of fine sediment concentration profiles and corresponding erodible bed depths under progressive, nonbreaking wave action over mud deposits. Prior field observations support the simulated trends. which reveal the genesis of a near-bed. high concentration fluidized mud layer coupled with very low surficial sediment concentrations. It is concluded that estimation of the depth of bottom erosion requires an understanding of mud dynamics and competent in situ sediment concentration profiling. Measurement of sediment concentration at the surface alone, without regard to the near-bed zone, can lead to gross underestimation of the erodible bed depth.

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Properties of Cement Mortar According to Substitution Ratio of High Calcium Fly Ash Based on Blast Furnace Slag (고로슬래그 기반 고칼슘 플라이애시 치환비율에 따른 시멘트 모르타르의 특성)

  • Cho, Seong-Woo;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.27-34
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    • 2020
  • In the industry, due to the carbon dioxide gas produced during cement production is increasing, research on recycling by-products has been actively conducted. In the industrial by-products, the high calcium fly ash(HCFA) produced by the blast-furnace in the circulating fluidized bed combustion method has a high ratio of CaO and CaSO4. In view of this, the purpose of this is to use high calcium fly ash(HCFA) as a stimulant in blast furnace slag powder and use it as a cement substitute. As a result, it is judged that the substitution ratio of HCFA should be 15% or less. In addition, although durability and strength are relatively lower than of OPC, it is considered that it can be utilized as an environmentally building material.

Effects of Operating Variables on Separation Rate and Separation Efficiency in Ash Separator for Solid Fuel Chemical Looping Combustor (고체연료 매체순환연소기를 위한 회재분리기에서 분리속도 및 분리효율에 미치는 조업변수들의 영향)

  • RYU, HOJUNG;LEE, DONGHO;YOON, JOOYOUNG;JANG, MYOUNGSOO;BAE, DALHEE;PARK, JAEHYEON;BAEK, JEOMIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.2
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    • pp.211-219
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    • 2016
  • To develop an ash separator for the solid fuel chemical looping combustion system, effects of operating variables such as solid injection nozzle velocity, diameter of solid injection nozzle, gap between solid injection line and vent line, vent line inside diameter, and solid intake height on solid separation rate and solid separation efficiency were measured and discussed using heavy and coarse particle and light and fine particles mixture as bed material in an acrylic fluidized bed apparatus. The solid separation rate increased as the solid injection nozzle velocity and the diameter of solid injection nozzle increased. However, the solid separation rate decreased as the gap between solid injection line and vent line, the vent line inside diameter, and the solid intake height increased. The solid separation efficiency was in inverse proportion to the solid separation rate. In this study, we could get high solid separation rate up to 2.39 kg/hr with 91.6% of solid separation efficiency.

Penicillin Fermentation using a Carrier-supported Mycelial Growth (담체에 고정화된 균사체 증식을 이용한 페니실린의 발효)

  • Park, Sang K.;Kim, Jung H.;Park, Young H.
    • Microbiology and Biotechnology Letters
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    • v.13 no.3
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    • pp.273-278
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    • 1985
  • A carrier-supported mycelial growth of Penicillium chrysogenum was applied to penicillin fermentation system. Among various materials tested, celite was found to be most effective for both spore adsorption and bioparticle development. Hyphal growth through pore matrices of the material showed strong anchorages and provided highly stable biofilm growths. When 5-10% celite was employed, both cell growth and penicillin production were observed to increase significantly comparing to the dispersed filamentous growth. Specific productivity of penicillin, however. was found to be kept almost constant at a value of 1,900 unit/g cell/hr. A semicontinuous fermentation in a fluidized-bed reactor. using the tarrier-supported biofilm growth, was conducted successfully although free mycelia appeared in the late phase of the fermentation made the reactor operation difficult. Control of the size of bioparticles was considered as a major operating factor to maintain the reactor productivity at a desired level.

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REACTION STEPS OF A FORMATION OF THE BLACK LAYER BEIWEEN IRON NTIRIDE AND TiN COATING

  • Baek, W.S.;Kwon, S.C.;Lee, J.Y.;Rha, J.J.;Lee, S.R.;Kim, K.H.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.312-316
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    • 1999
  • The interfacial structure of duplex treated AISI 4140 consisting of iron nitride and TiN layer was characterized by optical microscope, SEM and XRD. A black layer was formed from the decomposition of iron nitride during Ti ion bombardment. The black layer was characterized as an a-Fe phase transformed from the iron nitride by XRD. In order to identify the formation mechanism of the black layer, a thermal analysis of iron nitride undertaken by DSC method. As an iron nitride was mostly consisted of ${\gamma}$'-Fe$_4$N and $\varepsilon$-$Fe_3$N phase after plasma nitriding, in this study, a ${\gamma}$'$-Fe_4$N and $\varepsilon$-$Fe_3$N powders were separately prepared by the different processing conditions of gas nitriding of iron powder in the fluidized bed. From the DSC thermal analysis, the phase transformation of ${\gamma}$'$-Fe_4$N, $\varepsilon$-$Fe_3$N was followed the path of transformation; $ \Upsilon{'}-Fe_4$Nlongrightarrow${\gamma}$-Felongrightarrowa-Fe and of $\varepsilon$-$Fe_3$Nlongrightarrow$\varepsilon$-$Fe_{2.5}$ /N+${\gamma}$'$-Fe_4$Nlongrightarrow${\gamma}$'-Fe$_4$Nlongrightarrow${\gamma}$longrightarrowFelongrightarrowalongrightarrowFe, respectively. It explains the reason why the $\varepsilon$ $-Fe_3$N phase disappeared in the first time and then ${\gamma}$'-Fe$_4$N in the formation of the black layer in the duplex coating.

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A Study on the Improvement of Potassium Based Sorbent for Flue Gas Carbon Dioxide(CO2) (배가스 이산화탄소(CO2)용 Potassium계 흡수제의 성능 향상 연구)

  • Wi, Young Ho;Ryu, Chong Kul;Choi, Dong Hyeok
    • Journal of Climate Change Research
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    • v.2 no.2
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    • pp.107-113
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    • 2011
  • In this research, we described the experimental results for the improvement of Potassium based sorbents. These sorbents have been actually used in the 0.5 MW $CO_2$ capture plant located in Hadong #3 Power Plant. Firstly, we had shaped two kinds of sorbents using a spray dryer. These sorbents applied magnetite & copper oxide as an additive. And the magnetite sorbent was evaluated more excellent relatively in the attrition index. Secondly, We had obtained TGA multicycle experimental results of the improved Potassium based sorbent which applied magnetite as an additive. Consequently, $CO_2$ sorption capacity had been sustained 5.5 wt% after 2nd cycle and attrition index was very excellent as 0.5%. Finally, we had investigated the characteristics of the sorbent following in properties of supporters. As a result, the sorption capacity of the KMO sorbent used base material as a supporter was appeared as 7.2 wt%.

Properties of Non Sintered Cement Mortar using Ferro Nickel Slag (페로니켈 슬래그를 사용한 비소성 시멘트 모르타르의 특성)

  • Youn, Min-Sik;Na, Hyeong-Won;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.641-649
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    • 2022
  • This study aims to completely develop a non sintered cement mortar using industrial by-products. To replace Portland cement, blast furnace slag, circulating fluidized bed fly ash, and pulverized coal fly ash were used, and natural aggregates were substituted with ferronickel slag. To understand the characteristics of the non sintered cement mortar to which ferronickel slag is applied, an experiment was conducted by classifying the particle size. Fluidity and workability were confirmed through the flow test, and bending and compressive strength tests were conducted at 3, 7, and 28 days of age. In addition, durability was identified through a chloride ion penetration test. Through the study, it is judged that the binder, which completely replaced cement and aggregate, has high potential of being used as a construction material. Notably, it was confirmed to be advantageous for strength and durability.

A Study on the Pozzolan Reactivity and Mechanical Characteristic of Blended Portland Cements using CFBC Fly Ash (순환유동층 플라이 애시를 사용한 혼합시멘트의 포졸란 반응성과 역학적 성질에 관한 연구)

  • Park, JongTak;Oh, Hongseob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.207-213
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    • 2018
  • Nowadays, circulating fluidized bed combustor(CFBC) boilers system that can reduce environmental pollution particles are widely used in electric power plants. But the fly ash generated from CFBC boilers has lower $SiO_2$ and higher MgO and $SO_3$ contents and also has free CaO inducing expansion and abrupt initial setting of concrete. Therefore, revised KSL5405 for CFBC fly-ash as well as pulverized coal combustion(PCC) is introduced in the concrete field. In this study, the chemical properties and mechanical properties of blended cements with PCC and CFBC fly-ash produced in Korea are analyzed. The blended cement with only CFBC fly ash shows a lower length change than OPC but a higher flow change ratio. The compressive strength of blended cement paste with PCC and CFBC fly ash is slightly greater than that of cement paste with only PCC fly-ash. Based on the results, CFBC flyash blended cement products should be used with PCC flyash to ensure the material stability and material properties.