• Title/Summary/Keyword: Fluidity Properties

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A Study on Early Age Properties of Alkali Activated Slag Mortar According to Water/Binder Ratio (물-결합재비에 따른 알칼리 활성 슬래그 모르타르의 초기 재령 특성에 관한 연구)

  • Oh, Sang-Hyuk;Kim, Dae-Wang;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.63-69
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    • 2012
  • Recently, the cement industries brought very severe environment problems such as resource depletion and global warming with massive carbon dioxide during its production. The number of cases using industrial by-products such as the ground granulated blast furnace slag (GGBFS) in concrete mixtures is increasing to resolve the environmental issue. GGBFS is mainly used in the range between 20 to 50% to replace cement, but nowadays lots of researches are carried out to develop the alkali-activated slag (AAS) concrete with no cement. In this study, the early age properties of alkali activated slag (AAS) mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The experimental variables were the water-binder ratios of 0.3, 0.4, and 0.5 and NaOH as the alkali activator of 4%, 8%, and 12% by the mass of GGBFS, and compressive strength, flow, setting time, and ultrasonic pulse velocity of AAS mortars were measured and analyzed. It is found from the test results that as the normal concrete the lower W/B, the higher compressive strength. However, superplasticizer has to be used for producing high strength AAS concrete because the workability of AAS mortar are significantly lowered.

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Fabrication and Characteristics of Resin-Type Neutron Shielding Materials for Spent Fuel Shipping Cask (사용후핵연료 수송용기에 사용될 수지계 중성자 차폐재 제조 및 특성)

  • Cho, Soo-Haeng;Do, Jae-Bum;Ro, Seung-Gy;Do, Chun-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.597-604
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    • 1996
  • Resin-type neutron shielding materials, KNS-115A, 115B and 115C have been fabricated to be used for spent fuel shipping cask. The base material is epoxy resin, and polypropylene, aluminium hydroxide and boron carbide are added. These shielding materials offer good fluidity at processing, which makes it possible to apply this resin shield to complicated geometric shapes such as shipping cask. Several measurements were made for the shielding materials to evaluate the shielding property, combustion characteristics, fire resistance, thermal and mechanical properties. The neutron shielding ability of the shielding materials is estimated to be better than that of foreign's shielding material, NS-4-FR, due to higher hydrogen atomic density. Other properties of the shielding materials are as follows: Onset temperatures; $267{\sim}270^{\circ}C$, thermal conductivities; $0.62{\sim}0.72W/m{\cdot}K$, combustion characteristics; <$800^{\circ}C$, ATB(average time of burning); <5sec, AEB(average extent of burning) ; <5mm, tensile strengths; $2.3{\sim}3.0kg/mm^2$, compressive strengths; $5.3{\sim}13.3kg/mm^2$, flexural strengths; $4.4{\sim}5.4kg/mm^2$.

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The Fundamental Properties of High Fluidity Mortar with Activated Ternary Blended Slag Cement (활성화된 삼성분계 고유동 모르타르의 기초특성)

  • Bae, Ju-Ryong;Kim, Tae-Wan;Kim, In-Tae;Kim, Hyoung-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.74-82
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    • 2017
  • This research presents the results of the strength and drying shrinkage properties to study the effect of ground granulated blast furnace slag(GGBFS), fly ash(FA) and calcium sulfoaluminate(CSA) for activated ternary blended slag cement. The activated ternary blended cement(ATBC) mortar were prepared having a constant water-cementitious materials ratios of 0.4. The GGBFS contents ratios of 100%, 80%, 70% and 60%, FA replacement ratios of 10%, 20%, 30% and 40%, CSA ratios of 0%, 10%, 20% and 30% were designed. The superplasticizer of polycarboxylate type were used. The activator was used of 10% sodium hydroxide(NaOH) + 10% sodium silicate($Na_2SiO_3$) by weight of binder. Test were conducted for mini slump, setting time, V-funnel, water absorption, compressive strength and drying shrinkage. According to the experimental results, the contents of superplasticizer, V-funnel and compressive strength increases with an increase in CSA contents for all mixtures. Moreover, the setting time, water absorption ratios and drying shrinkage ratio decrease with and increase in CSA. One of the major reason for the increase of strength and decrease of drying shrinkage is the accelerated reactivity of GGBFS with alkali activator and CSA. The CSA contents is the main parameter to explain the strength development and decreased drying shrinkage in the ATBC.

Analysis of Fatty Acid Compositions and Biodiesel Properties of Seeds of Woody Oil Plants in Korea (국내 목본 유지식물 종자의 지방산 조성 및 바이오디젤 특성 분석)

  • Kim, Kwang Soo;Lee, Yong Hwa;Jang, Young Seok;Choi, In Hu
    • Korean Journal of Plant Resources
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    • v.26 no.5
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    • pp.628-635
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    • 2013
  • In order to evaluate their potential as sources of biodiesel, oil content and fatty acid composition of seeds and fatty acid methyl ester (FAME) properties from seven woody oil plants in Korea were analysed. The oil content of seed of all woody plant species ranged from 15.1 (Ligustrum lucidum) to 70.3% (Camellia japonica) by dry weight. Fatty acid composition consisted mainly of oleic acid, linoleic acid, linolenic acid, palmitic acid and stearic acid, with oleic acid being the most abundant. The content of unsaturated fatty acids of all species was higher than saturated fatty acids. Oxidation stability of seed oils of all woody plants ranged from 2.25 to 8.62 hours/$110^{\circ}C$. Fatty acid methyl ester of Styrax japonica has been found to have the highest iodine value, indicating that unsaturated fatty acid content is higher than other seed oils. Cold filter plug point(CFPP) was varied over a wide range from $0^{\circ}C$ to $-13^{\circ}C$. The cold fluidity of FAME of Chionanthus retusa were excellent.

Properties of Cementless Loess Mortar Using Eco-Friendly Hardening Agent (친환경 무기질 고화재를 사용한 무시멘트 황토모르타르의 특성)

  • Jung, Yong-Wook;Kim, Sung-Hyun;Lee, Dong-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.355-365
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    • 2015
  • This study examined the fluidity and strength properties, water resistance, durability, and freeze-thaw of cementless loess mortar using an eco-friendly hardening agent. The experimental result indicates that 28 days compressive and flexural strength of the loess mortar was increased regardless of the weathered granite soil and loess mixture ratio as the replacement ratio of the hardening agent increases. The strengths were significantly increased until 14 days regardless of the hardening agent, while the effect on the strengths increasement was relatively low after 14 days. Thus, the strength development of loess mortar concrete was found to be faster than that of the normal concrete. In addition, when the hardening agent of 10% was used, the average flexural strength was 1.7MPa which is insufficient compared to the 28-day flexural strength of 4.5MPa for the paving concrete. However, the flexural strengths of the loess mortar concrete using the hardening agents of 20% and 30% were 4.0MPa and 5.3MPa, respectively. Thus, the hardening agent need to be at least 20% so that the loess mortar can be used for paving concrete. The experiment for water resistance shows that the repeated absorption and dry reduced mass regardless of the mixing ratio of the loess. The maximum length change also decreased with increasing the substitution rate loess mixture ratio and the hardening agent. The result of the freeze-thaw resistance test indicates that the relative dynamic modulus of elasticity at 300 cycle freeze-thaw with the hardening agents of 20% and 30% were 75% and 79%, relatively. Thus, the hardening agent of at least 20% is required to obtain the relative dynamic modulus of elasticity of 60% for the loess mortar.

Effect of Silica Fume Types on the Mechanical Properties of Ultra-High Performance Concrete (실리카퓸 종류가 초고성능 콘크리트의 공학적 특성에 미치는 영향)

  • Park, Chun-Jin;Koh, Kyung-Teak;Ahn, Gi-Hong;Han, Min-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.220-227
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    • 2015
  • Ultra high performance concrete (UHPC) uses large quantities of steel fiber, silica fume, filler and superplasticizer for a low water-to-binder ratio (W/B). Despite of exceptional mechanical performances, UHPC exhibits increased viscosity due to the adoption of silica fume and its fabrication cost is costlier than ordinary concrete because of the use of large quantities of expensive materials. Following, this study evaluates the mechanical properties of 180MPa-UHPC using zirconium silica fume (Zr) instead of silica fume with respect to the quantity and type of superplasticizer (SP) and the size of filler. The results reveal that the Zr-UHPC using W/B of 20%, 100% of Zr, amount of SP-L of 2 to 3% and $4{\mu}m$-filler with steel fiber in 1.5 vol.% can develop better fluidity than the traditional mix composition using silica fume and secure a compressive strength higher than 180 MPa. In addition, the proposed mix composition is shown to enable a reduction of the fabrication cost by 33% compared to traditional UHPC.

A Study on the Fundamental Properties of Ultra Rapid Hardening Mortar using Coal-Ash (잔골재 대체재로서 석탄회를 이용한 초속경 보수모르타르의 기초적 특성에 관한 연구)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.128-135
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.

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An Experimental Study on the Influence of High Quality Fly ash and Water-Binder Ratio on Properties of the Ternary System Concrete (3성분계 콘크리트의 특성에 미치는 고품질 플라이애쉬의 치환율 및 물-결합재비 영향에 관한 실험적 연구)

  • Lee, Seung-Min;Kim, Dong-Sool;Rho, Hyoung-Nam;Jung, Yong;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.877-880
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    • 2008
  • Recently the press and institute recognized fly ash as it had excellent performance. Its research and applications are on the rise largely as a substitute for cement. On the contrary, it is in a situation that the regulation of high quality fly ash remains at a low level. Accordingly, this study was to establish 8000 class of fineness of fly ash and three levels of substitute like 15%, 3 0%, and 45% in order to analyze the replacement ratio and effect of water-binder ratio for fly ash that affected the properties of ternary system concrete. As a result of experiment by planning water-binder ratio for two levels like 40% and 50%, it increased the fluidity in a fresh state, and it decreased the air content. This study has found out the setting acceleration and reduction of heat of hydration. As for the strength property in a set state, this study has shown the tendency of being equal or higher in age 28 days.

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Cryopreservation with Trehalose Reduced Sperm Chromatin Damage in Miniature Pig

  • Park, Cheol-Ho;Kim, Sung-Won;Hwang, You-Jin;Kim, Dae-Young
    • Journal of Embryo Transfer
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    • v.27 no.2
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    • pp.107-111
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    • 2012
  • Miniature pig sperm cryopreservation is continually researched in biotechnology for breed conservation and reproduction. It is important to control the temperature at each stage of cryopreservation and cryoprotectant. It is also necessary to find the optimal cryoprotectant concentration and chemical elements of the extender. Recently, many studies have used various cryoprotectant materials, such as dimethyl sulphoxide (DMSO), ethylene glycol (EG), antifreeze protein (AFP), amides, and glycerol. Glycerol is a commonly used cryoprotectant. However, glycerol has critical cytotoxic properties, including osmotic pressure and it can cause irreversible damage to live cells. Therefore, We focused on membrane fluidity modifications can reduce cell damage from freezing and thawing procedures and evaluated on the positive effects of trehalose to the viability, chromatin integrity, and motility of boar sperm. Miniature pig sperm was separated from semen by washing with modified- Modena B (mMB) extender. After centrifugation, the pellet was diluted with the prepared first extender. This experiment was designed to compare the effects that sperm cryopreservation using two different extenders has on sperm chromatin. The control group used the glycerol only and it was compared with the glycerol and glycerol plus trehalose extender. Sperm viability and motility were evaluated using WST1 assays and computer-assisted semen assays (CASA). Chromatin structure was examined using acridine orange staining. For the motility descriptors, trehalose caused a significant (p<0.01) increase in total motility ($57.80{\pm}4.60%$ in glycerol vs. $75.50{\pm}6.14%$ in glycerol + trehalose) and progressive ($51.20{\pm}5.45%$ in glycerol vs. $70.74{\pm}8.06%$ in glycerol + trehalose). A significant (p<0.05) increase in VAP ($42.70{\pm}5.73{\mu}m/s$ vs. $59.65{\pm}9.47{\mu}m/s$), VSL ($23.06{\pm}3.27{\mu}m/s$ vs. $34.60{\pm}6.58{\mu}m/s$), VCL ($75.36{\pm}11.36{\mu}m/s$ vs. $99.55{\pm}12.91{\mu}m/s$), STR ($54.4{\pm}2.19%$ vs. $58.0{\pm}1.63%$), and LIN ($32.2{\pm}2.05%$ vs. $36.0{\pm}2.45%$) were also detected, respectively. The sperm DNA fragmentation index was 48.8% to glycerol only and 30.6% to glycerol plus trehalose. Trehalose added group showed higher percentages of sperm motility, stability of chromatin structure than glycerol only. In this study, we suggest that trehalose is effective in reducing freezing damage to miniature pig sperm and can reduce chromatin damage during cryopreservation.

Physical and Mechanical Properties of Magnesium Oxide Matrix depending on Addition Ratio of Magnesium Chloride (염화마그네슘 첨가율에 따른 산화마그네슘 경화체의 물리 및 역학적 특성)

  • Kim, Heon-Tae;Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.4
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    • pp.308-313
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    • 2014
  • Recently, for longevity of resident building, the main trend is that the change of the inside space organization of resident building from wall construction to rhamen construction, which resulted in increase in use of lightweight composite panel. Thus, in this study, authors analyzed the engineering property of oxide of magnesium depending on the magnesium chloride addition ratio. The results of this research is expected to contribute on providing a fundamental material for the surface materials of lightweight composite panel. As the result of the experiment, as fluidity increased, air content decreased and initial set and final set as the magnesium chloride addition ratio increase. In the aspect of flexural strength and compressive strength, the test specimen showed the highest strength at 40% of the magnesium chloride addition ratio. At 20% of the magnesium chloride addition ratio, the test specimen showed the lowest water absorption rate. As the magnesium chloride addition ratio increases, the expansibility tends to increase as well in the aspect of shrinkage strain. After observing microstructure, we can see hydration products in the form of needle. It appeared high flexural strength because the hydration products have mineral fibrous tissue shape, which also contribute to the cause of the expansibility.