• Journal of the Korean Ceramic Society
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• v.55 no.2
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• pp.160-165
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• 2018

This paper investigates the reaction rate of $CO_2$ storing carbonation hybrid reaction by comparing the behavior of carbonation between $Ca(OH)_2$ and fly ash with that of CFBC (Circulating Fluidized Bed Combustion) containing plenty of Free-CaO. Because fly ash with CFBC contains a lot of unreacted CaO, it cannot be used as a raw material for concrete admixtures and its usages are limited. To reuse such material, we stabilized unreacted CaO by carbonation and investigated the carbonation rate. We used a pH meter and a thermometer to check the rate of the carbonization. Also, we set the contents of fly ash with CFBC, $Ca(OH)_2$, flow and fluid of $CO_2$, respectively, to 100 g, 50 g, 100 ~ 1000 cc/min and 400 g based on the content of Free-CaO. We used carbonated water instead of water, and added an alkaline activator to promote the carbonation rate. As a result, the addition of the alkaline activator and carbonated water promoted the rate of carbonation via a hybrid reaction.

• Journal of Korean Port Research
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• v.14 no.4
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• pp.451-461
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• 2000

The design and maintenance of navigation channel and water facilities of an harbor which is located at the mouth of river or at the estuary area are difficult due to the complexity of estuarial water and sediment circulation. Effects of deepening navigable waterways, of changing coastline configurations, or of discharging dredged material to the open sea are necessary to be investigated and predicted in terms of water quality and possible physical changes to the coastal environment. A borad analysis of the transport mechanism in the estuary area was made in terms of sediment property, falling velocity, concentration and flow characteristics. In order to simulate the transport processes, a two-dimensional finite element model is developed, which includes erosion, transport and deposition mechanism of suspended sediments. Galerkin’s weighted residual method is used to solve the transient convection-diffusion equation. The fluid domain is subdivided into a series of triangular elements in which a quadratic approximation is made for suspended sediment concentration. Model could deal with a continuous aggregation by stipulating the settling velocity of the flocs in each element. The model provides suspended sediment concentration, bed shear stress, erosion versus deposition rate and bed profile at the given time step.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.7
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• pp.747-754
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• 2004

Thermo-fluid characteristics in coke oven, sintering machine and blast furnace in iron-making facility are key processes related to the quality and productivity of the pig iron. Solid material in the processes usually forms a bed in a gas flow. For simulation of the processes by mathematical model, the solid beds are idealized to be a continuum and a reacting solid flow in the gas flow. Governing equations in the form of partial differential equations for the solid material can be constructed based on this assumption. Iron ore sintering bed is simulated and limited amount of parametric study have been performed. The results have a good agreement with the experimental results or physical phenomena, which shows the validity and applicability of the model.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.345-349
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• 2016

보본체와 물받이공을 보호하는 바닥보호공(bed protection)은 굴요성 구조(flexible structure)인 돌망태, 블록공, 사석 등으로 설치되어야 하며, 일반적으로 경제성과 시공성이 우수한 사석(riprap)이 많이 이용된다. 이때 사석의 안정성 확보를 위한 설계기준으로 국내의 경우 포설길이에 대해서만 제시하고 있으나, 외국의 경우 수심, 유속 등의 값을 기초로 사석의 크기, 포설두께, 포설길이를 산정할 수 있도록 상세하게 제시하고 있다. 이와 같은 실정으로 국내 하천 실무자들이 바닥보호공을 설계 할 때 하천설계기준을 바탕으로 블라이 공식 또는 국립건설시험소 공식을 적용하여 사석의 포설길이는 산정하지만 사석의 크기, 중량 등의 제원들은 외국 설계기준을 차용하여 산정하거나 생략하는 경우도 있다. 따라서 하천설계기준의 보완 및 최근 국내 주요하천에서 발생하는 바닥보호공 유실, 침하 등의 문제를 해결하기 위한 연구가 필요하다. 본 연구는 전산유체동역학(Computational Fluid Dynamics, CFD) 모형인 FLOW-3D 모형을 이용하여, 바닥보호공 주변 흐름에 대한 수치모의를 수행하였다. 이때 난류 모형은 LES (Large Eddy Simulation) 모형을 적용하였으며, 바닥보호공에 작용하는 비교적 작은 척도의 와(vortex)를 해상할 수 있도록 조밀한 격자를 부여하였다. 초기 수치모형 결과의 적정성은 수리실험 결과와 비교하여 판단하였으며, 수리실험을 잘 재현해내는 격자, 매개변수 등을 적용하여 보의 하류 수위 변화에 따른 유속, 난류강도 등에 대한 분석을 수행하였다. 본 연구 결과는 바닥보호공 설계를 위한 기초자료로 활용될 수 있으며, 향후 수리실험과 병행하여 국내 실정에 맞는 설계식 개발에 대한 연구가 필요한 것으로 보인다.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.308-308
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• 2017

국내 하천에 설치된 횡단구조물은 2009년을 기준으로 약 20,753개로 알려져 있으며 수위 유지, 하상고 유지 등의 목적을 가지고 설치된다. 그러나 낙차를 가진 빠른 유속의 흐름을 형성시켜, 하류 하상에서 국소 세굴을 발생시킨다. 이를 방지하기 위해 횡단구조물 하류에 굴요성 구조(flexible structure)인 돌망태, 블록공, 사석 등으로 이루어진 바닥보호공(bed protection)이 설치되나 유실, 침하 등의 문제가 빈번히 발생되고 있어, 문제를 해결하기 위한 연구가 필요하다. 본 연구는 이러한 피복 대책에서 일어날 수 있는 파괴 기구인 전단파괴, 흡출 파괴, 경계 파괴, 하상 형태 변화에 따른 하부 침식 중 흡출 파괴(winnowing failure)를 유발하는 흐름을 검토하기 위한 수치모의를 수행하였다. 이때 흡출 파괴는 바닥보호공의 공극으로 미세한 하상 재료가 난류와 침투류의 작용에 의해 침식되어 바닥보호공이 침하되는 것을 말한다. 수치모의는 전산유체동역학(Computational Fluid Dynamics, CFD) 모형인 FLOW-3D 모형을 이용하였으며, 난류 모형으로 LES 모형을 적용하고 조밀한 격자를 부여하여 바닥보호공의 공극에서 발생되는 비교적 작은 척도의 와(vortex)를 해상할 수 있도록 하였다. 수치모의에 적용된 횡단구조물은 보, 물받이공, 바닥보호공으로 구성하였으며 특히, 바닥보호공의 형상은 구체(sphere)로 가정하여 다층으로 배치하였다. 바닥보호공의 공극 또는 구체 사이에서 발생되는 유속, 압력 등의 흐름특성을 분석한 결과, 바닥보호공 두께가 두꺼울수록 흡출 파괴에 대해 안정적인 것으로 나타났다. 이는 바닥보호공 설계를 위한 기초자료로 활용될 수 있으며, 향후 입자영상유속계(Particle Image Velocimeter, PIV)와 같이 공극에서 흐름을 측정할 수 있는 방법과 병행한 연구를 수행할 수 있을 것이다.

• Journal of the Korea Institute of Building Construction
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• v.18 no.1
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• pp.25-31
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• 2018

In this study, the Controlled Low Strength Material (CLSM) was investigated to utilize the bottom ash and fly ash generated in the Circulating Fluidized Bed Combustor (CFBC). It was confirmed that the CFBC fly ash (CFBC-F) and CFBC bottom ash (CFBC-B) had an irregular particle shape through SEM measurement. According to the results of the hazard analysis, it was also confirmed that they were environmentally safe. In the case of mixing with CFBC-F, the unit quantity was increased. Regarding the rate of change of length, shrinkage in the range of -0.05~0.50% occurred in the air dry curing condition and expansion in the range of 0.1~0.6% in the sealed curing condition. Compressive strength was increased in the sealed curing condition compared to the air dry curing condition because there was enough moisture for hydration reaction in the long term. Therefore, the results of this study are likely be used as basic research data of mine filler materials.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.475-483
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• 2019

Special chemical warfare agents are lethal gases that attack the human respiratory system. One of such gases are blood agents that react with the irons present in the electron transfer system of the human body. This reaction stops internal respiration and eventually causes death. The molecular sizes of these agents are smaller than the pores of an activated carbon, making chemical adsorption the only alternative method for removing them. In this study, we carried out a Computational Fluid Dynamics simulation by passing a blood agent: cyanogen chloride gas through an SG-1 gas mask canister developed by SG Safety Corporation. The adsorption bed consisted of a Silver-Zinc-Molybdenum-Triethylenediamine activated carbon impregnated with copper, silver, zinc and molybdenum ions. The kinetic analysis of the chemical adsorption was performed in accordance with the test procedure for the gas mask canister and was validated by the kinetic data obtained from experimental results. We predicted the dynamic behaviors of the main variables such as the pressure drop inside the canister and the amount of gas adsorbed by chemisorption. By using a granular packed bed instead of the Ergun equation that is used to model porous materials in Computational Fluid Dynamics, applicable results of the activated carbon were obtained. Dynamic simulations and flow analyses of the chemical adsorption with varying gas flow rates were also executed.

• Journal of Pharmaceutical Investigation
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• v.33 no.3
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• pp.179-185
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• 2003

Melatonin (MT) is an indole amide pineal hormone. It has not only very short half-life but also pH-sensitive property. The sustained release dosage form which delivers MT in a circadian fashion over 8 h is clinical value. The purpose of this study is to prepare sugar beads using multiple coating methods and enteric-coated in a sustained release to evaluate in vitro release characteristics in simulated gastric and intestinal fluids. The $Eudragit^{\circledR}$ as a polymer, sustained release membrane, and triethylcitrate (TEC) as a plasticzer were used. Multi-coated melatonin delivery system was composed of sugar, various excipients, $Eudragit^{\circledR}$ and enteric materials (e.g. hydroxy propyl methyl cellulose phthalate, HPMCP), and prepared by fluid bed coater. The dissolution test was carried out using the basket method at a stirring speed of 100 rpm at $37^{\circ}C$ in simulated gastric (pH 1.2) and intestinal fluid (pH 7.4). The released amount of MT was determined by High performance liquid chromatography method. The morhologies of surface and cross section of multi-coated beads were observed by scanning electron microscope. Size of multi-coated sugar beads was ranged over $1000{\sim}1300\;{\mu}m$. The release rate of MT from coated beads was limited in simulated gastric fluid (pH 1.2), but it was sustained in intestinal fluid (pH 7.4) during $3{\sim}8$ hours. The MT beads may provide small-intestine-targeted device for oral delivery. Studies on animal and relative experiment are in process.

• Journal of Pharmaceutical Investigation
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• v.38 no.3
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• pp.177-182
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• 2008

The purposes of this study were to prepare dual-layered coated compact pellets containing three nutrients Glucose, Chromium picolinate, Vitamin C) for rumen bypass. The core compact pellets were prepared by an extrusionspheronization method and then double layered coated with pH independent EC (ethyl cellulose) and pH-dependent polymers ($Eudragit^{(R)}$ E100) using a fluid-bed spray coater. Depending on the coating levels of EC and $Eudragit^{(R)}$ E100, release profiles were variable in simulated rumen (pH 6.8) and abomasums (pH 2.0) fluid using USP apparatus I (basket method). When compact pellets were coated with EC (about 10% level in inner layer) and then $Eudragit^{(R)}$ E100 (20% level in outer layer) in a dual-layered manner, rumen-bypass delivery resisting rumen fluid followed by release in abomasums fluid could possible. The friability was also satisfactory based on chewing behavior of ruminants. The dual-layered coated compact pellets showed smooth surface and distinct inner/outer layers using scanning electron microscopy (SEM). The current rumen bypass delivery system can be also applicable to deliver other nutrients in ruminants.

• Applied Biological Chemistry
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• v.29 no.3
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• pp.241-247
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• 1986

The relationship between rice and the fluid during cooking was investigated to examine the factors affecting the quality of cooked rice and a new rice cooking method was proposed to improve the unpalatability of aged Milyang 23-long grain rice variety. The changes of heights of rice-bed and the fluid during cooking were measured with a laboratory cooking apparatus made of flat bottomed graduated glass cylinder. Around the boiling, a sudden disappearance of the fluid was observed and then thin film was formed on the rice grains. This film coating was fortified by the addition of 1-2%(w/w) of glutinous rice powder as a film forming agent. The artificial coating on the cooked rice of low quality remarkably improved the gloss, moisture content and shape and the extent of leaching of rice solid into the fluid was reduced with the treatment.