• 한국응용과학기술학회지
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• 제13권2호
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• pp.1-20
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• 1996

Surfactants are the surface-active molecules that display amphiphilicity, Because of this surface activity and amphiphilicity, surfactants have been used in wide industrial applications such as foods, detergents, cosmetics, medicine, polymers, paints, flotation, textiles. These days, their applications extend to high-technology industries such as microelectronics, magnetic recording material, advanced batteries, novel separations, etc. As new applications of surfactants are found and the demand of the surfactants increases, surfactant industry has been more pressed to face a formidable challenge, which is to develop surfactants that are envirionmentally friendly. In this regard biosurfactants may be alternatives to chemical surfactants, since biosurfactants are biologically compatible, more biodegradable, less toxic, and highly specific. Because of these excellent advantages over those of chemical surfactants, much efforts have been made in biosurfactant research. This article reviews biosurfactants in several aspects, that is, their definition, structures, properties, applications, and prospects.

• 대한화학회지
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• 제35권4호
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• pp.389-396
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• 1991

침전 부선기술에 의해 물시료 중 극미량 비소의 분리 농축 및 정량에 관하여 연구하였다. 부유물질을 걸러낸 물시료 1.0l를 삼각 플라스크에 취하고 비소를 pH 8.5${\pm}$0.1에서 La(OH)$_3$ 침전과 함께 공침시켰다. 몰비 1:8의 sodium oleate와 sodium dodecyl sulfate 혼합 계면활성제를 가하여 침전을 소수성으로 만든 다음, 부선용기에서 질소기체를 bubbling하여 용액 표면으로 띄웠다. 뜬 침전을 감압에 의하여 유리거르게에 정량적으로 걸러 모으고 작은 부피의 1.0M 황산으로 녹여서 탈이온수로 정확하게 25.00 ml의 표선까지 묽혔다. 농축된 비소를 아르신으로 발생시켜 silver diethyldithiocarbamate의 착물을 만든 다음 분광광도법으로 정량하였다. 검정곡선은 원래의 용액 중에서 20 ng/ml까지 직선성이 좋았다. 분석 결과는 캠퍼스 폐수와 강물 중에서 비소의 함량이 8.2 ng/ml 와 1.0 ng/ml임을 보여 주었고, 이들 시료에 일정량의 비소를 첨가하고 분석한 결과로부터의 회수율은 각각 93${\%}$와 90${\%}$이었다. 이로서 본 방법이 여러 가지 물시료 중의 극미량 비소 정량에 응용이 가능함을 결론지을 수 있었다.

• 한국물환경학회지
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• 제35권6호
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• pp.567-573
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• 2019

DABF(Dissolve Air Flotation with Ball Filter) is developed as the DAF with the addition of a fiber ball at the lower part of the DAF. The DABF with a capacity of 4,500 ㎥/h was constructed at Gijang SWRO plant in Busan. Since the ball filter has high filtration rate, the loading rate of DABF was designed from 20 to 42 ㎥/h/㎡. When one DABF basin is in the back washing mode, the loading rate of other two DABF basins is increased to 42 ㎥/h/㎡. Turbidity at the BF outlet in DABF is <2 NTU at turbidity of 5-10 NTU at the BF inlet. If there is no algae bloom and turbidity is low in raw seawater, only BF in DABF is operated and meets <2 NTU at the BF outlet. Even if BF is operated at high hydraulic loading rates, no significant differential pressure increases and reduction in the turbidity removal rate is minimal in a day. Thus, DABF is the pre-treatment technology that provides stable water quality even with BF onlyoperation without DAF operation. Compared with the DAF, DABF requires additional facilities such as valves, piping, and drainage systems for backwashing the BF. But in terms of footprint and operating costs, DABF has more advantages than DAF. With DABF application, the load of the downstream filtration equipment is decreased so that the capacity of the filtration equipment can be reduced. Also, if the downstream filtration equipment is to be maintained the same regardless of DABF, the operating cost of DABF is less than DAF.

• 분석과학
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• 제5권4호
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• pp.425-431
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• 1992

$La(OH)_3$ 공침에 의한 극미량 인산이온의 부선 및 농축에 관한 연구를 가시/자외선 분광광도법을 이용하여 수행하였다. 암모니아용액으로 조절한 pH 9.5의 1.0L 시료용액 중 인산 이온을 수산화란탄 침전에 공침시켰다. 1:8의 sodium oleate와 sodium dodecyl sulfate 혼합 계면활성제를 가하고 질소기체를 bubbling하여 침전들을 용액 표면으로 띄웠다. 뜬 침전들을 감압 플라스크에 모은 다음 용액을 걸러 버리고 침전을 묽은 암보니아용액으로 씻고 황산에 녹였다. 몰리브덴 청색법으로 농축된 용액 중 인산이온을 정량하였다. 이상의 방법으로 수도물과 강물 중 인산이온을 분석하였고 각 시료에 인산이온을 20.0ng/mL 가하여 분석한 결과 각각 93%와 86%의 회수율을 얻었다.

• 산업기술연구
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• 제10권
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• pp.83-88
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• 1990

The samples used for this work were low grade c1ay($Fe_2O_3$ : 2.90%, $TiO_2$ : 1.65%) produced from Youngsan-po district, and for the iron-bearing impurities removal having a bad influence on Kaoline sample was carried out column floatatoin using Oleic acid, Potassium oleat, Aero 840 promotor, Aero 870 promotor and Keroseneas collectors. For removal of the iron-vearing impurities from the kaoline, investigated first chemical composition size distribution of Kaoline sample, also performanced a basic study on pulp density, collector and pH change on a sort of frother. The flotation separation of impurities from kaoline can be achieved by using both oleic acid and Aero 840 promotor as collectors within narrow acid limits(pH 2-3). Pine oil was more effective frother than MIBC with olelic acid as aa collector.

• 펄프종이기술
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• 제31권5호
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• pp.18-23
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• 1999

This study examined the effects of multiple recycling on deinkability and properties of recycled paper from laser computer printout(LCPO). First, alkaline paper with a 20% printed area was disintegrated by TAPPI standard disintegrator. After dewatering , the pulp was followed by flotation, handsheet making, and drying at room temperature, in order. A sequence of printing , disintegrating, flotating , handsheet making and drying was one recycling cycle and this cyclic treatment was repeateed from zero to five times. The residual ink content in recycled handsheets by SEM-EDXA and Py-GC analyseswas increased slightly as recycling number increase. After five cycles of recycling the ISO brightness of recycled handsheets dropped to about 90% of the original brightness. However, it had a gain of 10% in opacity. The most of physical properties of recycled handsheets were decreased as recycling numbers increase except of for tear strength.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2011년도 추계학술발표회 논문집
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• pp.119-123
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• 2011

The application of flexo printed ONP and OCC leads to brightness decrease of deinked stock in ONP recycling system. The largest problems are due to accumulation of flexo ink & introduction of brown fibers. All these are emphasized by variations in the amount of flexo printed ONP and OCC in recovered ONP stock. Most of the brightness problems caused by flexo ink can be helped and solved by applying a proper polyelectrolytes as coagulation agent and flocculation agent. This requires exact evaluation of sedimentation or dissolved air flotation potentials of flexo ink and polyelectrolytes. Effect of bleaching chemical (H2O2) addition level on the increase of brightness of OCC included stock has been investigated by lab scale test.

• 펄프종이기술
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• 제35권4호
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• pp.34-41
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• 2003

The effect of wettability of deinking agents which formed with various nonionic surfactants against the pulp fibers and ink particles were studied, And the effect of flotation processes on the deinking were also investigated. The wettabilities of the deinking agents against the water and ink particles were measured by Washburn tube and sessile drop techniques, respectively. As the water absorption increased (i.e., hydrophilicity increased), the ink removal increased, which indicates that the ink removal is strongly affected by the detachment process due to the swelling of the pulp. Also, when the contact angle of air/ink/deinking agent increased, the hydrophobicity of the ink particles increased, the efficiency of the ink removal and the brightness increased.

• 대한환경공학회지
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• 제38권9호
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• pp.482-496
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• 2016

하천과 호수의 부영양화로 인하여 남조류가 대량으로 증식하게 되면 고유의 생물독소로 인한 위해뿐만 아니라 정수처리 과정에서 경제적 손실을 야기할 가능성이 있다. 현재 상용화되어있는 천연조류제거제인 M사의 W.H. 응집제(이하 W.H.)는 참나무 유래 성분의 살조 및 타감작용을 이용한 응집.부상공정을 통하여 조류를 사전에 제거함으로써 정수공정에 미치는 영향을 효과적으로 저감할 수 있다. 그러나, W.H.를 활용한 응집 부상공정은 정수처리의 전처리공정으로 적용된 사례가 없기 때문에 최적주입농도의 결정기법에 대한 보고 또한 전무한 실정이다. 본 연구에서는 (1) 한강에서 채취한 복합 조류와 (2) 남조류를 선택적으로 대량 배양하여 광조건 하에서 W.H. 투여량 및 조류농도 등의 여러 조건을 변화시키면서 Jar-test를 시행하여 응집 부상공정에서의 조류의 제거기작을 검토하였다. Jar-test 결과를 바탕으로 IBM-SPSS를 활용한 다중회귀분석을 실시하여 최적 W.H. 주입농도를 결정하기 위한 Chl-a 농도와 탁도를 변수로 하는 두 가지 선형식을 도출하였다. 또한 유입수질의 변동에 따라 W.H. 주입농도를 신속하게 결정하고 자동화할 수 있는 자동제어 로직의 프로토타입(Prototype)을 제시하였다.

• Journal of Microbiology and Biotechnology
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• 제20권1호
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• pp.179-186
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• 2010

In biological wastewater treatment, high lipid concentrations can inhibit the activity of microorganisms critical to the treatment process and cause undesirable biomass flotation. To reduce the inhibitory effects of high lipid concentrations, a two-phase anaerobic system, consisting of an anaerobic sequencing batch reactor (ASBR) and an upflow anaerobic sludge blanket (UASB) reactor in series, was applied to synthetic dairy wastewater treatment. During 153 days of operation, the two-phase system showed stable performance in lipid degradation. In the ASBR, a 13% lipid removal efficiency and 10% double-bond removal efficiency were maintained. In the UASB, the chemical oxygen demand (COD), lipid, and volatile fatty acid (VFA) removal efficiencies were greater than 80%, 70%, and 95%, respectively, up to an organic loading rate of 6.5 g COD/l/day. No serious operational problems, such as significant scum formation or sludge washout, were observed. Protein degradation was found to occur prior to degradation during acidogenesis.