• Korean Journal of Materials Research
• /
• v.12 no.5
• /
• pp.391-397
• /
• 2002

Synthesis and process development of nano-size Ti powder by SFE(Sodium/halide Flame Encapsulation) method were investigated. Four concentric coflow burner was used and its flame configuration was $TiCl_4/Ar/Na/Ar$ in order from the center. Flame has been controlled by the various processing parameters such as temperature of burner and flow rates of both $TiCl_4$(g) precursor and Na(g). It was found that yellow-colored flame was shown in the flow rates of 70cc/min of $TiCl_4$(g) precursor and 2 $\ell$ /min of Na(g) which were regarded as optimum flame condition. The powders encapsuled by NaCl were produced having the average powder size of 250nm. The results of X-ray diffraction showed that powders from the optimized condition consisted of pure Ti and NaCl. TEM analysis confirmed that the several Ti powders of 20-100nm were encapsulated with NaCl. After removing sodium chloride by heat treatment, the spherical Ti powders with the size range of 80 to 150nm were obtained.

• Journal of the Korean Society of Combustion
• /
• v.19 no.1
• /
• pp.17-28
• /
• 2014

In this study, the laminar burning velocity of syngas fuel($H_2/CO$) and flame structure with various hydrogen contents were studied using both experimental measurements and detailed kinetic analysis. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including chemical kinetic analysis were made using CHEMKIN Package with USC-Mech II. A wide range of syngas mixture compositions such as $H_2$ : CO = 10 : 90, 25 : 75, 50 : 50, 75:25 and equivalence ratios from lean condition of 0.5 to rich condition of 5.0 have been considered. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increment of $H_2$ content although the burning velocity of hydrogen is faster than the carbon monoxide above 10 times. This phenomenon is attributed to the rapid production of hydrogen related radicals such as H radical at the early stage of combustion, which is confirmed the linear increase of radical concentrations on kinetic analysis. Particular concerns in this study are the characteristics of burning velocity and flame structure different from lean condition for rich condition. The decrease of OH radicals and double peaks are observed with $H_2$ content in rich condition once $H_2$ fraction exceeds over threshold.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.20 no.8
• /
• pp.2626-2636
• /
• 1996

A study of soot deposition and reentrainment was carried out both theoretically and experimentally to understand behavior of soot formed by incomplete combustion in a diesel engine. Theoretically, soot deposition on engine cylinder wall and/or piston head was studied with a stagnation point flow approximation. Soot reentrainment occurred upon exhaust gas blowdown was also studied by assuming a long-normal shear velocity distribution. Experimentally, a LPG$O_2/N_2$ flame impinging on a disk, produced by a concentric tubular burner, was chosen as deposition configuration and a shear flow unit with compressed air was installed for the study of reentrainment. For selected flame configuration, soot deposition measurements were conducted and showed that the dominant deposition mechanism was thermophoresis. Distributions of gas temperature and soot number density were estimated by combining data obtained by a B-type thermocouple with a thermophoretic transport theory. Disk temperature distributions were directly measured using a K-type thermocouple. Soot size and morphology were estimated from a TEM photograph. Ratios of soot deposit to reentrained amount were measured for a wide range of shear flow velocities, which showed that the reentrainment model was reasonable.

• Journal of Welding and Joining
• /
• v.9 no.3
• /
• pp.18-25
• /
• 1991

The purpose of this paper was to investigate the effect of deposition configuration on the mechanical properties of the flame sprayed titania ceramic coating. The sprayed deposition configuration was made in different five types with titania ceramic and Ni-base alloy on the mild steel substrate. The composite coating exhibited superior mechanical properties such as hardness, adhesive strength, thermal shock resistance and corrosion resistance, whereas the mixed coating proved to be more resistant to erosion. Especially graded coating, which consist of Ni-base alloy undercost, intermediate grade coat and titania ceramic overcost, showed excellent mechanical properties.

• 한국연소학회:학술대회논문집
• /
• 2005.10a
• /
• pp.132-137
• /
• 2005

The burning characteristics of interacting spherical droplet in a turbulent flow are numerically investigated. The transient combustion of 3-dimensionally arranged droplets, both the fixed streamwise droplet distances of 3 radii and 10 radii and different turbulence intensities, is studied. The results obtained from the present numerical analysis show that droplet vaporization rate for heptane droplet is insensitive to turbulence intensity, and that the transient flame configuration and retardation of droplet surface temperature augmentation with streamwise droplet spacing substantially influence vaporization process of interacting droplets. Single flame mode in which individual flames are merged into single flame, with decreasing streamwise droplet spacing, becomes faster. Therefore, vaporization rate of the second droplet with decreasing streamwise droplet spacing decreases remarkably with flame movement.

• 한국연소학회:학술대회논문집
• /
• 2002.11a
• /
• pp.105-112
• /
• 2002

The objective of this research is to determine generally applicable design principles for the development of internally staged combustion devices. Utilizing a triple annulus combustor, air staged commercial propane flame configuration are studied. For this triple air staged combustor, the angular momentum weighted by it's swirl number and air distribution ratio was observed to be the critical criteria. An internal recirculation zone which develops on the centerline of the flame immediately downstream of the burner entraps the fuel into a fuel rich eddy. Then sufficient heat must he transferred from the flame via radiation to the chamber heat transfer surfaces, such that when the second air is introduced, peak flame temperatures are suppressed. It is experimentally found out that the total NOx emission level in this type of burner is lower than 0.75g/kg.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.10
• /
• pp.1355-1363
• /
• 2002

An experimental study was conducted to investigate the interaction phenomena of droplet array combustion in ambient environment. The droplet with 1 mm in diameter was supported from an optical fiber and ignited with a hot wire. Combustion lifetimes and burning rate constants were measured for fuel of nheptane according to parameters, which were junction and suspender spacings, and array configuration. Results show that the burning process considerably depends on the initial away configuration. The d$^2$-law is found to be correct when applied to both of the droplets in away and the single droplet. For separation distance of about 5mm, there exists a critical state. So the transition from a merged flame to separated flames occurs and burning velocity is much faster than before. Combustion lifetime of the lower droplet is shorter than that of the upper droplet in the two-dimensional arrays combustion. Burning rate constants of the droplets in arrays are smaller than that of the single droplet, while they become higher as separation distance increases. Combustion lifetimes of the droplets in arrays are longer than that of the single droplet and decrease as separation distance increase. It is concluded that the array configuration and the mergedness of the flame are the most important factors governing multi-droplet combustion.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.6
• /
• pp.688-696
• /
• 2004

Nonlinear dynamic behavior of diffusive-thermal instability in diluted CH$_4$/O$_2$ diffusion flames is numerically investigated by adopting detailed chemistry and transport. Counterflow diffusion flame is adopted as a model flamelet. Particular attention is focused on the pulsating-instability regime, which arises for Lewis numbers greater than unity, and the instability occurs at high strain rate near extinction condition in this flame configuration. Once a steady flame structure is obtained for a prescribed value of initial strain rate, transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed on the steady flame. Transient evolution of the flame depends on the initial strain rate and the amount of perturbed strain rate. Basically, the dynamic behaviors can be classified into two types, namely non-oscillatory decaying solution and diverging solution leading to extinction. The peculiar oscillatory solution, which has been found in the previous study adopting one-step chemistry and constant Lewis numbers, is net observed in this study, which is attributed to both convective flow and preferential diffusion effects.

• 한국연소학회:학술대회논문집
• /
• 2004.06a
• /
• pp.95-101
• /
• 2004

Dynamic behavior of diffusive-thermal instability in diluted $CH_4/O_2$ diffusion flames is numerically investigated by adopting detailed chemistry and transport. Counterflow diffusion flame is adopted as a model flamelet. Particular attention is focused on the pulsating-instability regime, which arises for Lewis numbers greater than unity, and the instability occurs at high strain rate near extinction condition in this flame configuration. Once a steady flame structure is obtained for a prescribed value of initial strain rate. transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed Oil the steady flame. Transient evolution of the flame depends on the initial strain rate and the amount of perturbed strain rate. Basically, the dynamic behaviors can be classified into two types, namely non-oscillatory decaying solution and diverging solution leading to extinction. The peculiar oscillatory solution. which has been found in the previous study adopting one-step chemistry and constant Lewis numbers, is not observed in this study, which is attributed to both convective flow and preferential diffusion effects.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.30 no.4 s.247
• /
• pp.343-349
• /
• 2006

Systematic experiments in $CH_4/Air$ counterflow diffusion flames diluted with He have been undertaken to study the oscillatory instability in which lateral flame size was less than burner nozzle diameter and thus lateral heat loss could be remarkable at low global strain rate. The oscillatory instability arises for Lewis numbers greater than unity and occurs near extinction condition. The oscillation is the direct outcome from the advancing and retreating edge flame. The dynamic behaviors of extinction in this configuration can be classified into three modes; growing, harmonic and decaying oscillation mode near extinction. As the global strain rate decreases, the amplitude of the oscillation becomes larger. This is caused by the increase of lateral heat loss which can be confirmed by the reduction of lateral flame size. Oscillatory edge flame instabilities at low global strain rate are shown to be closely associated with not only Lewis number but also heat loss (radiation and lateral heat loss).