• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.3
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• pp.221-228
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• 2013

An experimental study was carried out to investigate the effects of the injection timing on the spray and combustion characteristics in a spray-guided direct-injection spark-ignition (DISI) engine under lean stratified operation. An in-cylinder pressure analysis, exhaust emissions measurement, and visualization of the spray and combustion were employed in this study. The combustion in a stratified DISI engine was found to have both lean premixed and diffusion controlled flame combustion characteristics. The injection timing condition corresponding to the stratified mixture characteristics was verified to be a dominant factor for these flame characteristics. For the early injection timing, a non-luminous blue flame and low combustion efficiency were observed as a result of the lean homogeneous mixture formation. On the other hand, a luminous sooting flame was shown at the late injection timing because of an under-mixed mixture formation. In addition, the smoke emission and incomplete combustion products were increased at the late injection timing as a result of the increased locally rich area. On the other hand, the NOx emissions decreased and IMEP increased as the injection timing retarded. The combustion phasing produced by the injection timing was verified as the reason for this observation.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.11
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• pp.1379-1389
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• 1999

A new technique for control of size and shape of flame-made particles is Introduced. The characteristic sintering time can be controlled Independently of collision time by heating the particles with irradiation of laser because the sintering time strongly depends on temperature. A coflow oxy-hydrogen diffusion flame burner was used for $SiCl_4$ conversion to silica particle. Nanometer sized aggregates irradiated by a high power CW $CO_2$ laser beam were rapidly heated up to high temperatures and then were sintered to approach volume-equivalent spheres. The sphere collides much slower than the aggregate, which results in reduction of sizes of particles maintaining spherical shape. Light scattering of Ar ion laser and TEM observation using a local sampling device were used to confirm the above effects. When the $CO_2$ laser was irradiated at low position from the burner surface, particle generation due to gas absorption of laser beam occurred and thus scattering intensity increased with $CO_2$ laser power. At high irradiation position, scattering intensity decreased with $CO_2$ laser power and TEM image showed a clear mark of evaporation and recondensation of particles for high $CO_2$ laser power. When the laser was irradiated between the above two positions where small aggregates exist, average size of spherical particles obviously decreased to 58% of those without $CO_2$ laser irradiation with the spherical shape. Even for increased carrier gas flow rate by a factor of three, TEM photograph also revealed considerable reduction of particle size.

• Journal of Energy Engineering
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• v.22 no.2
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• pp.128-135
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• 2013

In order to estimate the combustion characteristics and the gas interchangeability for natural gas with various compositions per each production area, equivalent gas are using to replace natural gas. It is known that an equivalent gas has the same the heating value, the compression factor, the relative density, CO emission and the burning velocity as the original natural gas. However, it is not reported that the flame shape and thermal efficiency and NOx emission by real gas appliance. In this study, equivalent gas was examined the validation to replace natural gas. The CO emission the burning velocity and the flame temperature were reconfirmed, and the flame shape, the NOx emission and the thermal efficiency were numerically and experimentally investigated. As results, there was not a large difference between natural gas and equivalent gas. This result demonstrated that there was no problem using equivalent gas to replace natural gas.

• Environmental Analysis Health and Toxicology
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• v.22 no.2 s.57
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• pp.157-163
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• 2007

Tetrabromobisphenol A (TBBPA) is the most widely used BFR (brominated flame retardants) as a reactive flame retardant in printed circuit boards, and as additive applications in several types of polymers. The purpose of this study is to assess the adverse effects of TBBPA on the benthic amphipod (Hyalella azteca). Results on the acute toxicity of TBBPA using Hyalella azteca showed that NOEC and LOEC are 100mg/kg and 200mg/kg, respectively. In addition, when chronic toxicity of TBBPA was investigated at the concentration ranges between 0.01 to 100mg/kg, it was found that NOECs are $10mg/kg(fecundity){\sim}100mg/kg(viability)$, respectively. Significant fecundity inhibition was appeared at 100mg/kg of TBBPA, however, this concentration did not show severe adverse effect on weight increment. The values of PNEC were determined as 0.1mg/kg (fecundity) and 1mg/kg (lethal effect), respectively, using a safety factor suggested by EU and OECD.

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.829-835
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• 2011

A dispersive liquid-liquid microextraction based on solidification of floating organic droplet (DLLME-SFO) has been developed as a new approach for the extraction of trace copper in water and beverage samples followed by the determination with flame atomic absorption spectrometry. In the DLLME-SFO, 8-hydroxy quinoline, 1-dodecanol, and methanol were used as chelating agent, extraction solvent and dispersive solvent, respectively. The experimental parameters related to the DLLME-SFO such as the type and volume of the extraction and dispersive solvent, extraction time, sample volume, the concentration of chelating agent and salt addition were investigated and optimized. Under the optimum conditions, the enrichment factor for copper was 122. The method was linear in the range from 0.5 to $300\;ng\;mL^{-1}$ of copper in the samples with a correlation coefficient (r) of 0.9996 and a limit of detection of $0.1\;ng\;mL^{-1}$. The method was applied to the determination of copper in water and beverage samples. The recoveries for the spiked water and beverage samples at the copper concentration levels of 5.0 and $10.0\;ng\;mL^{-1}$ were in the range between 92.0% and 108.0%. The relative standard deviations (RSD) varied from 3.0% to 5.6%.

• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2813-2818
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• 2010

A novel method was developed for the speciation of chromium in natural water samples based on homogeneous liquid-liquid extraction and determination by flame atomic absorption spectrometry (FAAS). In this method, Cr(III) reacts with a new Schiff's base ligand to form the hydrophobic complex, which is subsequently entrapped in the sediment phase, whereas Cr(VI) remained in aqueous phase. The Cr(VI) assay is based on its reduction to Cr(III) by the addition of sodium sulfite to the sample solution. Thus, separation of Cr(III) and Cr(VI) could be realized. Homogeneous liquid-liquid extraction based on the pH-independent phase-separation process was investigated using a ternary solvent system (water-tetrabutylammonium ion ($TBA^+$)-chloroform) for the preconcentration of chromium. The phase separation phenomenon occurred by an ion-pair formation of TBA and perchlorate ion. Then sedimented phase was separated using a $100\;{\mu}L$ micro-syringe and diluted to 1.0 mL with ethanol. The sample was introduced into the flame by conventional aspiration. After the optimization of complexation and extraction conditions such as pH = 9.5, [ligand] = $1.0{\times}10^{-4}\;M$, [$TBA^+$] = $2.0{\times}10^{-2}\;M$, [$CHCl_3$] = $100.0\;{\mu}L$ and [$ClO_4$] = $2.0{\times}10{-2}\;M$, a preconcentration factor (Va/Vs) of 100 was obtained for only 10 mL of the sample. The relative standard deviation was 2.8% (n = 10). The limit of detection was sufficiently low and lie at ppb level. The proposed method was applied for the extraction and determination of chromium in natural water samples with satisfactory results.

• Korean Journal of Optics and Photonics
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• v.29 no.6
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• pp.233-240
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• 2018

In this paper, a design method to reduce fabrication errors in reflector shape of a test lamp for a flame detector is carried out. Although the test lamp should be operated in parallel with a high-intensity light, it is difficult to fix the small reflector that controls the central light during fabrication. To solve these problems, a small spherical reflector is designed to minimize the performance degradation for a light loss factor of less than 5%, even during tilt and decenter, and a spherical shape is proposed for a small reflector with little effect on the error when designing the optical system.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1976-1980
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• 2010

A simple and reliable method has been developed to selectively separate and concentrate trace amounts of Fe(III) ions from water and food samples by using flame atomic absorption spectrometry. A new reagent, 5-hydroxy-4-ethyl-5,6-di-pyridin-2-yl-4,5-dihydro-2H-[1,2,4] triazine-3-thione, was synthesized and characterized by using FT-IR spectroscopy and elemental analysis. Effects of pH, concentration and volume of elution solution, sample flow rate, sample volume and interfering ions on the recovery of Fe(III) were investigated. The optimum pH was found to be 5. Eluent for quantitative elution was 10 mL of 2 M HCl. The preconcentration factor of the method, detection limit (3s/b, ${\mu}gL^{-1}$) and relative standard deviation values were found to be 25, 4.59 and 1%, respectively. In order to verify the accuracy of the method, two certified reference materials (TMDA 54.4 lake water and SRM 1568a rice flour) were analyzed. The results obtained were in good agreement with the certified values. The method was successfully applied to the determination of Fe(III) ions in water and food samples.

• Proceedings of the KSME Conference
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• 2001.11b
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• pp.842-846
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• 2001

Our company produces boilers for industrial usages or power plants. The aim of this study is to investigate the flame structure, heat transfer to evaporator tube wall and NOx emission in the furnaces. Also we are to derive correct FEGT(Furnace Exit Gas Temperature) characteristic curve. When we design furnace and superheater, economizer etc. FEGT characteristic curve is very important factor for optimum design. We calculated turbulent reacting flow, heat transfer and NOx emission in furnace by using numerical modeling with the help of commercial code. Three dimensional steady state calculation is done. k-e turbulence model and equilibrium chemistry combustion model with $\beta-probability$ density function is used. To calculate radiation heat transfer discrete ordinates model is used. And we measured FEGT at several operating plants. Measurement is done by R-type thermocouple. Radiation shield is attached to the thermocouple to prevent radiation effect. Measured and calculated results show good agreement. And we could understand the flame structure and NOx formation positions in each furnaces.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.74-80
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• 2019

Hydrogen refueling stations that use compressed hydrogen at high pressure provide safety distances between facilities in order to ensure safety. Most accidents occurring in hydrogen stations are accidental leaks. When a leak occurs, various types of ignition sources generate a jet flame. Therefore, the analysis of leaked gas diffusion and jet flame due to high pressure hydrogen leakage is one of the most important factor for setting the safety distance. In this study, the leakage accidents that occur in the hydrogen refueling station operated in high pressure environment are simulated for various leakage source sizes. The results of this study will be used as a reference for the future safety standards.