• Journal of the Korean Society of Safety
• /
• v.21 no.3 s.75
• /
• pp.45-52
• /
• 2006

The AITs(autoignition temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are often used as a factor in determining the upper temperature limit for processing operations and conditions for handling, storage and transportation, and in determining potential fire hazard from accidental contact with hot surfaces. The measurement AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, time lag. Therefore, the AITs reported by different ignition conditions are sometimes significantly different. This study measured the AITs of benzene, toluene and xylene isomers from time lag using AS1M E659-78 apparatus. The experimental ignition delay times were a good agreement with the calculated ignition delay times by the proposed equations wtih a few A.A.D.(average absolute deviation). Also The experimental AITs of benzene, toluene, o-xylene, m-xylene and p-xylene were $583^{\circ}C,\;547^{\circ}C,\;480^{\circ}C,\;587^{\circ}C,\;and\;557^{\circ}C$, respectively.

• Journal of Mechanical Science and Technology
• /
• v.16 no.6
• /
• pp.851-860
• /
• 2002

In this study, it was attempted to obtain the fundamental data for the formation and oxidation of soot from a diesel engine. Combustion of spray injected into a cylinder is complex phenomenon having physical and chemical processes, and these processes affect each other. There are many factors in the mechanism of the formation and oxidization of soot and it is necessary to observe spray combustion microscopically. In order to observe with that view, free fuel droplet array was used as an experimental object and the droplet array was injected into an atmospheric combustion chamber with high temperature. Ambient temperature of the combustion chamber, interdroplet spacing, and droplet diameter were selected as parameters, which affect the formation and oxidation of soot. In this study, it was found that the parameters also affect ignition delay of droplet. The ambient temperature especially affected the ignition delay of droplet as well as the flame temperature after self-ignition. As the interdroplet spacing that means the local equivalence ratio in a combustion chamber was narrow, formation of soot was increased. As diameter of droplet was large, surface area of the droplet was also broad, and hence evaporation of the droplet was more active than that of a droplet with relative small diameter.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.10
• /
• pp.1387-1393
• /
• 2002

The measurement of velocity and stain rate field has been conducted in opposed impinging jet combustion. When a smaller diameter (5mm) orifice of pre-chamber was used, previous studies had reported that the combustion phase showed a shift from weak turbulent combustion to moderate turbulent combustion in the modified Borghi Diagram. In the case with smaller orifice diameter (5mm), NOx emission was substantially reduced by a factor 1/2 while the combustion pressure remains at the same as that in the conventional combustion. Hence, in this study, the experiment setup using PIV technique was designed to identify the relation of the strain rate distribution and NOx reduction associated with moderate turbulent combustion. As a result, it was found that the highly strained pockets are widely distributed during the combustion in the middle of chamber when the orifice diameter is 5mm. And the corresponding PDF distribution of strain rates she was the smoothly distributed strain .ate within the range of ｜$\pm$1000｜ (1/sec) rather than a spike shape about zero point. This is the unique feature observed in the combustion with 5mm orifice diameter. Therefore, it can be concluded that the substantial NOx reduction in opposed impinging combustor is mainly attributed to the strain rate distribution within the range of ｜$\pm$1000｜resulting in the combustion phase shift to moderate turbulent combustion.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.16 no.4
• /
• pp.151-158
• /
• 2008

Gasoline Homogeneous Charge Compression Ignition (HCCI) combustion is a new combustion concept. Unlike the conventional internal combustion engine, the premixed fuel mixture with high residual gas rate is auto-ignited and burned without flame propagation. There are several operating factors which affect HCCI combustion such as start of combustion (SOC), residual gas fraction, engine rpm, etc. Among these factors SOC is a critical factor in the combustion because it affects exhaust gas emissions, engine power, fuel economy and combustion characteristics. Therefore SOC of gasoline HCCI should be controlled precisely, and SOC detection should be preceded SOC control. This paper presents a control oriented SOC detection method using 50 percent normalized difference pressure. Normalized difference pressure is defined as the normalized value of difference pressure and difference pressure is difference between the in-cylinder firing pressure and the motoring pressure. These methods were verified through the HCCI combustion experiments. The SOC detection method using difference pressure provides a fast and precise SOC detection.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.996-999
• /
• 2011

The flow and combustion dynamics in the ignition and ramjet sustainer phase of an integrated rocket-ramjet(IRR) engine are investigated. The physical model includes the entire engine flowpath, from the freestream in front of the inlet to the exit of the exhaust nozzle. The flowfield obtained from a rocket booster study is used as the initial condition for the present analysis, so that the complete operation history of the engine can be obtained. The analysis for the primary factor governing flame propagation during the ignition and the key mechanisms for driving and sustaining the flow oscillations are performed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.11b
• /
• pp.251-254
• /
• 2001

In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC 600[V] wire. Messurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflaming pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of $2.5{\pm}0.04[w/cm^{2}]$ for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomplete combustion of FR-PVC which has high content of carbon in compound.

• Journal of Welding and Joining
• /
• v.17 no.4
• /
• pp.53-59
• /
• 1999

Amorphous alloys have also been called glassy alloys or non-crystalline alloys. They are made by the rapid solidification. The solidification occurs so rapid that the atoms are frozen in their liquid configuration. There are unique magnetic, mechanical, electrical and corrosive behaviors which result form their amorphous structure. In the study. amorphous coatings were manufactured with Ni-Cr-B-Si powders by flame spray. Measurement of hardness, were resistance, corrosion resistance and observation of microstructures and XRD, DSC were performed to investigate characteristics of amorphous coatings. The experimental results obtained as follow: 1) Amorphous powders could not be manufactured with the spraying in the spraying in the liquid nitrogen. But, amorphous coatings could be manufactured with the rotation cooling method by liquid nitrogen. In the fabrication of amorphous coatings, major factor was the rapid cooling by rotation of the substrate. 2) Hardness of coatings was obtained Hv 960 by formation of amorphous phase. But, wear resistance decreased. That was due to porosity in the coatings by the rapid cooling. 3) In the case of corrosion resistance, amorphous coatings were superior to air-cooled coatings. That was due to formation of amorphous phase. 4) After amorphous coatings were heat-treated at 520℃ for 1hr. hardness increased 80% and wear resistance increased 30% comparing with air cooled coatings. These were due to crystallization of amorphous phase and decrease of porosity by heat-treatment.

• Analytical Science and Technology
• /
• v.8 no.4
• /
• pp.807-814
• /
• 1995

Accurate measurements of ozone precursors are required to understand the process and extent of ozone formation in rural and urban areas. Nonmethane hydrocarbons (NMHCs) have been identified as important ozone precursors. Identification and quantification of NMHCs are difficult because of the large number present and the wide molecular weight range encountered in typical air samples. A major plan of the research team of the Climate and Air Quality Taiwan Station (CATs) was the measurement of atmospheric nonmethane hydrocarbons. An analytical method has been development for the analysis of the individual nonmethane hydrocarbons in ambient air at ppb (v) and subppb(v) levels. The whole ambient air samples were collected in canisters and analyzed by GC-FID with $Al_2O_3$/KCl PLOT column. Our targeted for quantitative analysis 43 compounds that may be substantial contributors to ozone formation. The retention indices and molar response factors of some commercially available $C_2{\sim}C_{10}$ hydrocarbons were determined and used to identify and quantify air samples. A quality assurance program was instituted to ensure that good measurements were made by participating in the International Nonmethane Hydrocarbon Intercomparison Experiments (NOMHICE).

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.47 no.12
• /
• pp.848-855
• /
• 2019

Eco-friendly gas turbine combustors are getting attention due to emission regulations. Swirler is important design factor for flame stability and flashback inside the combustor. Design methods of the axial swirler and the radial swirler were discussed and the suitability of the swirl number calculation considering the geometric design variables and the flow loss was examined in the radial swirl for gas turbine combustor. The swirl number of flow was calculated by computational fluid dynamics and compared with swirl number according to each design method.

• Journal of the Korean Society of Safety
• /
• v.29 no.4
• /
• pp.78-84
• /
• 2014

Viscosity agents were added to water to improve extinguishing performance of low pressure water mist suppression system on wood cribs fire, and a small scale wood cribs fire experiment was conducted to measure the extinguishing performance. CMC and agar were used for viscosity agent and as the amount of viscosity agent enlarges, it showed the increase of the viscosity of aqueous solution and the decrease of the fluidity. On wood cribs fire experiment, the extinguishing efficiency was improved with supplemental viscosity agent as it enhanced the adhesive time of aqueous solution on the wood, and therefore expanded the contact time of fire surface. The surface tension of aqueous solution was decreased with the addition of agar which to be assumed as an increase factor of extinguishing efficiency. By the extinguishing experimental result, the most effective extinguishing agent was CMC 0.6 wt.%, with the flame suppression time and the extinguishing time were reduced by 70s and 93s respectively at this concentration.