• Title/Summary/Keyword: Fitting of the discharge curve

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Analysis of Hydrodynamic Characteristics Apply to Nature-Friendly Stream Protection Method (자연형 호안공법을 적용한 소하천의 수리특성 분석)

  • Lee, Gang-Seuk;Park, Jong-Hwa;Yeon, Kyu-Bang
    • KCID journal
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    • v.17 no.2
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    • pp.71-81
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    • 2010
  • Stream Pilot Project, which began in May 2003 and finished in December 2003, was selected to develop effective methods applicable to nature-like streams. Stream restoration projects aim to maintain or increase ecosystem goods and services while protecting downstream and coastal ecosystems. Fields environmental monitoring such as flow discharge and precipitation were conducted along the Idong stream for amount of channel zone change in 2007. This study selected three monitoring positions to measure the water level and discharge of flowing water. A stage-discharge relation is obtained from direct discharge measurements for three stations by fitting an empirical relationship to the data set. Since discharge measures are made only for low flow conditions, a curve of discharge against stage can then be built by fitting these data with a power curve. And this study used data obtained from floodmark checkup as well as HEC-RAS model to analyze the hydrodynamic characteristics of monitoring sites. Reach-averaged hydraulic parameters for the supply reach were calculated from the small area's HEC-RAS model for Idong stream, and a HEC-RAS model used to analyze hydraulics for a period in 2007, after the stream was considered bank stabilization.

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Prediction of Lithium Diffusion Coefficient and Rate Performance by using the Discharge Curves of LiFePO4 Materials

  • Yu, Seung-Ho;Park, Chang-Kyoo;Jang, Ho;Shin, Chee-Burm;Cho, Won-Il
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.852-856
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    • 2011
  • The lithium ion diffusion coefficients of bare, carbon-coated and Cr-doped $LiFePO_4$ were obtained by fitting the discharge curves of each half cell with Li metal anode. Diffusion losses at discharge curves were acquired with experiment data and fitted to equations. Theoretically fitted equations showed good agreement with experimental results. Moreover, theoretical equations are able to predict lithium diffusion coefficient and discharge curves at various discharge rates. The obtained diffusion coefficients were similar to the true diffusion coefficient of phase transformation electrodes. Lithium ion diffusion is one of main factors that determine voltage drop in a half cell with $LiFePO_4$ cathode and Li metal anode. The high diffusion coefficient of carbon-coated and Cr-doped $LiFePO_4$ resulted in better performance at the discharge process. The performance at high discharge rate was improved much as diffusion coefficient increased.

XPS Analysis of PVDF Film Treated by Corona Discharge in Ethyl Methacrylate Vapor Atmosphere (에틸메타크릴레이트 증기 분위기에서 코로나 방전 처리한 PVDF 필름의 XPS 분석)

  • Moon, HuiKwon;Seomoon, Kyu
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.627-632
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    • 2016
  • Ethyl methacrylate (EMA) monomer coupling onto the polyvinylidene fluoride (PVDF) film surface was attempted to enhance the interfacial adhesive force between PVDF-polyvinyl chloride (PVC) bilayer films via dielectric barrier corona discharge. The interfacial forces were quite enhanced when PVDF films were treated by corona discharge in an EMA 1% atmosphere. The contact angle of PVDF films decreased due to corona treatment. X-ray photoelectron spectroscopy (XPS) analysis showed that the carbon and oxygen content of the PVDF film surface increased with corona discharge while the fluoride content decreased. The curve fitting of XPS $C_{1s}$ peaks revealed that the non-polar C-C bonded carbon and oxygen-bonded carbon increased gradually with corona treatment, while the fluorine-bonded carbon decreased.

Improvement of Rating Curve Fitting Considering Variance Function with Pseudo-likelihood Estimation (의사우도추정법에 의한 분산함수를 고려한 수위-유량 관계 곡선 산정법 개선)

  • Lee, Woo-Seok;Kim, Sang-Ug;Chung, Eun-Sung;Lee, Kil-Seong
    • Journal of Korea Water Resources Association
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    • v.41 no.8
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    • pp.807-823
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    • 2008
  • This paper presents a technique for estimating discharge rating curve parameters. In typical practical applications, the original non-linear rating curve is transformed into a simple linear regression model by log-transforming the measurement without examining the effect of log transformation. The model of pseudo-likelihood estimation is developed in this study to deal with heteroscedasticity of residuals in the original non-linear model. The parameters of rating curves and variance functions of errors are simultaneously estimated by the pseudo-likelihood estimation(P-LE) method. Simulated annealing, a global optimization technique, is adapted to minimize the log likelihood of the weighted residuals. The P-LE model was then applied to a hypothetical site where stage-discharge data were generated by incorporating various errors. Results of the P-LE model show reduced error values and narrower confidence intervals than those of the common log-transform linear least squares(LT-LR) model. Also, the limit of water levels for segmentation of discharge rating curve is estimated in the process of P-LE using the Heaviside function. Finally, model performance of the conventional log-transformed linear regression and the developed model, P-LE are computed and compared. After statistical simulation, the developed method is then applied to the real data sets from 5 gauge stations in the Geum River basin. It can be suggested that this developed strategy is applied to real sites to successfully determine weights taking into account error distributions from the observed discharge data.

Identification of Uncertainty in Fitting Rating Curve with Bayesian Regression (베이지안 회귀분석을 이용한 수위-유량 관계곡선의 불확실성 분석)

  • Kim, Sang-Ug;Lee, Kil-Seong
    • Journal of Korea Water Resources Association
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    • v.41 no.9
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    • pp.943-958
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    • 2008
  • This study employs Bayesian regression analysis for fitting discharge rating curves. The parameter estimates using the Bayesian regression analysis were compared to ordinary least square method using the t-distribution. In these comparisons, the mean values from the t-distribution and the Bayesian regression are not significantly different. However, the difference between upper and lower limits are remarkably reduced with the Bayesian regression. Therefore, from the point of view of uncertainty analysis, the Bayesian regression is more attractive than the conventional method based on a t-distribution because the data size at the site of interest is typically insufficient to estimate the parameters in rating curve. The merits and demerits of the two types of estimation methods are analyzed through the statistical simulation considering heteroscedasticity. The validation of the Bayesian regression is also performed using real stage-discharge data which were observed at 5 gauges on the Anyangcheon basin. Because the true parameters at 5 gauges are unknown, the quantitative accuracy of the Bayesian regression can not be assessed. However, it can be suggested that the uncertainty in rating curves at 5 gauges be reduced by Bayesian regression.

Electrochemical Aspects of Lithium and Sodium Intercalation into Two Dimensional FeMo$O_4$Cl (리튬과 소듐이 층간삽입된 FeMo$O_4$Cl의 전기화학적 성질)

  • Chang, Soon Ho;Song, Seung Wan;Choy, Jin Ho
    • Journal of the Korean Chemical Society
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    • v.41 no.9
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    • pp.488-494
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    • 1997
  • Lithium and sodium ions have been intercalated into two dimensional structure of $FeMoO_4Cl$. The electronic localization and the large difference in unit cell parameter between the pristine material and the intercalates lead to the existence of large biphased domains. In the case of the lithium system, a narrow range of $Li_xFeMoO_4Cl$ ($0.95{\leq}x{\leq}1.06$) solid solution has been found around the $LiFeMoO_4Cl$ composition. The OCV curve fitting has been performed using Armand's model. The occurrence of several parts in the charge-discharge curve is related to the electronic and structural modifications of the material during the intercalation process.

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Sealing analysis of sealing rings with respect to rubber material properties for high pressure valve of FCEV (FCEV용 고압 밸브 실링부의 고무재질에 따른 기밀해석)

  • Park, G.Y.;Yang, K.J.;Ro, E.D.;Park, J.S.;Chon, M.S.;Lee, H.W.
    • Journal of Institute of Convergence Technology
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    • v.7 no.2
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    • pp.13-16
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    • 2017
  • The design of sealing mechanisms of a manual pressure valve was analyzed with FE analysis for a hydrogen fuels charge and discharge system of FCEV. The damage prediction of the O-ring with respect to the material models of rubbers was calculated by the gap analysis of the backup ring and O-ring according to the internal pressure. Two kinds of the rubber material characteristic models were adopted to the O-ring. One was the linear elastic and the other was hyperelastic of Ogden $3^{rd}$ order model. The experimental data of urethane of Shore hardness 90 was utilized to the curve fitting of hyperelastic properties. It was found that the contact pattern of the backup ring was different in two models and the sealing mechanism was better in the case of the hyperelastic characteristic model.

Hybrid Vehicle Battery Modeling using Boundary Condition (경계조건을 반영한 하이브리드 자동차 배터리 모델링)

  • Lee, Jae-Joong;Lee, June-Sang;Bae, Hyun-Ju;Kim, Mi-Ro;Kweon, Hyck-Su;Nah, Wan-Soo
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1678-1679
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    • 2011
  • 고속/고전압으로 동작하는 자동차 전장품에 대한 EMI/EMC(Electromagnetic Interfere / Electromagnetic Compatibility) 문제는 기존의 PCB(Printed Circuit Board)에서의 문제와 다르며 하이브리드/전기 자동차에서 중요하게 다뤄지는 배터리에 대한 최적화 된 모델링 방법이 본 논문에 소개 되어있다. 기존의 단순한 저항과 커패시터의 연결로 표현 된 모델링이 아닌 고주파를 반영 할 수 있는 모델링 방법을 사용하였다. 이를 분석하기 위해 ANSYS사의 Simplorer와 Matlab을 사용해서 결과를 보았다. 본 논문에서는 DOD(Depth Of Discharge)에 따른 통합 등가회로 모델을 구현하면서 기존의 단순한 지수함수 곡선적합(Curve fitting)이 아닌 SOC(State Of Charge)의 경계조건을 반영하여 정확성을 높였다. 이로써 실험 데이터를 이용해 배터리 등가회로 모델링을 하여 정확한 배터리 동작의 해석을 할 수 있고 이에 따른 전도성 방사(CE : Conducted Emission)문제에 보다 쉽게 접근 할 수 있다.

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