• Transactions of the Korean hydrogen and new energy society
• /
• v.13 no.4
• /
• pp.259-269
• /
• 2002

A battery based on the lithium/elemental sulfur redox couple has the advantage of high theoretical specific capacity of 1,675 mAh/g-sulfur. However, Li/S battery has bad cyclic durability at room temperature due to sulfur active material loss resulting from lithium polysulfide dissolution. To improve the cycle life of Li/S battery, PEGDME (Poly(ethylene glycol) dimethyl ether) 500 containing 1M LiTFSI salt which has high viscosity was used as electrolyte to retard the polysulfide dissolution and nano-sized $Mg_{0.6}Ni_{0.4}O$ was added to sulfur cathode as additive to adsorb soluble polysulfide within sulfur cathode. From experimental results, the improvement of the capacity and cycle life of Li/S battery was observed( maximum discharge capacity : 1,185 mAh/g-sulfur, C50/C1 = 85 % ). Through the charge-discharge test, we knew that PEGDME 500 played a role of preventing incomplete charge-discharge $behavior^{1,2)$. And then, in sulfur dissolution analysis and rate capability test, we first confirmed that nano-sized $Mg_{0.6}Ni_{0.4}O$ had polysulfide adsorbing effect and catalytic effect of promoting the Li/S redox reaction. In addition, from BET surface area analysis, we also verified that it played the part of increasing the porosity of sulfur cathode.

• Journal of Korea Water Resources Association
• /
• v.38 no.12 s.161
• /
• pp.1029-1037
• /
• 2005

Urban Storm Sewer Optimal Design Model(USSOD) was developed to compute pipe capacity, pipe slope, crown elevation, excavation depth, risk and return cost in the condition of design discharge. Rational formula is adopted for design discharge and Manning's formula is used for pipe capacity. Discrete differential dynamic programming(DDDP) technique which is a kind of dynamic programming (DP) is used for optimization and first order second moment approximation method and uncertainty analysis is also for developing model. USSOD is applied to hypothetical drainage basin to test and verify. After testing the model, it is also applied to Ulsan drainage basin which was developed by Korea Land Cooperation(KOLAND). Comparing the design results of USSOD with those of KOLAND, discharge capacity 0.35 $m^3/sec$, the crown elevation is 0.77m higher and return cost is $9\%$ less than design results of KOLAND, which verify the improvement of USSOD. Layout design model using GIS and optimization including detention or retention effect are needed in the future study.

• Journal of environmental and Sanitary engineering
• /
• v.1 no.1 s.1
• /
• pp.81-96
• /
• 1986

510 random samples were studied during the months of may through November 1985 at the various industries and conclustions were made as follows; 1. $43.94\%$ of the plants studied operated their plants with semiautomatic control system, and better efficiency were observed at the plants where automatic control systems emplorid and also large industries showed more tendency adopting the automatic plant control system. 2. Overall efficiency of the treatment plants were seen much higher at the first and secand discharge class categories then the lower discharge classes, $80.79\%$ of the plants were see their daily plant operation being controlled by the operator himself. 3. The main causes of the plant stopage and in efficient discharge control were found to be malfunctioning of the plants machineries and equipment or inadequate decision made by the management to save chemicals or electricity. 4. The study showed $60\%$ of the industry treated their wastwater wholly and the rest discharged only with dilution without receiving any further treatment, and this tendency pronounced at the 4th and 5th class discharge category industries. 5. $66.17\%$ of the industry had their storage capacity to accommodate the waste discharge during plants outage while $92.67\%$ of the air pollution discharge industries had no means for the plant outage. 6. $56.77\%$ of the studied industry maintained 24 hour operation of their discharge control systems whill $18.67\%$ of air pollution discharge industries and $10.53\%$ of the waste water discharge industries showed no control effort during the night.

• Journal of the Korean Electrochemical Society
• /
• v.11 no.1
• /
• pp.47-50
• /
• 2008

A new anode composition material comprising of SiO and Graphite has been prepared by adopting High energy ball milling (HEBM) technique. The anode material shows high initial charge and discharge capacity values of 1139 and 568 mAh/g, respectively. The electrode sustains reversible discharge capacity value of 719 mAh/g at 30th cycle with a high coulombic efficiency${\sim}99%$. Since the materials formed during initial charge process the nano silicon/$Li_4SiO_3$ and $Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversibility$(Li_2O)$ will deliver higher reversible capacity. In this study, constant current-constant voltage (CC-CV) charge method was employed in place of usual constant current (CC) method in order to convert efficiently all the SiO particles which resulted high initial discharge capacity at the first cycle. We improved considerably the initial discharge specific capacity of SiO/G composite by pretreatment(CC-CV).

• Korean Journal of Materials Research
• /
• v.11 no.4
• /
• pp.294-299
• /
• 2001

Effects of the surface fluorination on the electrochemical charge-discharge properties of $Mg_2$Ni electrode in Ni-MH batteries fabricated by mechanical alloying were investigated. After 20h ball milling, Mg and Ni powder formed nanocrystalline $Mg_2$Ni. Discharge capacity of this alloy increased greatly at first one cycle, but due to the formation of Mg(OH)$_2$ passive layer, it showed a rapid degradation in alkaline solution within 10cyc1es. In case of 6N KOH +xN KF electrolyte (x = 0.5, 1, 2), a continuous and stable fluorinated layer formed by adding excess F$^{[-10]}$ ion, increased durability of $Mg_2$Ni electrode greatly and high rate discharge capability(90-100mAh/g). 2N KF addition led to the highest durability of all tested here. The reason of the improvement is due to thin MgF$_2$, which can prevent the $Mg_2$Ni electrode from forming Mg(OH)$_2$layer that is the main cause of degradation.

• Korean Chemical Engineering Research
• /
• v.61 no.1
• /
• pp.39-44
• /
• 2023

In this study, the particle size of Si polycrystals was controlled through wet-sedimentation method, and changes in the capacity and cyclic characteristics of the Si anode material according to the particle size were observed. After wet-sedimentation of Si particles pulverized by a vibration mill, the non-uniform particle distribution of Si was uniformly controlled. The d₅₀ of a sample in which Si was sedimented for 24 hours decreased to 0.50 ㎛. As a result of the electrochemical characteristic analysis, the Rct value representing the resistance in the electrode was significantly reduced due to the decrease in particle size. The unclassified Si sample exhibited a discharge capacity of 2,869 mAh/g in the first cycle, and decreased to 85.7 mAh/g after 100 cycles. The sample in which Si was classified for 24 hours showed a capacity of 3,394 mAh/g initially, and maintained a capacity of 1,726 mAh/g after 100 cycles. As the size of the Si particles decreased, the discharge capacity increased and the cycle life was also increased.

• Korean Journal of Community Nutrition
• /
• v.26 no.6
• /
• pp.455-466
• /
• 2021

Objectives: The purpose of this study was to investigate the effects of internal and external capacity on the practical capacity for food waste disposal in adults. Methods: The study subjects were 410 adults who answered a structured questionnaire. The survey was conducted in January 2021. Data were analyzed through descriprive analysis, t-test, ANOVA, and multiple regression analysis using the SPSS Win 24.0. Results: First, in the analysis of internal capacity, attitude (3.95 out of 5 points) scored higher than knowledge (3.59 points). Attitudes showed significant differences according to gender (P < 0.001), age (P < 0.001), and income (P < 0.001). Knowledge showed significant differences according to gender (P < 0.01) and age (P < 0.05). Second, in the analysis of capacity, market constraints (3.73 points) scored the highest, followed by institutional conditions (3.48 points) and reference group (3.36 points). Market constraints differed according to gender (P < 0.001), and institutional conditions differed according to income (P < 0.001). There was a significant difference in the reference group according to the level of education (P < 0.05) and income (P < 0.05). Third, the practical capacity scores appeared in the order of separating discharge behavior, using behavior, purchasing behavior, and leadership behavior. Separating discharge behavior showed significant differences according to gender (P < 0.001), education level (P < 0.05), and income (P < 0.01). Using behavior showed a difference according to gender (P < 0.01), and purchasing behavior showed a significant difference according to income (P < 0.05). Leadership behavior showed no difference according to demographic factors. Fourth, internal capacity and external capacity showed a significant positive relationship with practical capacity. Factors affecting purchasing behavior were knowledge, attitude, institutional conditions, and reference group, and their explanatory power was 53%. Factors influencing using behavior were knowledge, attitude, institutional conditions, and reference group, and had an explanatory power of 37%. Leadership behavior was influenced by institutional conditions and the reference group, with an explanatory power of 31%. Conclusions: Internal capacity, external capacity, and practical capacity show differences according to demographic factors. Factors influencing the practical capacity of adults were knowledge, attitude, institutional conditions, and reference group.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.19 no.1
• /
• pp.19-27
• /
• 2007

Analytical investigation on the performance of a two stage twin rotary compressor for $CO_2$ heat pump water heater system has been carried out. A computer simulation program was made based on analytical models for gas compression in control volumes, leakages among neighboring volumes, and dynamics of moving elements of the compressor. Calculated cooling capacity, compressor input, and COP were well compared to those of experiments over the compressor speeds tested. For the operating condition of suction pressure of 3 MPa, and discharge pressure of 9 MPa, and compressor inlet temperature of $35^{\circ}C$, the compressor efficiency was calculated to be 80.2%: volumetric, adiabatic, and mechanical efficiencies were 88.3%, 93.2%, and 92.7%, respectively. For the present compressor model, volumetric and adiabatic efficiencies of the second stage cylinder were lower by about $6{\sim}7%$ than those of the first stage mainly due to the smaller discharge port at the second stage. Parametric study on the discharge port size showed that the compressor performance could be improved by 3.5% just by increasing the discharge port diameter by 20%.

• Korean Journal of Materials Research
• /
• v.5 no.1
• /
• pp.112-122
• /
• 1995

Metal hydride alloys of TiFe based system have been produced by mechanical alloying(MA) method and their electrochemical characteristics have been evaluated for application for Ni/MH battery electrode. These alloys became amorphous after 36hrs ball milling and easily activated electrochemically. All MA amorphous alloys reached at the first charge/discharge cycle the maximum capacity which was 2-3 times higher than the crystalline state. But their cyclic lives were much inferior to the crystalline state. Alloying elements such as Ni, Co, Cr, Mo substituting Fe greatly improved the capacity and 180 mAh/g capacity was obtained in an alloy of TiFe_{0.6}Ni_{0.1}Co_{0.1}Cr_{0.1}Mo_{0.1}$.

• Korean Journal of Materials Research
• /
• v.12 no.4
• /
• pp.240-247
• /
• 2002

Tin oxide thin films doped with silicon as anodes for lithium secondary battery were fabricated by R.F. magnetron sputtering technique. The electrochemical results showed that the irreversible capacity was reduced during the first discharge/charge cycle, because the audition of silicon decreased the oxidic state of Tin. Capacity was increased with the increase of substrate temperature, however decreased with the increase of RTA temperatures. The reversible capacity of thin films fabricated under the substrate temperature of $300^{\circ}C$ and the Ar:$O_2$ratio of 7:3 was 700mA/g.