• Title/Summary/Keyword: Fire- and explosion safety

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Risk Research on Chemical Product Styrene Monomer Shipped in a Vessel (선박적재 화학물 Styrene Monomer의 위해성 조사)

  • Park, Seung-Ho;Kim, Dae-Jeong;Yim, Jeong-Bin
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2019.11a
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    • pp.268-268
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    • 2019
  • The purpose of this study is to understand the risk of chemical product, Styrene Monomer(SM), shipped in a vessel. SM is harmful chemical product which can make injury, explosion and/or fire in a vessel. The understand of SM risk is very important to protect seafarer's body and vessel safety. This research can be expected that the understanding of SM risk by a seafarer's to prevent accidents by SM explosion and/or fire.

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Design for a Fuse Element of Sub-miniature Fuse with High Breaking Capacity Characteristics (높은 차단용량 특성을 갖는 초소형 미니어처 퓨즈의 가용체 설계)

  • Ahn, Chang Hwan
    • Journal of the Institute of Electronics and Information Engineers
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    • v.54 no.3
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    • pp.131-137
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    • 2017
  • In order to safely protect high over current flowing into the main circuit at short-circuit without any explosion or fire, the enclosed cartridge fuse with a high interrupting capacity should be applied. But this fuse is impossible to be applied to an inner electronic circuit because of a limited space problem result from the miniaturization trend of products. Therefore, it is necessary to apply a sub-miniature fuse with a relatively small size. However the semi-enclosed fuse which is more free for an influx of air than the enclosed cartridge fuse and is possible to protect fuse elements with chemical and physical combination can be adoptable. But it has a limit of implementing the characteristic of a high breaking capacity. For these reasons, the Fe-42wt%Ni fuse elements alloy and fuse-link with less space were designed to increase a breaking capacity of sub-miniature fuse and its safety for fire and explosion was confirmed in this paper.

Minimum Autoignition Temperature Behavior(MAITB) of the Flammable Binary Systems (가연성 이성분계의 최소자연발화온도 거동(MAITB))

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.70-75
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    • 2008
  • The values of the AIT(Autoignition temperature) for fire and explosion protection are normally the lowest reported. The minimum autoignition temperature behavior(MAITB) of flammable liquid mixtures is exhibited when the AIT of mixture is below the AIT of the individual components. The MAITB is an interesting experimental features, which can be significant from the perspective of industrial safety. In this study, the AITs of m-xylene+n-butyric acid and ethylbenzene+n-butanol systems were measured using ASTM E659-78 apparatus. The AITs of m-xylene, n-butyric acid, ethylbenzene and n-butanol which constituted two binary systems were $587^{\circ}C$, $510^{\circ}C$, $475^{\circ}C$ and $340^{\circ}C$ respectively. The m-xylene+n-butyric acid system is exhibited MAITB at 0.3 mole fraction of m-xylene, and its minimum autoignition temperature was $460^{\circ}C$.

CFD-based Fire Accident Impact Analysis in Clean Room for semiconductor PR Process (반도체 PR 공정의 클린룸내 CFD 기반 화재 사고 영향 분석)

  • Chun, Kwang-Su;Yi, Jinseok;Park, Myeongnam
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.35-44
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    • 2021
  • The PR (Photo Resist) process in the semiconductor process is a process that uses a mixture of flammable substances. Due to the process equipment is installed in a clean room and when flammable substances leak, there is a high risk of suffocation, fire, and explosion. It is necessary to analyze the impact of accidents that may occur during operation and to evaluate whether the safety of workers can be guaranteed. In this study, the value of radiant heat and temperature change at the monitor point set up virtual inside the clean room was confirmed through CFD simulation of 10 leak and fire scenarios using the FLACS CFD - Fire Module. A fire that occurs inside a clean room transfers high radiant heat to the inter-story structure, but its scope is quite limited, and it is unlikely that it will collapse in a single fire accident. There was no scenario in which two stairs leading to the exit were exposed to high radiant heat at the same time due to a fire accident, therefore workers were able to escape in case of a fire. In addition, it was confirmed that the level of radiant heat and temperature rise rapidly decreased as they moved downstairs. According to the API 520 standard, workers exposed to 6.31 kW/m2 of radiant heat that workers can withstand for 30 seconds were confirmed that it was possible to sufficiently escape from the inside.

A Study on the Installation of Rupture Disk for Emergency Discharge of Dangerous Substances in Case of Styrene Monomer Runaway Reaction (스티렌모노머 폭주반응 시 위험물 비상 배출을 위한 파열판 적정 크기 선정에 관한 연구)

  • Sang Ryung Kim;Jae Min Ryu;Hyang Nam Choi;Jong Su Hyun;Hyung Sik Byun
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.24-31
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    • 2024
  • In the chemical industry, fires and explosions constantly occur due to runaway reactions during the production of various chemical products. To prevent this, much research has been conducted, and the possibility of runaway reactions for each substance is reviewed and interlocking devices are installed to prepare for adverse reactions to prepare for fires and explosions. However, despite legal and technical safety measures, accidents due to runaway reactions still occur every year. Accordingly, in this study, based on cases of fire and explosion accidents in styrene monomer reactors, the discharge capacity during runaway reactions was examined through experiments and graphs. Unlike the commonly calculated fire equation, in the case of a runaway reaction where pressure and temperature increase rapidly, discharge is made in two phases rather than a single phase, so the size of the rupture disk must also increase, and the orientation must be adjusted before the rupture disk is installed at the top of the pressure vessel. It was found that position adjustment was necessary.

A Study on the Selection of Hydrogen Refueling Station Locations within Military Bases Considering Minimum Safe Distances between Adjacent Buildings (인접 건물 간 최소 안전거리를 고려한 군부대 내 수소충전소 위치선정 연구)

  • Dong-Yeon Kim;Hyuk-Jin Kwon
    • Journal of Internet Computing and Services
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    • v.24 no.6
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    • pp.171-180
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    • 2023
  • Hydrogen energy technology is gaining importance in the era of the Fourth Industrial Revolution, offering military advantages when applied to military vehicles due to its characteristics such as reduced greenhouse gas emissions, noise, and low vibration. Korea's military has initiated the Army Tiger 4.0 plan, focusing on hydrogen application, downsizing, and AI-based smart features. The Ministry of National Defense plans to collaborate with the Ministry of Environment to expand hydrogen charging stations nationwide, anticipating increased deployment of military hydrogen vehicles. However, considering the Jet Fire and VCE(Vapor Cloud Explosion) nature of hydrogen, ensuring safety during installation is crucial. Current military guidelines specify a minimum safety distance of 2m from adjacent buildings for charging stations. Scientific methods have been employed to quantitatively assess the accident damage range of hydrogen, proposing a minimum safety distance beyond the affected area.

Reliability Analysis on Safety Instrumented System by Using Safety Integrity Level for Fire.Explosion Prevention in the Ethyl Benzene Processes (Ethyl Benzene 공정에서 화재.폭발방지를 위하여 안전건전성수준을 이용한 안전장치시스템의 신뢰도 분석)

  • Ko, Jae-Sun;Kim, Hyo;Lee, Su-Kyoung
    • Fire Science and Engineering
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    • v.20 no.3 s.63
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    • pp.1-8
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    • 2006
  • The purpose of this work is to analyze quantitatively if the safety instrumented system(SIS) like the pressure safety valves(PSV) in the processes of ethyl benzene plant have been designed relevantly to the safety integrity level because overpressure in the benzene or ethyl benzene columns causes the explosive reactions, fires and reactor explosions. The safety integrity level(SIL) 3 has been adopted as a target level of SIS based on the general data of the Probability of Failure on Demand of PSV, $1.00E-4{\sim}1.00E-3$. The standard model of the reliability has been set up and then the fault tree analysis of it has been carried out to get the PFD of SIS, and the results show 8.97E-04, 5.37E-04, 5.37E-04 for benzene prefractionator column, benzene column and EB column, respectively. Thus, we conclude that the SIS is designed to fulfill the condition of SIL3, and when the partial stroke test for the control valve are carried out every sixth month, the SIS of each column is expected to increase its reliability up to $22{\sim}27%$.

Development and Use of Data for Chemical Risk Assessment (화학물질 유해성 평가를 위한 정보의 작성 및 활용)

  • Rim, Kyung-Taek;Kim, Hyun-Ok;Kim, Young-Kyo;Cho, Hae-Won;Ma, Yong-Seok;Lee, Kwon-Seob;Lim, Cheol-Hong;Kim, Hyeon-Yeong;Yang, Jeong-Seon
    • Environmental Analysis Health and Toxicology
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    • v.22 no.1 s.56
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    • pp.91-101
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    • 2007
  • The new chemicals are developed and circulated without the verified toxicity data. So, the accidents and occupational diseases, such as explosion, fire, suffocation about deadly poisons etc. are frequently to workers. Classifications of chemicals suited with guideline and an offer of correct chemical information data are the molt important thing for the establishment of suitable chemical management system. The GHS (Globally Harmonized System of classification and labeling of chemicals) is based with the chemical classifications and unification plan. The warning symbol and phrases are established for improvements of chemical information data system. According to these unified and improved systematic form of data, and the chemical information data, the workplaces will be presented many chemical safety and risk data correctly. In this paper, we will present constructions and accomplishment contents-based chemical management of workplace through development of chemical information data and the nice using for new chemical investigation and risk assessment of chemicals in workplaces.

The Measurement and Prediction of Flash Point for Binary Mixtures of Methanol, Ethanol, 2-Propanol and 1-Butanol at 101.3 kPa (Methanol, Ethanol, 2-Propanol 그리고 1-Butanol 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정 및 예측)

  • Oh, In Seok;In, Se Jin
    • Fire Science and Engineering
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    • v.29 no.5
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    • pp.1-6
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    • 2015
  • Flash point is one of the most important variables used to characterize fire and explosion hazard of liquids. The lower flash point data were measured for the binary systems {methanol + 1-butanol}, {ethanol + 1-butanol} and {2-propanol + 1-butanol} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The measured FP data agreed well with the predicted values of Raoult's law, Wilson, NRTL and UNIQUAC models. The average absolute deviation between the predicted and measured lower FP was less than 1.14 K.

Risk Analysis for Installation Types of Pressure Safety Valve used in the High-pressure Gas Facility (고압가스 사용시설 내 안전밸브 설치유형별 리스크 분석)

  • Kim, Myung-Chul;Woo, Jeong-Jae;Lee, Hyung-Sub;Baek, Jong-Bae
    • Journal of the Korean Society of Safety
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    • v.32 no.4
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    • pp.129-136
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    • 2017
  • This study investigated the probability of possible accident through qualitative and quantitative analysis of the pressure safety valve types installed in facilities using high pressure gas to compare the installation domestic and foreign pressure safety valve standards sought the safety characteristics and safety improvement direction accordingly. The three types are the case where the shut-off valve is not installed at the front of the PSV (Case A), If a shut-off valve is installed at the front of the PSV for inspection (Case B) and If a shut-off valve is installed in front of PSV (C.S.O), PSV is installed in parallel (Case C). Three types of cases were compared with FTA and HAZOP. The results of study of the possible accidents due to over-pressure safety valve installation type, used in a high-pressure gas facilities was shows in the following order Case B > Case A > Case C. The results of analysis through FTA was in order to protect the reservoir for the possible occurring of accident the safety valve installation is depend on its type. In the FTA analysis, defects in the device itself which attached to the storage tank as a substitute for analysis of the probability of operator mistakes was Case B with as high as $2.01{\times}10^{-6}$. Depending on the type of installation analysis of Case B in order to ensure safety is prohibited to install shut-off valve and believes that mandatory regulations are needed. Rationally installing of pressure safety valve in the high pressure using facilities will be expected to improve the industrial safety from severe accidents such as high-pressure gas fire explosion.