Microstructures and chemistry of anorthoclase, a high-temperature phase of alkali feldspars, were studied using EPMA and TEM. BSE images of anorthoclase displayed mixtures of Na-rich areas and K-rich areas forming lamella of various sizes. EPMA analysis indicated that the Na-rich area is composed of Ab: 81%, Or: 3% and An: 11% in average, while the K-rich area is composed of Ab: 45%, Or: 44% and An: 11 % in average. TEM analysis revealed albite with Albite twins in the Na-rich area, contrasting to mixtures of albite with fine Albite twins and orthoclase without twins, forming regular lamella of about 100 nm sizes, in the K-rich area. The [001] electron diffraction pattern of the K-rich area also indicated coexistence of the two phases. While streaking parallel to the (010)$^{*}$ direction appeared only in albite due to the twin structure, streaking parallel to the $(100)^{ *}$ direction appeared both in albite and orthoclase, probably due to strain on the interface as well as order-disorder phenomena of Al and Si. It is suggested that the reverse orientation of albite and orthoclase is caused by pole switching to reduce strain on their interfaces. Based on these observations and analyses, the mineral studied is identified as lower-temperature cryptoperthite rather than high-temperature anorthoclase, which has a midium degree of Al-Si ordering and $400^{\circ}C$∼$600^{\circ}C$ of estimated temperatures for the microstructure formation.
This experiment was carried out to investigate the growth and yield responses of hydroponically grown tomato as affected by the different substrates using perlite and mixtures with perlite. Substrates used in this experiment were perlite (fine and coarse granule), peatmoss, rice hull and carbonized rice hull. The results obtained were as follows ; The best results in terms of total fruit yield and average fruit weight obtained in the single treatment of perlite, followed by perlite mixture with rice hull and carbonized rice hull. Leaf area was also higher in the plots of perlite mixture and optimum mixing ratio of perlite, peatmoss and carbonized rice hull was determined as 5:3:2 by volume. The more the rice hull was added to the mixed substrates, the less in fruit production was observed. However, adding perlite to other substrates brought higher fruit yield. Single treatment of rice hull showed the lowest fruit yield but enhanced in soluble solids contents over 6.0 $^{\circ}$Brix at each cluster.
Magazine of the Korean Society of Agricultural Engineers
/
v.27
no.2
/
pp.57-71
/
1985
The characteristics of compaction and unconfined compressive strength were investigated by mixing with lime to all soils adjusted by given percentages of two kinds of clays to sand to obtain the most effective distribution of grain size and the optimum lime content for soil stabilization. In addition, unconfined compressive strength and durability tested by adding of sodium metasilicate, sodium sulfate, sodium carbonate, sodium gydroxide and magnesium oxide to lime-soil mixture mixed with 8 percent lime to adjusted soil having the mixing percentage of 60 percent of cohesive black clay and 40 percent of sand by weight to get the effect and the optimum content of chemicals. The results obtained were as follows; 1.With the addition of more lime, the optimum moisture content was increased, and the maximum dry density was decreased, whereas the more the amount of clay and the less was the maximum drt density. 2. In the soil having more fine grain size the unconfined compressive strength was larger in the earlier stage of curing period, in accordance with the longer period, the mixing percentages of sand to clay showing the maximum unconfined compressive strength, on the basis of 28-day strength, were 60% : 40% (black clay) and 40% : 60% (brown clay) respectively. 3. The reason why the soil adjusted with black clay was remarkably bigger in the unconfined compressive strength than ones adjusted with brown clay for all specimen of lime-soil mixture was the difference in the kind of clay, the amount of chemical compositions the value of pH. Black clay was mainly composed of halloysite that reacted with lime satisfactorily, whereas the main composition of brown clay was kaolinite that was less effect in the enhance of unconfined compressive strength. Also the difference of unconfined compressive strength was because black clay was larger in the amount of composition of calcium oxide and magnesium oxide in the value of pH affecting directly on the unconfined compressive strength of lime-soil mixture than brown clay. 4. In the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40%, on the standard of 7-day strength, the effect of chemical was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium hydroxide and sodium metasilicate. 5. The optimum amount of chemical being applicable to the maximum unconfined compressive strength of lime-chemical-soil mixture was 1 percent by weight for air dry soil in the case of adding sodium carbonated and 0.75 percent on sodium hydroxide, the unconfined compressive strength was increased continuously with increase of the amount of chemical up to 2 percent of chemical content is the lime-chemical-soil mixture added sodium metasilicate, sodium sulfate and magnesium oxide. 6. It was considered that the chemical played and accelerant role of early revelation of strength because the rate of increase of unconfined compressive strength of all of lime-chemical-soil mixtures was largest on the 7-day cured specimen. 7. The effect of test on freezing and thawing after adding suitable amount of chemical on the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40% was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium metasilicate and sodium hydroxide.
Magazine of the Korean Society of Agricultural Engineers
/
v.28
no.4
/
pp.66-76
/
1986
This study was attempted to investigate the effects of delayed compaction on the unconfined compressive strengh and dry density of Soil-cement mixtures. Soil-cement construction is a time-consuming procedure. Time-delay is known as a detrimental factor to lower the quality of soil-cement layer. A laboratory test was performed using coarse and fine weathered granite soils. The soils were mixed with 7% cement at optimum moisture content and excess moisture content in part. Socondary additives such as lime, gypsum-plaster, flyash and sugar were tried to counteract the detri-mental effect of delayed compaction. The specimens were compacted by Harvard Miniature Compaction Apparatus at 0,1,2,4,6 hors after mixing. Two kinds of compactive efforts(9 kgf and 18 kgf tamper) were applied. The results were summarized as follows: 1.With the increase of time delay, the decrease rate of dry density of the specimen compacted by 9 kgf tamper was steeper than that of the specimen compacted by 18kgf tamper. In the same manner, soil-B had steeper decreasing rate of dry density than soil-A. 2.Based on the results of delayed compaction tests, the dry density and unconfined compressive sterngth were rapidly decreased in the early 2 hours delay, while those were slowly decreased during the time delay of 2 to 6 hours. 3.The dry density and unconfined compressive strength were increased by addition of 3% excess water to the optimum moisture content during the time delay of 2 to 6 hours. 4.Without time delay in compaction, the dry densities of soil-A were increased by adding secondary additives such as lime, gypsum-plaster, flyash and sugar, on the other hand, those of soil-B were decreased except for the case of sugar. 5.The use of secondary additives like lime, gypsum-plaster, flyash and sugar could reduce the decrease of unconfined compressive strength due to delayed compaction. Among them, lime was the most effective. 6.From the above mentioned results, several recommendations could be suggested in order to compensate for losses of unconfined compressive strenght and densit v due to delayed compaction. They are a) to use coarse-grained granite soil rather than fined-grained one, b) to add about 3% excess compaction moisture content, c) to increase compactive effort to a certain degree, and d) to use secondary additives like line gypsum-plaster, flyash, and sugar in proper quantity depending on the soil types.
Kwon, Woo Teck;Kim, Soo Ryong;Kim, Younghee;Lee, Yoon Joo;Kim, Jong Il;Lee, Hyun Jae;Oh, Sea Cheon
Resources Recycling
/
v.22
no.3
/
pp.28-35
/
2013
The recycling of the Si/SiC mixture sludge obtained from solar cell industry is very significant, environmentally and economically. The sintering characteristics of Si/SiC mixture sludge was studied for the purpose of recycling. In this study, to understand sintering behavior, SiC content in the Si/SiC mixture was controlled using an air separator. Various Si/SiC mixtures having different SiC contents were sintered using carbon black, clay and aluminum hydroxide as sintering aids. Physical properties of Si/SiC mixture and sintered bodies have been characterized using SEM, XRD, particle size analyzer and apparent density measurement. SEM and particle size analysis result confirmed that the fine particles less than 1 ${\mu}m$ decreased or removed more effectively through the air separator in the case of 95% SiC sample compared than the case of 75% SiC sample or original SiC sample. Further, with addition of the Aluminum Hydroxide, ${\beta}$-cristobalite phase gradually decreased while mullite phase gradually increased. The addition of the carbon black improved the sintering characteristics.
The strength of granular mixtures can be controlled by the majority of the mixture, fine grains. However, in some cases, the small amount of gravel in the mixture may influence the strength of the mixture. In this study, the effect of some dispersed gravels on strength of sand is evaluated. Gravels are embedded in the middle of each cemented sand layer. The size and number of embedded gravels varies. After two days curing, a series of unconfined compression tests is performed on the cemented sand with dispersed gravels. In addition to that, a series of direct shear tests is also carried out on clean sand with gravels to evaluate its friction angle. For the specimens with the same ratio of gravel weight of 7% in which gravel size and number are different, an unconfined compressive strength(UCS) of a specimen with gravels decreases up to 15% compared to a specimen without gravel and then increases with increasing gravel number. For specimens embedded with the same size of gravel, UCS decreases and then increases as a number of gravel increases. As a number of gravel increases, a friction angle of clean sand with gravels decreases up to $5^{\circ}$ and then recovers up to that of a specimen without gravel.
KSCE Journal of Civil and Environmental Engineering Research
/
v.30
no.5C
/
pp.209-218
/
2010
In residual soils, large particles such as rock fragments or gravel are surrounded by sand or clay. The strength of such granular mixtures can be controlled by the concentration of fine or coarse grains. The percentage by weight, size or shape of gravel in the mixture that can control the strength of the mixture has not been clearly determined for various granular mixtures. In this study, the effect of dispersed gravels on the shear characteristics of sand was evaluated. Large and small gravels were inserted in the middle of each layer with moist Nakdong River sand and compacted into a cylindrical sample with five equal layers. Embedded gravel ratios by weight were 0, 3, 9, and 14%. After consolidation, a series of undrained triaxial compression tests was performed on Nakdong River sand with dispersed gravels. Maximum deviator stresses of the Nakdong River sand with large gravels decrease up to 38% as a percentage of embedded gravels increases. Such strength degradation decreases as a confining pressure increases. The maximum deviator stress increases as the percentage by weight of small gravel increases; at 3 or 9% of gravel weight it slightly increases but at 14% of gravel weight it increases up to 34%.
Journal of the Korean Recycled Construction Resources Institute
/
v.11
no.4
/
pp.425-432
/
2023
In this study, we aim to develop a carbon-reducing concrete technology by incorporating biochar. Performance evaluation experiments were conducted on concrete mixtures containing biochar with insulating and carbon-capturing properties, which are essential for key infrastructure sectors such as construction and tunnels. Concrete mixtures were designed with different biochar incorporation rates of 0 %, 5 %, 10 %, 15 %, and 20 %, as w ell as w ater-to-binder ratios of 0.25, 0.30, 0.35, and 0.40. To assess the physical properties of each mixture, unit weight, total porosity, and permeability were measured, while mechanical properties were determined through the measurement of concrete compressive and flexural strengths. Key factors for enhancing the insulating effect of carbon-reducing concrete containing biochar were identified through regression analysis, indicating a close correlation among biochar incorporation rate, unit weight, concrete strength, and thermal conductivity. It is anticipated that it can be utilized as an insulating material to enhance thermal performance in northern regions with severe winter climates.
$YBa_2Cu_3O_{6+x}(Y123)-Ag$ high-Tc superconducting wires were fabricated by plastic extrusion technique using pyrophoric synthetic and mechanical mixing powder with and without Ag addition(20 wt.%). This method involves powder preparation, plastic paste making, die extrusion, binder burn-out and the sintering process. In order to fabricate a good-quality superconducting body, it is required to use homogeneous and fine-size power as a starting materials. $Y_2O_3-BaCO_3-CuO$ precursor powders with/without Ag addition were prepared both by pyrophoric synthetic(PS) and mechanical mixing(MM) method of raw powders. The formation kinetics of the powder mixtures into Y123 phase was investigated at various temperatures and times in air atmosphere. The powder prepared by PS method was more easily converted into a Y123 phase than the MM powder. The fine size and good chemical homogeneity of the powder prepared by PS method is attributable to the fast formation into a Y123 phase. The critical current density($J_c$) of the Y123-Ag superconducting wires made by plastic extrusion method were in the range of $150A/cm^2{\sim}230A/cm^2$. depending on the charateristics of starting material powders. $J_c$ of the wire prepared by pyrophoric synthetic powder with 20 wt.% Ag addition was $230A/cm^2$.
Proceedings of the Korea Concrete Institute Conference
/
2008.11a
/
pp.641-644
/
2008
This paper investigated the plant and raw material of the ready-mixed concrete company which could supply to the second Lotte World on Pusan. the results were summarized as following. Almost plants were mainly using Twin shaft mixer which was 210m$^3$/hr and horizontal type. There was different the number of admixture silos at each plants, and they were separated by types. The mixtures mainly consisted of the ordinary portland cement, fly ash and blast furnace slag. For favorable quality control, each materials had to carry from same factories, and the monitering standard for quality control should be prepared. The coarse aggregates were used with many different producing districts, so they were only used from Y caused by exclusion of quality difference. The crushed, washed and river sands were generally used as fine aggregates, so the fine aggregates which could be possible to supply stable quality were chosen. This study used Poly Carbonic Acid Admixture which was developed to satisfy maintenance of performance till 2 hours and 10MPa at 15 hours.
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