• Title/Summary/Keyword: Fine dominant

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Analysis of Trace Copper Metal at The Electrode Consisting of Carbon Nanotube using Stripping Voltammetry (벗김전압전류법을 이용한 카본나노튜브 전극에서의 구리 분석)

  • Choi, Chang-Kun;Jung, Young-Sam;Kim, Nack-Joo;Pak, Dae-Won;Chung, Kun-Yong;Kim, Lae-Hyun;Kwon, Yong-Chai
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.933-937
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    • 2012
  • In the present study, we evaluate the sensitivity and optimal stripping voltammetry (SV) conditions of copper (Cu), which is one of the main trace heavy metals inducing the environmental contamination, using carbon nanotube (CNT) electrode. In addition, the reaction mechanism of stripping reaction of Cu is investigated. The electrochemical analyses such as squarewave stripping voltammetry (SWSV) and linear scan voltammetry (LSV) are used for the evaluations. As a result of that, the best SWSV conditions like squarewave amplitude of 15 mV, frequency of 60 Hz, deposition potential of -1.0V vs. Ag/AgCl and deposition time of 200s are determined with the measured Cu sensitivity of $1.824{\mu}A/{\mu}M$. As a driving force affecting the stripping reaction of Cu, surface reaction is more dominant one than diffusion. These results are compared with other reference results and it is confirmed that our suggested CNT electrode gives rise to better Cu sensitivity result than other references.

Chemical and Mineralogical Properties of Two Low-Humic Gley Soils of Korea (우리나라 Low-Humic Gley Soil의 이화학적(理化學的) 및 광물학적(鑛物學的) 특성(特性)에 관(關)한 연구)

  • Dewan, H.C.;Han, K.H.;Lee, Y.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.1 no.1
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    • pp.129-136
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    • 1968
  • Low-Humic Gley Soils occur very commonly in Korea and constitute important paddy soils of the country. These soils are developed either on alluvial or fluvio-marine materials. The soils in the present invest igation are derived from the latter. The interesting morphological features of these two soils are the presence of $FeCO_3$ concretions in the subsoil and the occurrence of a buried black organic horizon of variable thickness(25-100 cm). The organic horizon overlies the greenish marine material and underlies the continental material. These soils have poor drainage and are wet most of the year. The presence of $FeCO_3$ concretions in poorly drained paddy soils has previously been reported in North America(8), Japan(9) and West Europe(7). The purpose of this investigation is to study the chemical and mineralogical characteristics of these soils; and the genesis of $FeCO_3$ concretions. Profile samples of both these soils were collected from Gimjae area, in co-operation with the Soil Survey Party. These profiles were described as follows:

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Sedimentologic Linkage of depositional environments of Han River and Kyunggi Bay, Korea (한강 유역과 경기만 퇴적환경의 연계성)

  • 오재경;방기영
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.3
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    • pp.225-236
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    • 2003
  • In order to understand the relationship of depositional environment between fluvial and estuarine-embayment in Han River system, including depositional change in main Han River, more than 250 bottom sediment and 70 suspended sediment were analyzed with hydrologic data. Based on the previous data, the study area can be divided into two environment(fluvial and estuarine-embayment) by Singok underwater dam. The gravelly facies occurs in the South and North Han Rivers and sandy and silty facies occupies in the main Han River. Depositional environment of main Han River changed mainly because of limited sediment transport and hydrological condition. In the estuarine-embayment environment, coarse-grained sediments are dominant in tidal channel and of shore whereas fine and poorly sorted sediments are observed in coastal area. During moderate period, relationship between fluvial-estuarine-embayment system is discontinuou s because of flow restriction by artificial construction such as dam and underwater dam, so that each river system characterizes the individual environment. Fluvial and estuarine system is influenced by tide and, thus, transition zone of estuarine- embayment system moves landward. During flooding period, however, each river system is integrated as continuous depositional system by high discharge and, thus, transition zone of fluvial-estuarine-embayment system moves seaward. For further detailed systems about the lower Singok under-water dam, joint research of South-North Korea should be necessary.

Environmental Characteristics of Natural Habitat of Protothaca jedoensis in Gamak Bay, Korea (가막만 살조개, Protothaca jedoensis 서식지 환경특성)

  • Yoon, Ho-Seop;Choir, Sang-Duk
    • Journal of Aquaculture
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    • v.19 no.1
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    • pp.7-13
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    • 2006
  • In this study, environmental parameters of natural habitat were measured to find out suitable place for release and improve the productivity of Protothaca jedoensis in Gamak Bay. Water temperature, salinity of the habitat ranged from 5.4 to 27.6 and from 26.5 to $34.5\%_{\circ}$, respectively. Range of pH, DO, COD, Chl-a, T-N and T-P were $7.82{\sim}8.39,\;5.31{\sim}11.28mg/L,\;0.13{\sim}1.38mg/L,\;3.05{\sim}11.55mg/L,\;0.005{\sim}0.180mg/L\;and\;0.007{\sim}0.028mg/L$ respectively. Dominant grain size was fine silt and the IL of sediment was ranged from $0.75{\sim}7.26%$. The water content was $20.16{\sim}53.65%$ and highest value was observed in Baegyado. The COD and AVS in the sediments ranged from $0.53{\sim}8.67mg/g-dry$ and $0.002{\sim}0.113mg/g-dry$ respectively. The bottom condition of Baegyado was higher than other area.

Study on the Applicability of High Frequency Seismic Reflection Method to the Inspection of Tunnel Lining Structures - Physical Modeling Approach - (터널 지보구조 진단을 위한 고주파수 탄성파 반사법의 응용성 연구 - 모형 실험을 중심으로 -)

  • Kim, Jung-Yul;Kim, Yoo-Sung;Shin, Yong-Suk;Hyun, Hye-Ja;Jung, Hyun-Key
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.2 no.3
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    • pp.37-45
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    • 2000
  • In recent years two reflection methods, i.e. GPR and seismic Impact-Echo, are usually performed to obtain the information about tunnel lining structures composed of concrete lining, shotcrete, water barrier, and voids at the back of lining. However, they do not lead to a desirable resolution sufficient for the inspection of tunnel safety, due to many problems of interest including primarily (1) inner thin layers of lining structure itself in comparison with the wavelength of source wavelets, (2) dominant unwanted surface wave arrivals, (3) inadequate measuring strategy. In this sense, seismic physical modeling is a useful tool, with the use of the full information about the known physical model, to handle such problems, especially to study problems of wave propagation in such fine structures that are not amenable to theory and field works as well. Thus, this paper deals with various results of seismic physical modeling to enable to show a possibility of detecting the inner layer boundaries of tunnel lining structures. To this end, a physical model analogous to a lining structure was built up, measured and processed in the same way as performed in regular reflection surveys. The evaluated seismic section gives a clear picture of the lining structure, that will open up more consistent direction of research into the development of an efficient measuring and processing technology.

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Observation of Secondary Organic Aerosol and New Particle Formation at a Remote Site in Baengnyeong Island, Korea

  • Choi, Jinsoo;Choi, Yongjoo;Ahn, Junyoung;Park, Jinsoo;Oh, Jun;Lee, Gangwoong;Park, Taehyun;Park, Gyutae;Owen, Jeffrey S.;Lee, Taehyoung
    • Asian Journal of Atmospheric Environment
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    • v.11 no.4
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    • pp.300-312
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    • 2017
  • To improve the understanding of secondary organic aerosol (SOA) formation from the photo-oxidation of anthropogenic and biogenic precursors at the regional background station on Baengnyeong Island, Korea, gas phase and aerosol chemistries were investigated using the Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-ToF-MS) and the Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS), respectively. HR-ToF-AMS measured fine particles ($PM_1$; diameter of particle matter less than $1{\mu}m$) at a 6-minute time resolution from February to November 2012, while PTR-ToF-MS was deployed during an intensive period from September 21 to 29, 2012. The one-minute time-resolution and high mass resolution (up to $4000m{\Delta}m^{-1}$) data from the PTR-ToF-MS provided the basis for calculations of the concentrations of anthropogenic and biogenic volatile organic compounds (BVOCs) including oxygenated VOCs (OVOCs). The dominant BVOCs from the site are isoprene (0.23 ppb), dimethyl sulphide (DMS, 0.20 ppb), and monoterpenes (0.38 ppb). Toluene (0.45 ppb) and benzene (0.32 ppb) accounted for the majority of anthropogenic VOCs (AVOCs). OVOCs including acetone (3.98 ppb), acetaldehyde (2.67 ppb), acetic acid (1.68 ppb), and formic acid (2.24 ppb) were measured. The OVOCs comprise approximately 75% of total measured VOCs, suggesting the occurrence of strong oxidation processes and/or long-range transported at the site. A strong photochemical aging and oxidation of the atmospheric pollutants were also observed in aerosol measured by HR-ToF-AMS, whereby a high $f_{44}:f_{43}$ value is shown for organic aerosols (OAs); however, relatively low $f_{44}:f_{43}$ values were observed when high concentrations of BVOCs and AVOCs were available, providing evidence of the formation of SOA from VOC precursors at the site. Overall, the results of this study revealed several different SOA formation mechanisms, and new particle formation and particle growth events were identified using the powerful tools scanning mobility particle sizer (SMPS), PTR-ToF-MS, and HR-ToF-AMS.

Survey of Airborne Fungi Levels in 24 Seasonal Divisions and Correlation Analysis with Meteorological Elements (24절기 야외 부유곰팡이 농도 조사 및 기상요소와의 상관성 분석)

  • Kim, Myoung Nam;Hong, Jin Young;Lee, Jeong Min;Park, Ji Hee
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.652-663
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    • 2019
  • To identify daily and annual changes in outdoor airborne fungi, it is necessary to shorten the collection cycle and increase the number of measurements. In this study, measurements were performed by employing an air sampler and potato dextrose agar media on the rooftop of National Research Institute of Cultural Heritage during a period of one year (August 2018 to July 2019). The collection cycle spanned the twenty-four seasonal divisions and the collection time was 2 p.m. and 11 p.m.. Meteorological elements were collected at intervals of one hour. Furthermore, the concentration of airborne fungi was monitored and correlation analysis with meteorological elements was subsequently conducted. Obtained results indicate that the concentration of airborne fungi is found to be highest in November, autumn, night, followed by autumn, summer, winter, and spring. The concentration, type, and dominant species of airborne fungi can vary depending on factors such as rainfall, typhoons, and yellow dust (fine dust). The concentration of airborne fungi indicates a strong positive linear relationship between precipitation, number of precipitation days, and relative humidity. The concentration of airborne fungi was related to the period of increase of dead plants in terms of nutrition source, and to the high relative humidity conditions including rainfall in terms of meteorological elements.

Distribution Characteristics of Polychlorinated Biphenyls in Sediments inside Jeju Harbor (제주항내 퇴적물의 PCBs 분포특성)

  • Heo, Ryun-Yong;Kam, Sang-Kyu;Cho, Eun-Il
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.2
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    • pp.220-227
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    • 2016
  • In this paper, polychlorinated biphenyls (PCBs) were measured in surface sediments collected three times (June, October, December, 2013), inside Jeju Harbor as major harbors of Jeju Island. The concentration of PCBs inside Jeju Harbor was in the range of 1.62~4.45 (mean) ng/g on a dry weight basis and the levels were very low. In the analysis of PCBS homologue patterns, high-chlorinated PCB congeners were dominant in surface sediments inside Jeju Harbor, indicating that their sources were originated from shipping activity. In the relationships between PCBs concentrations and particle size (mud, sand and gravel) in surface sediments, PCBs concentrations were higher in the sediments with higher mud content, indicating that higher PCBs were distributed with increasing sediments of fine gradules. The PCBs concentrations in surface sediments in this study were very low, compared with ER-L (effect range-low) and TEL (threshold effects level) among sediment quality guideleines (SQGs) applied in foreign countries, such as USA, Canada, and Australia, etc), indicating that their biological effects on the bottom organisms in marine environment were expected to be very low.

Creation of an Environmental Forest as an Ecological Restoration

  • Lee, Chang-Seok;You, Young-Han
    • The Korean Journal of Ecology
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    • v.24 no.2
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    • pp.101-109
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    • 2001
  • We created an environmental forest on the basis of ecological design around the incineration plant of Jindo Engineering and Construction Co., Ltd., which is located in Jeongwang-dong, Siheung-si, Kyunggi-do. To get ecological information of this site, physico-chemical properties of soil on salt marsh, which is located close to the syudy site and of forest soil transported from other sites for ecological restoration were analyzed. Texture of salt marsh and transported soils were loam and sandy loam, respectively. pH, organic matter, T-N, available P, and exchangeable K and Na contents of salt marsh and transported forest soils were 6.7 and 5.4, 4.1 and 0.4%, 1.0 and 0.3mg/g, 46.7 and 6.8ppm, 521 and 207ppm, and 3.8 and 0.5mg/g, respectively. Introduced plants were selected among the dominant species of forests and the species composing the potential natural vegetation around the present study site. Those plants were selected again by considering the tolerances to air pollution and to salt, and their availability. Selected trees were Pinus thunbergii, Sophora japonica, Celtis sinensis, Quercus aliena, Q. serrata, Q. dentata, and Q. acutissima. Selected sub-trees were Albizzia julibrissin, Koelreuteria poniculata, and Styrax japonica and shrubs were Rhododendron yedoense var. poukhanense, R. mucronulatum, Callicarpa japonica, Euonymus alatus, E. japonica, and R. schlippenbachii. On the other hand, introduction of herbs was not considered except for Liriope platyphylla, which was ornamentally planted in one site. Planting bed of mound type was adopted to provide the fine drainage system. Mound was designed to furnish litter, A, B, and C layers simuating the profile of forest soil. Slope of mound was mulched by rice straw of 2cm in thickness to prevent for sliding of litter and soil in cases of strong wind or heavy rain. Height of mound was designed to secure more than 1 m by combining A and B layers. Narrow zones, in which mound with stable slope degree cannot be prepared, was designed to equip the standard soil depth with the introduction of stone for supporting. On the other hand, plants with shallow root system were arranged in some zones, in which satisfactory soil depth cannot be ensured. Plants were arranged in the order of tree, sub-tree, and shrub from center to edge on the mound to make a mature forest of a dome shape in the future. Dispersion of plants was designed to be random pattern rather than clumped one. Problems on creation of the environmental forest by such ecological design were found to be management or inspection by non-specialized project operators and inspecting officers, and regulations for construction without ecological background. Alternative plans to solve such problems were suggested.

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Characteristics of Heavy Metal Distribution in Surface Sediments from the south Sea of Korea (남해 대륙붕 표층퇴적물 중 중금속 원소의 분포 특성)

  • 조영길;이창복
    • 한국해양학회지
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    • v.29 no.4
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    • pp.338-356
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    • 1994
  • Sediment samples from the continental shelf of the South Sea of Korea are analysed to determine the concentration of Al, Fe, Mn, cu, Ni, Zn, Co, Cr and Pb. among these samples, fine-grained sediments were also analysed by a sequential extraction technique to know geochemical forms of the metals in this environments. The total concentration of Al, Fe, Cr, Ni, Cu and Zn in bulk sediments decreased gradually with the increase of distance from the coastal zone. This distribution patterns are well coincide with grain size distribution. However, the patterns of Mn, co and Pb do not follow such and overall distribution. The concentration of Pb, particularly, did not show any features in areal distribution, which may be result from different pathways to the sediments, compared to the other metals. the speculation data show that a considerable amount of Cd, Mn and Co are bounded in the carbonate fraction, accounting for 42.8%, 40.3% and 30.6%, respectively. Cu, Zn, Mn and Fe are largely associated to oxide fraction with proportions of 34.4%, 23.1%, 15.5% and 13.7%, respectively. However, the metals in residual fraction account for more than 50% of the total metal concentration, except for Mn. These observations emphasize that residual fraction in the dominant component controlling the elemental concentration.quartz and glauconite grains.Accordingly,these sediments are interpreted as an extension part of transgressive sand deposit that are widely distributed on the continental shalf floor of southern Yellow Sea.

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