• Title/Summary/Keyword: Fibril

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Physical and Electrochemical Properties of Polyaniline-Ionic Liquid Composite (폴리아닐린-이온성 액체 복합체의 물리적전기화학적 특성)

  • Bang, Joo-Yong;Jeong, Woo-Sung;Park, Hyung-Soon;Chung, Kyung-Ho;Nath, Narayan Chandra Deb;Lee, Jae-Joon;Cha, Eun-Hee;Lee, Jae-Kwan
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.181-185
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    • 2010
  • Polyaniline-ionic liquid composite was prepared and investigated its physical and electrochemical properties. The quasi-solidification was presented in imidazolium-based ionic liquid (1-methly-3-propylimidazolium iodide, PMI-I) containing above 30 wt% of polyaniline (emeraldine base), which exhibited around 80% decrease of conductivity compared to pristine ionic liquid, resulting in fibril structure trough ${\pi}-{\pi}$ self-assembled of imidazolium aromatic ring of ionic liquid on polyaniline framework.

Structure Variation of Polypropylene Hollow Fiber Membrane with Operation Parameters in Stretching Process (연신 공정 조업변수에 따른 폴리프로필렌 중공사막의 구조 변화)

  • Lee Gyu-Ho;Kim Jin-Ho;Song Ki-Gook;Kim Sung-Soo
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.175-181
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    • 2006
  • Hybrid process of thermally-induced phase separation and stretching was developed for the preparation of microporous polypropylene hollow fiber membranes. Precursor for stretching was prepared by using soybean oil as a diluent and benzoic acid as a nucleating agent far the sphenlite control and it was stretched far the micrporous hollow fiber membrane. The effects of stretching ratio and deformation rate for stretching process were investigated. Increase of stretching ratio resulted in the greater pore size with nonuniform size distribution. Higher deformation rate also increaser the pore size with uniform size distribution. Stretching ratio was closely related with the orientation of polymer chain and increased the mechanical strength of the fiber. Increase of deformation rate had little effects on the orientation of crystalline phase, and decreased the orientation of amorphous phase which caused the decrease of tensile strength of the fiber and broke the micro-fibrils connecting spherulites to form a circular pore shape.

Particle and NOM Fouling in Ultrafiltration with Softening Pretreatment (연수화 전처리를 적용한 한외여과에서 입자상 물질 및 자연유기물 막오염)

  • Kweon, Ji-Hyang;Lawler, Desmond F.
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.534-541
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    • 2003
  • Membrane processes are now frequently considered for application in drinking water treatment. The biggest impediment for applying membrane processes is fouling that comes from mass flux (such as particle and organic matter) to the membrane surface and its pores due to convection flow through the membrane. Natural organic matter (NOM) has been reported as the most detrimental foulant. Some research also indicated that particles were often the dominant cause of fouling. Therefore, both NOM and particle fouling need to be examined to better understand fouling in ultrafiltration. Two waters from natural sources, Lake Austin water and Missouri River water, were selected. Both waters are relatively hard waters but has significantly different particle concentrations, which will elucidate effects of particles on membrane fouling. Precipitative softening is traditionally designed to remove hardness ions in hard waters but it can also remove particles and organic matter. Therefore, the integrated water treatment with softening and ultrafiltration is proposed as a promising option for hard waters. The three levels of softening were used to represent different degrees of pretreatment to ultrafiltration in terms of organic matter (i.e., NOM fouling) and precipitates (i.e., particle fouling by further precipitation). Results showed that natural particles in Missouri River water was detrimental foulants of ultrafiltration. As the levels of softening were increased, NOM and particle removal was increased, and thus fouling was decreased. Direct images of the surface of the membranes by scanning electron microscopy allowed observation of the different properties of particles caught in fibril networks of natural organic matter.

Synthesis and Evaluation of Oleanolic Acid-Conjugated Lactoferrin for β-Amyloid Plaque Imaging

  • Kim, Sung-Min;Kim, Dongkyu;Chae, Min Kyung;Jeong, Il-Ha;Cho, Jee-Hyun;Choi, Naeun;Lee, Kyo Chul;Lee, Chulhyun;Ryu, Eun Kyoung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3671-3675
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    • 2012
  • ${\beta}$-Amyloid accumulation in the brain is a pathological hallmark of Alzheimer's disease (AD). Since early detection of ${\beta}$-amyloid may facilitate more successful and timely therapeutic interventions, many investigators have focused on developing AD diagnostic reagents that can penetrate the blood-brain barrier (BBB). Oleanolic acid (OA) is a substance found in a variety of plants that has been reported to prevent the progression of AD in mice. In this study, we synthesized and evaluated a new radioligand in which OA was conjugated to lactoferrin (Lf, an iron-binding glycoprotein that crosses the BBB) for the diagnosis of AD. In an in vitro study in which OA-Lf was incubated with ${\beta}$-amyloid (1-42) aggregates for 24 h, we found that OA-Lf effectively inhibited ${\beta}$-amyloid aggregation and fibril formation. In vivo studies demonstrated that $^{123}I$-OA-Lf brain uptake was higher than$^{123}I$-Lf uptake. Therefore, radiolabeled OA-Lf may have diagnostic potential for ${\beta}$-amyloid imaging.

Characteristics of High Strength Polyethylene Tape Yarns and Their Composites by Solid State Processing Methods (고상공정법에 의한 고강도 폴리에틸렌 테이프사와 그 복합재료의 특성)

  • Lee, Seung-Goo;Cho, Whan;Joo, Yong-Rak;Song, Jae-Kyung;Joo, Chang-Whan
    • Composites Research
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    • v.12 no.2
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    • pp.91-100
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    • 1999
  • The manufacture of high strength polyethylene(HSPE) tape yarns has been accomplished by a solid state processing(SSP) method as the compaction of ultra-high molecular weight polyethylene(UHMWPE) powders and drawing of the compacted film under the melting point without any organic solvents. In this study, the characteristics of HSPE tape yarns produced by SSP which is desirable for production cost and environmental aspect were analyzed. As the results, tensile strengths of HSPE tape yarns increased with increasing the draw ratio and the fracture morphology of highly drawn HSPE tape yarns showed more fibrillar shape than the low drawn one. Interfacial shear strengths of HSPE tape yarns with vinylester resin increased by $O_2$ plasma treatment and maximum interfacial shear strength was obtained in the plasma treatment condition of 100W and 5min. In addition, mechanical properties of HSPE tape yarn reinforced composites were investigated and compared with those of the gel spun HSPE fiber reinforced composites.

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New Evaluation of Initial Growth Mechanisms of Hydroxyapatite on Self-assembled Collagen Nanofibrils by Using ToF-SIMS and AFM Techniques

  • Park, Young-Jae;Choi, Gyu-Jin;Lee, Tae-Geol;Lee, Won-Jong;Moon, Dae-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.397-397
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    • 2010
  • Bone is considered as hierarchically organized biocomposites of organic (collagen) and inorganic (hydroxyapatite) materials. The precise structural dependence between hydroxyapatite (HAp, $Ca_{10}(PO_4)_6(OH)_2)$ crystals and collagen fibril is critical to unique characteristics of bone. To meet those conditions and obtain optimal properties, it is essential to understand and control the initial growth mechanisms of hydroxyapatite at the molecular level, such as other nano-structured materials. In this study, collagen fibrils were prepared by adsorbing native type I collagen molecules onto hydrophobic surface. Hydrophobicity was introduced on the Si wafer surface by using PECVD (plasma enhanced chemical vapor deposition) method and cyclohexane as a precursor. Biomimetic nucleation and growth of HAp on the self-assembled collagen nanofibrils were occurred through incubation of the sample in SBF (simulated body fluid). Chemical and morphological evolution of HAp nanocrystals was investigated by surface-sensitive analytical techniques such as ToF-SIMS (Time-of-Flight Secondary Ion Mass Spectrometry) and AFM (Atomic Force Microscopy) in the early growth stages (< 24 hrs). The very initial stages (< 12 hrs) of mineralization could be clearly demonstrated by ToF-SIMS chemical mapping of surface. In addition to ToF-SIMS and AFM measurement, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction analysis were conducted to characterize the HAp layer in the late stages. This study is of great importance in the growth of real bone-like materials with a structure analogous to that of natural bones and the development of biomimetic nanomaterials.

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MULTILAYER SPECTRAL INVERSION OF SOLAR Hα AND CA II 8542 LINE SPECTRA WITH HEIGHT-VARYING ABSORPTION PROFILES

  • Chae, Jongchul;Cho, Kyuhyoun;Kang, Juhyung;Lee, Kyoung-Sun;Kwak, Hannah;Lim, Eun-Kyung
    • Journal of The Korean Astronomical Society
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    • v.54 no.5
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    • pp.139-155
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    • 2021
  • We present an updated version of the multilayer spectral inversion (MLSI) recently proposed as a technique to infer the physical parameters of plasmas in the solar chromosphere from a strong absorption line. In the original MLSI, the absorption profile was constant over each layer of the chromosphere, whereas the source function was allowed to vary with optical depth. In our updated MLSI, the absorption profile is allowed to vary with optical depth in each layer and kept continuous at the interface of two adjacent layers. We also propose a new set of physical requirements for the parameters useful in the constrained model fitting. We apply this updated MLSI to two sets of Hα and Ca II line spectral data taken by the Fast Imaging Solar Spectrograph (FISS) from a quiet region and an active region, respectively. We find that the new version of the MLSI satisfactorily fits most of the observed line profiles of various features, including a network feature, an internetwork feature, a mottle feature in a quiet region, and a plage feature, a superpenumbral fibril, an umbral feature, and a fast downflow feature in an active region. The MLSI can also yield physically reasonable estimates of hydrogen temperature and nonthermal speed as well as Doppler velocities at different atmospheric levels. We conclude that the MLSI is a very useful tool to analyze the Hα line and the Ca II 8542 line spectral daya, and will promote the investigation of physical processes occurring in the solar photosphere and chromosphere.

Histopathological studies on the degenerative changes of somatic muscle in soft tunic syndrome of ascidian, Halocynthia roretzi (멍게 물렁증 근육변성의 병인에 관한 연구)

  • Huh, Min Do;Lee, Hyo Eun;Lee, Mu Kun;Kim, Bo Sung
    • Journal of fish pathology
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    • v.34 no.1
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    • pp.63-70
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    • 2021
  • As a part of research to elucidate the pathogenesis of so called Soft Tunic Syndrome(STS), that caused mass mortalities in the cultured sea squirts, Halocynthia roretzi, the epidemiological and pathological analysis were done to both clinically normal and diseased groups of the farms of Tongyoung and Geoje coastal areas in southeast sea from February to July, 2008. In the histological finding of the tunic, most of individuals showed tunic softness syndromes that included the disarrangement and destruction of tunic fiber with the simultaneous presence of flagellates-like cells, recently suspected as main agents of tunic softness syndromes. Simultaneously, the intensive degenerative changes of the skeletal muscle of diseased sea squirts were recognized. The changes were characterized with the hyalinization and condensation of muscle fibril and hemocytic infiltration in the muscle fibers. Those were thought to be a kind of typical Zenker's necrosis as in the skeletal muscle of higher vertebrates. Besides of the diseased sea squirts, Zenker's necrosis of skeletal muscles were seen in the normal ones. Epidemiological inquiry for diseased groups revealed that the higher incidences of tunic softness syndrome were recorded in the fast growing groups and in the sites presuming the organic pollution. And Higher malondialadehyde(MDA) and glutathione peroxidase(GPx) activity were detected in the groups showing STS. Those results suggested that Zenker's necrosis of body muscles was a kind of"nutritional myopathy" by oxidative stress. Conclusively, it was considered that Zenker's necrosis of body muscles gives an important clue for elucidating pathogenesis of STS of cultured squirts. And it seems that the necrosis were caused by the oxidative stress to body muscle during abnormal rapid growth of sea squirts.

A Study on Conferring Orientation to Myoblast for Realizing Tissue of Cultured Meat (배양육 조직구현을 위한 배향성 부여에 관한 연구)

  • Seok, Yong-Joo;Zo, Sun-Mi;Choi, Soon-Mo;Han, Sung Soo
    • Textile Coloration and Finishing
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    • v.34 no.4
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    • pp.284-301
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    • 2022
  • The limitations of food production caused by global warming, consumption of soil fertility, and land shortage have demanded the development of alternative foods. Their market has been increasing, and in particular, there is an urgent need for an alternative meat. Among them, the non-slaughtered cell-cultured meat that can be manufactured in the laboratory, that is, cultured meat, is in the spotlight, which can solve the problem of meat consumption while including the advantages of meat. It is classified into minced cultured meat and structured one with a structure similar to that of real meat. The latter is currently facing limitations related scaffolds, cells, and the multiplicative problems, and many attempts are being made to solve them. The complex problem is related to secure texture and taste as well as structural similarity to actual meat. To solve the problems, it is necessary to lay emphasis on cells, there are fat cells and vascular cells, and the most fundamental cells, muscle cells. These are the main cells that control the texture and nutrients of meat, and unlike other cells, they grow in the form of fibers. A myofibril (also known as a muscle fibril) is a basic rod-like organelle of a muscle cell, which is a quantitatively major component of meat, and one of the tissues that maintain the appearance of the body and bones. In this review article, we focused on the growth of muscle cells into long, tubular cells known as muscle fibers using the fabricated fibrous scaffold, and reviewed not only research results for muscle tissue engineering but also various results in the related fields for the last five years.

An Electron Microscopy of Spermiogenesis in the Dragonfly, Crocothemis servilia Drury (고추잠자리의 精子完成의 電子顯微鏡的 硏究)

  • Paik, Kyong Ki;Choi, Choon Keun;Lee, Kuk Bum
    • The Korean Journal of Zoology
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    • v.15 no.3
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    • pp.133-147
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    • 1972
  • Ultrastructures of spermiogeneis in other invertebrates were investigated by several workes (Anderson, et al., 1967; Bloch, et al., 1964; Christen, 1961; Gatenby, et al., 1959; Paik, et al., 1968; Silveira, 1964; Yasuzumi, 1957) but spermiogenesis of dragonfly has not been reported previously. Testes and vass deferentia of the Korean dragonfly, Crocothemis servilia, were used for electron microscopic study of spermiogenesis. Materials were prefixed for 1-2 hours at $3^{\circ}C$ in 1.25% glutaraldehyde buffered to pH 7.2 with 0.2M sodium cacodylate buffer. Fixed tissue was washed twice in 0.2M cacodylate buffer and was subsequently postfixed for 2 hours at $3^{\circ}C$ in 1% osmium tetroxide buffered to pH 7.2 with 0.4M sodium cacodylate buffer solution. Specimens were dehydrated in graded ethyl alcohol, and finally embedded in epoxy Epon resin. Thin sections prepared from all the blocks were doubly stained; first in uranyl acetate and then in lead citrate. All thin sectios were examined with a Hitachi HS-7S electron microscope. The results of this study were summarized as follows. 1. Along the condensation of chromatin in nucleus, the shpae of nucleus was changed from spherical shpae to ellipse and cone cell type. 2. During the elongation of nucleus and the migration of cytoplasm, the nucleus removed to the one side of spermatid and began to invaginate from the posterior portion of nucleus. 3. There are ring centrioles in invaginated portion and axial filaments derived from centriole extend to the tail through the tailward half of spermatid. 4. In the cross sections the axial filament consisted of a central sheath, a central fibril, and 9 peripheral doublets.

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