• Title/Summary/Keyword: Fiber surface engineering

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Optimal Design of FRP Taper Spring Using Response Surface Analysis (반응표면 분석법을 이용한 FRP 테이퍼 판 스프링의 최적설계)

  • 오상진;이윤기;윤희석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.676-679
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    • 1997
  • The present paper is concerned with the optimal deslgn that the static spring rate of the fiber-reinforcement composite spring is fitted to that of the steel leaf spring. The thickness and w~dth of springs were selected as deslgn variables. And object functions of the regression model were obtained through the analysis with a common analytic program. After regression coefficients were calculated to get functions of the regression model, optimal solutions were calculated with DOT. E-GlassIEpoxy and CarbonIEpoxy were used as fiber reinforcement materials in the design, which were compared and analyzed with the steel leaf spring. It was found that the static spring rate of the optimal model was almost similar to that of the existing spring.

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An Overview of the Activated Carbon Fibers for Electrochemical Applications

  • Lee Gyoung-Ja;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.9 no.1
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    • pp.10-18
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    • 2006
  • This article is concerned with the overview of the activated carbon fibers. Firstly, this review provides a comprehensive survey of the overall processes for the synthesis of the activated carbon fibers from the carbonaceous materials. Subsequently, the physicochemical properties such as pore structures and surface oxygen functional groups of the activated carbon fibers were discussed in detail. Finally, as electrochemical applications of the activated carbon fibers to electrode materials for electric double-layer capacitor (EDLC), the electrochemical characteristics of the activated carbon fiber electrodes and the various methods to improve the capacitance and rate capability were introduced. In particular, the effect of pore length distribution (PLD) on kinetics of double-layer charging/discharging was discussed based upon the experimental and theoretical results in our work. And then we discussed in detail the applications of the activated carbon fibers to adsorbent materials for purification of liquid and gas.

Electrochemical Removal Efficiency of Pollutants on ACF Electrodes

  • Oh, Won-Chun;Park, Joung-Sung;Lee, Ho-Jin;Yum, Min-Hyung
    • Carbon letters
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    • v.5 no.4
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    • pp.191-196
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    • 2004
  • The electrochemical removal (ECR) of water pollutants by activated carbon fiber (ACF) electrodes from wastewater was investigated over wide range of electrochemical reaction time. The ECR capacities of ACF electrodes were associated with their internal porosity and were related to physical properties and to reaction time. And, surface morphologies and elemental analysis for the ACFs after electrochemical reaction are investigated by SEM and EDX to explain the changes in adsorption properties. The FT-IR spectra of ACFs for the investigation of functional groups show that the electrochemical treatment is consequently associated with the homogeneous removal of pollutants with the increasing surface reactivity of the activated carbon fiber surfaces. The ACFs were electrochemically reacted to waste water to investigate the removal efficiency for the COD, T-N and T-P. From these removal results of pollutants using ACFs substrate, satisfactory removal performance was obtained. The outstanding removal effects of the ACFs substrate were determined by the properties of the material for adsorption and trapping of organics, and catalytic effects.

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Low Temperature Suspension Polymerization of Methyl Methacrylate for the Preparation of High Molecular Weight Poly(methyl methacrylate)/Silver Nanocomposite Microspheres

  • Yeum, Jeong-Hyun;Ghim, Han-Do;Deng, Yulin
    • Fibers and Polymers
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    • v.6 no.4
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    • pp.277-283
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    • 2005
  • In order to prepare high molecular weight poly(methyl methacrylate) (PMMA)/silver nanocomposite microspheres, methyl methacrylate was suspension-polymerized in the presence of silver nanoparticles at low temperature with 2,2'-azobis(2,4-dimethylvaleronitrile) as an initiator. The rate of conversion was increased by increasing the initiator concentration. When silver nanoparticles were added, the rate of polymerization decreased slightly. High monomer conversion (about $85\%$) was obtained in spite of low polymerization temperature of $30^{\circ}C$. Under controlled conditions, PMMA/silver microspheres with various number-average degrees of polymerization (6,000-37,000) were prepared. Morphology studies revealed that except for normal suspension microspheres with a smooth surface, a golf ball-like appearance of the microspheres was observed, due to the migration and aggregation of the hydrophilic silver nanoparticles at the sublayer beneath the microsphere's surface.

A Structural Study of the Activated Carbon Fibers as a Function of Activation Degrees

  • Roh, Jae-Seung;Suhr, Dong-Soo
    • Carbon letters
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    • v.5 no.2
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    • pp.51-54
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    • 2004
  • Isotropic pitch-based carbon fiber was isothermally activated in $CO_2$ atmosphere. Structural parameters of the isotropic carbon fibers and activated carbon fibers (ACFs) were evaluated by X-ray diffraction (XRD). The $d_{002}$ and La of the carbon fibers were measured to be 4.04 ${\AA}$ and 23.6 ${\AA}$ and those of ACFs were 4.29 ${\AA}$ and 22.7 ${\AA}$, respectively, representing less ordered through activation process. The pores in the ACFs were characterized by BET, and they showed super-high specific surface area of maximum value 3,495 $m^2/g$ from average pore size of 8.3 ${\AA}$ at 59% burn-off. It was recognized that 8-9 ${\AA}$ was optimum range of pore size for efficient creation of high specific surface area. The average size of the pores formed at higher temperature ($1100^{\circ}C$) was larger than that of the pores formed at lower temperature ($900^{\circ}C$).

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Fabrication and Characterization of Polystyrene/Gold Nanoparticle Composite Nanofibers

  • Kim, Jung-Kil;Ahn, Hee-Joon
    • Macromolecular Research
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    • v.16 no.2
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    • pp.163-168
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    • 2008
  • Polystyrene/gold nanoparticle (PS/AuNP) composite fibers were fabricated using an electrospinning technique. Transmission electron microscopy (TEM) showed that the diameters of the naphthalenethiol-capped gold nanoparticles (prior to incorporation into the PS fibers) ranged from 2 to 5 nm. UV-vis spectroscopy revealed the surface plasmon peaks of the gold nanoparticles centered at approximately 512 nm, indicating that nano-sized Au particles are well-dispersed in solution. This was consistent with the TEM observations. The electrospun nanofibers of PS/AuNP composites were approximately 60-3,000 nm in diameter. The surface morphology of the PS/AuNP composite and the dispersability of the Au nanoparticles inside of PS after electrospinning process were investigated by SEM and TEM. The thermal behavior of the pure PS and PS/AuNP nanocomposites and fibers were examined by DSC.

Effects of electrochemical oxidation of carbon fibers on interfacial shear strength using a micro-bond method

  • Kim, Dong-Kyu;An, Kay-Hyeok;Bang, Yun Hyuk;Kwac, Lee-Ku;Oh, Sang-Yub;Kim, Byung-Joo
    • Carbon letters
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    • v.19
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    • pp.32-39
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    • 2016
  • In this work, we studied the effects of electrochemical oxidation treatments of carbon fibers (CFs) on interfacial adhesion between CF and epoxy resin with various current densities. The surface morphologies and properties of the CFs before and after electrochemical-oxidation-treatment were characterized using field emission scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and single-fiber contact angle. The mechanical interfacial shear strength of the CFs/epoxy matrix composites was investigated by using a micro-bond method. From the results, electrochemical oxidation treatment introduced oxygen functional groups and increased roughness on the fiber surface. The mechanical interfacial adhesion strength also showed higher values than that of an untreated CF-reinforced composite.

PVP Hydrogel Coatings on Polypropylene Fibers using E-beam Irradiation (전자 빔을 이용한 폴리프로필렌 섬유의 PVP 하이드로젤 코팅)

  • Lee, Ji Eun;kwak, Hyo-Bin;Lee, Yong-Hyo;Kim, Kyung-Min;Lim, Jung-Hyurk
    • Journal of Adhesion and Interface
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    • v.20 no.2
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    • pp.66-70
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    • 2019
  • The surface of hydrophobic polypropylene (PP) fibers (spun-bonded fabric) was treated by an atmospheric plasma treatment method. These pre-treated hydrophilic PP fabrics were dip-coated in the aqueous poly(N-vinyl pyrrolidone) (PVP) solution. PVP layers on the surface of PP fiber were crosslinked by an irradiation of electron beam. The thickness of PVP hydrogels coated on the surface was easily controlled by changing the concentration of PVP in coating solution. The stepwise surface treatment, PVP coating, and hydrogel formation via electron beam irradiation were analyzed by the measurement of contact angle, scanning electron microscopy, and optical microscopy.

A Study on the Mechanical Characteristic Change Accordance with Surface Damaged Submarine GFRP Repairing (잠수함용 GFRP 표면결함 수리에 따른 기계적 특성변화 연구)

  • Jung, Young In;Koo, Ja Gil;Lee, Yoon Suk
    • Journal of Korean Society for Quality Management
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    • v.48 no.2
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    • pp.257-267
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    • 2020
  • Purpose: The purpose of this study is to define guideline for fiber-glass-resin-putty repairing method for submarine GFRP by comparing structural strength between normal GFRP and putty repaired GFRP. Methods: GFRP specimen tensile and flexural tests are conducted in accordance with ASTM D3039/3039M-17 and ASTM D790 Procedure A. The collected data was analysed whether satisfies its structural strength criteria. Furthermore, It is analysed to find dominant reason of structural strength changes. Results: The result of the study is as follows; flexural strength of GFRP is satisfied strength criteria for all test cases, but tensile strength is not satisfied its criteria for some cases which over 2 mm depth of surface damage. Conclusion: The fiberglass-resin-putty repairing method should be applied to under 2 mm depth of damage which is not affecting to roving fiber layer destruction in GREP laminate.

A Study on Heating Element Properties of Carbon Nanotube/Silicon Carbonitride Composite Sheet using Branched Structured Polysilazane as Precursor (가지 달린 구조의 폴리실라잔을 전구체로 이용해 제조한 카본 나노튜브/실리콘 카보나이트라이드 복합체 시트의 발열특성에 관한 연구)

  • Huh, Tae-Hwan;Song, Hyeon Jun;Jeong, Yeong Jin;Kwark, Young-Je
    • Composites Research
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    • v.33 no.6
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    • pp.395-400
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    • 2020
  • In this paper, we manufactured silsesquiaznae (SSQZ)-coated carbon nanotube (CNT) surface heating elements, which allowed stable heating at high temperatures. The prepared composite sheet was confirmed by FE-SEM that the SSQZ fully coated the surface of CNT sheet. Furthermore, it was also confirmed that the silicon carbonitride (SiCN) ceramic formed by heat treatment of 800℃ have no defects found and maintain intact structure. The CNT/SiCN composite sheet was able to achieve higher thermal stability than raw CNT sheets in both nitrogen and air atmosphere. Finally, the CNT/SiCN composite sheet was possible to heat up at a temperature of over 700℃ in the atmosphere, and the re-heating was successfully operated after cooling.