• Title/Summary/Keyword: Ferroelectric Films

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Fabrications and properties of MFIS structure using AIN buffer layer (AIN 버퍼층을 사용한 MFIS 구조의 제작 및 특성)

  • 정순원;김용성;이남열;김진규;정상현;김광호;유병곤;이원재;유인규
    • Proceedings of the IEEK Conference
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    • 2000.11b
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    • pp.29-32
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    • 2000
  • Meta1-ferroelectric-insulator-semiconductor(MFIS) devices using Pt/LiNbO$_{3}$/AIN/Si structure were successfully fabricated. AIN thin films were made into metal-insulator-semiconductor(MIS) devices by evaporating aluminum in a dot array on the film surface. The dielectric constant of the AIN film calculated from the capacitance in the accumulation region in the capacitance-voltage(C-V ) characteristic is 8. The gate leakage current density of MIS devices using a aluminum electrode showed the least value of 1$\times$10$^{-8A}$ $\textrm{cm}^2$ order at the electric field of 500㎸/cm. A typica] value of the dielectric constant of MFIS device was about 23 derived from 1MHz capacitance-voltage (C-V) measurement and the resistivity of the film at the field of 500㎸/cm was about 5.6$\times$ 10$^{13}$ $\Omega$.cmcm

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Crystalline and Electrical Properties of (Pb, La)TiO3 Ferroelectric Films ((Pb,La) TiO3 강유전체막의 결정성과 전기적특성)

  • 장호정
    • Journal of the Microelectronics and Packaging Society
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    • v.5 no.2
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    • pp.59-64
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    • 1998
  • Pt/SiO2/Si 기판구조위에 스크린인쇄법과 졸-겔법에 의해 (Pb, La)TiO3(PLT) 후막 과 박막을 도포시켜 $650^{\circ}C$후속열처리 온도에서 결정화한후 결정특성과 전기적 특성을 조사 하였다. $650^{\circ}C$ 온도에서 후속열처리된 PLT 시료의 경우 전형적인 perovskite 결정구조를 보 여주었다. SEM 단면형상으로부터 Pt 전극과 PLT막 사이에는 비교적 평활한 계면형상을 보여주었다. PLT 후막과 박막시료의 잔류분극(2Pr) 값은 약 1$\mu$C/cm2 으로각각 나타났으며 이와같이 후막 PLT시료에 비해 박막시료의 잔류분극값이 큰이유는 박막시료가 보다 양호 한 결정성을 지니기 때문이었다. 상온부근에서 후막과 박막시료의 초전계수값은 약 1.5nC/cm2.$^{\circ}C$와 4.0nC/cm2.$^{\circ}C$의 값을 각각 나타내었으며 누설전류의 크기는 약 0.3~0.8$\mu$ A/cm2의 비교적 양호한 누설전류 특성을 얻었다.

Ferroelectric properties of Pb[(Zr. Sn)Ti]NbO$_3$Thin Films prepared by RF Magnetron Sputtering Method (RF 마그네트론 스퍼터링 방법으로 제작된 Pb[(Zr. Sn)Ti]NbO$_3$박막의 강유전 특성)

  • 최우창;최혁환;이명교;권태하
    • Proceedings of the IEEK Conference
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    • 1999.11a
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    • pp.199-202
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    • 1999
  • 반강유전 물질인 Pb[(Zr. Sn)Ti]NbO₃를 La/sub 0.5/Sr/sub 0.5/CoO₃/Pt/Ti/SiO₂/Si 기판상에 RF 마그네트론 스퍼터링 방법으로 박막화하여 그 결정성과 전기적 특성을 조사하였다. 80 W의 RF power, 400℃의 기판온도, Ar:O₂= 9:0.5의 분위기에서 증착되고, 650 ℃에서 10초동안 RTP(Rapid Thermal Process) 방법으로 열처리된 박막이 가장 우수한 페로브스카이트 구조를 보였으며, 10 ㎑ 에서 유전상수(ε')는 721, 유전손실(tan δ)은 0.06을 나타내었다. 잔류분극(Pr)은 15.5 μC/㎠ 였으며, 항전계(Ec)는 51 ㎸/㎝로 비교적 낮은 값을 나타내었다.

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Structural Properties of KLN Thin Film Deposited on Pt Coated Si Substrate (Pt 코팅된 Si 기판에 제조한 KLN 박막의 구조적 특성)

  • 박성근;이기직;백민수;전병억;김진수;남기홍
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.410-416
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    • 2001
  • KLN thin films were fabricated on Pt coated Si(100) wafer using an rf-magnetron sputtering method. The grown KLN thin film consists of 4-fold grains. In this experiment, the structure of 4-fold grained thin film was investigated using XRD and SEM measurements. Pt layer was also deposited using the rf-magnetron sputtering method,. XRD measurement showed that he Pt thin film has Gaussian distribution form with strong (111) direction orientation. The KLN thin film has preferred-orientation of (001) direction, and the peak consists of 2 separate peaks; one with broad FWHM and the other with narrow FWHM. The sharp peak is due to single crystal, and combining with Em results, the 4-fold grain consists of singel crystals with c-axis normal to substrate.

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Characterization of Pt thin Fiims for Bottom Electrode of Ferroelectric Thin Films Using Metal-organic Chemical Vapor Deposition (강 유전체 박막을 위한 하부전극 MOCVD-pt 박막의 특성)

  • Gwon, Ju-Hong;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.6 no.12
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    • pp.1263-1269
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    • 1996
  • 반도체 메모리 소자에 이용되는 하부전극의 Pt 박막을 MOCVD 증착방법을 이용하여 SiO2(100nm)/Si 기판위에 증착하였다. 반응개스로 O2개스를 사용하였을 경우에 순수한 Pt 박막을 얻었으며 증착층은(11)우선방향을 가지고 성장하였다. 증착온도가 45$0^{\circ}C$에서는 결정립 경계에 많은 hole이 형성되어 박막의 비저항을 증가시켰다. MOCVD에 의해 얻어진 Pt 박막은 전 증착온도범위에서 인장응력을 가지고 있었으며 40$0^{\circ}C$이상의 온도에서 hole이 형성되면서 응력은 감소하였다. MOCVD-Pt 위에 PEMOCVD로 증착한 강 유전체 SrBi2Ta2O9박막은 균일하고 치밀한 미세구조를 보였다.

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Study of Pixel Isolated PSCOF Mode

  • Kim, Dong-Woo;Shin, Sung-Tae;Jung, Jong-Wook;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.399-402
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    • 2005
  • We have studied the Pixel Isolated Phase Separated Composite Organic Film (PI-PSCOF). The PI-PSCOF can be made by the anisotropic phase separation between Ferroelectric Liquid Crystals and Pre-polymer materials by irradiating the UV with optimizing its intensity and time. In the technology, the FLC molecules are isolated in pixels where FLCs are surrounded by the inter-pixel vertical polymer walls and the horizontal polymer films on the upper substrate. The good merits of this technology are fast response time, and good mechanical and thermal stability against external high pressure and temperature. We will compare the results obtained from FLC, PSCOF, and PI-PSCOF modes by using the electro-optic measurement and x-ray scattering, and mechanical method. We believe that the PI-PSCOF technology can be a best candidate for future Flexible Display Applications.

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The properties of $(Ba_{0.7}\;Sr_{0.3})TiO_3$ by Multilayer structure (다층 구조에 의한 $(Ba_{0.7}\;Sr_{0.3})TiO_3$의 물리적 특성)

  • Hong, Kyung-Jin;Cho, Jae-Cheal
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.31-34
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    • 2006
  • In this study, $(Ba_{0.7}\;Sr_{0.3})TiO_3$ was coated on Pt/Ti/$SiO_2$/Si wafer by using Sol-Gel method. Coating process was repeated 3~5 times and then sintered at 750[$^{\circ}C$] for 1 hour. Each specimen was analyzed structure and electrical characteristics. In structure characteristics, EDX analyzed the samples ratio of the formation on the structural property. Thermal behavior was observed with TG-DTA and concluded that the heat-treatment of the samples was degreed 750[$^{\circ}C$]. Surface and section of thin films were observed with SEM.

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In-situ structural analysis during heating of an epitaxial $BaTiO_3$ thin film (에피탁시 $BaTiO_3$박막의 승온중 in-situ 구조분석)

  • 김상섭;제정호
    • Journal of the Korean Vacuum Society
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    • v.8 no.2
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    • pp.111-115
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    • 1999
  • The structural characteristics of an epitaxial $BaTiO_3$ film on MgO(001) grown by sputtering were studied as a function of temperature using in-situ, real time synchrotron x-ray scattering experiments. We found that the as-grown film was single c-domain but strained at room temperature and tetragonally distorted with the c-axis normal to the film surface. Interestingly, its lattice parameters were found to be expanded in both the in-plane and the out-of -plane directions, i.e. biaxially, comparing with those of a bulk $BaTiO_3$ . More importantly, as it was heated up to $600^{\circ}C$, the tetragonal structure was kept up through without and any phase transition, which is usually observed in other epitaxial ferroelectric thin films.

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Ferroelectric and ferromagnetic properties of $BiFeO_3-PrFeO_3-PbTiO_3$ solid solutions ($BiFeO_3-PrFeO_3-PbTiO_3$계의 강자성-강유전 특성)

  • Kim, Jeong-Seog;Cheon, Chae-Il;Park, Yong-Nam;Jang, Pyung-Woo
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.40-41
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    • 2002
  • Synthesis of the ferroelectromagnetic material exhibiting ferromagnetism and ferroelectricity simultaneously has been an interesting subject due to not only for a possible application in electronic devices but also from the view point of solid state physics. In this study bulk ceramics and thin films of xBiFeO$_3$-yPrFeO$_3$-zPbTiO$_3$(x+y+z=1) and (1-w)BiFeO$_3$-wPbTiO$_3$ have been explored for finding ferroelectromagnetic material, in which ferroelectricity and ferromagnetism coexist simultaneously. (omitted)

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