• Proceedings of the Korean Magnestics Society Conference
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• 2013.12a
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• pp.118-118
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• 2013

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.316-316
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• 2007

리튬폴리머 전지용 정극활물질인 $LiFePO_4$를 수열법으로 합성하였다. 제조한 정극활물질 $LiFePO_4$는 X-ray 회절분석을 통하여 olivine 구조임을 확인하였다. 전극 제조 시 첨가된 도전재의 종류에 따른 전기화학적 특성변화를 알기 위하여, Acetylene Black, Super-Black, Multi-Walled Carbon Nanotube(MWCNT), SP270을 도전재로 제조된 정극활물질과 PVDF를 결합제로 사용하였다. 셀은 제조된 정극과 고체전해질 $25PVDFLiCIO_4EC_{10}PC_{10}$를 사용하고, 부극은 금속리튬으로 coin 타입의 cell을 조립하여 충방전을 진행하였다. 충방전 진행결과, Multi-Walled Carbon Nanotube(MWCNT)를 도전재로 사용하였을 경우, 초기 방전용량은 94mAh/g, 100cycle 후에는 약 93mAh/g인 기타 도전재를 사용하였을 때보다 안정하고 높은 방전용량을 나타내었다. 이때의 충방전 전류밀도는 0.1mAh/g이고 전압범위 는 2.5~4.3V이었다.

• Computers and Concrete
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• v.21 no.4
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• pp.399-406
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• 2018

The present study focuses on the performance of basalt fiber reinforced concrete (BFRC) lining in tunnel situated in sandstone rock when subjected to internal blast loading. The blast analysis of the lined tunnel is carried out using the three-dimensional (3-D) nonlinear finite element (FE) method. The stress-strain response of the sandstone rock is simulated using a crushable plasticity model which can simulate the brittle behavior of rock and that of BFRC lining is analyzed using a damaged plasticity model for concrete capturing damage response. The strain rate dependent material properties of BFRC are collected from the literature and that of rock are taken from the authors' previous work using split Hopkinson pressure bar (SHPB). The constitutive model performance is validated through the FE simulation of SHPB test and the comparison of simulation results with the experimental data. Further, blast loading in the tunnel is simulated for 10 kg and 50 kg Trinitrotoluene (TNT) charge weights using the equivalent pressure-time curves obtained through hydrocode simulations. The analysis results are studied for the stress and displacement response of rock and tunnel lining. Blast performance of BFRC lining is compared with that of plain concrete (PC) and steel fiber reinforced concrete (SFRC) lining materials. It is observed that the BFRC lining exhibits almost 65% lesser displacement as compared to PC and 30% lesser displacement as compared to SFRC tunnel linings.

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.923-928
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• 1999

Polycarbonate(PC)/polypyrrole(PPy) conducting composites were prepared by precipitation polymerization. $FeCl_3$, pyrrole and chloroform were used as oxidant, monomer, and solvent, respectively. The electrical conductivity was increased with increasing the amount of PPy, while the mechanical property was decreased. When the PPy content was 25 wt %, the electrical conductivity of the composites was increased up to 0.23 S/cm. The electrical conductivity, the stability of conductivity in air and mechanical properties of the composites of different PPy content were investigated and the morphology of the composite films was observed.

• The Journal of Korean Academy of Prosthodontics
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• v.54 no.4
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• pp.354-363
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• 2016

Purpose: The aim of this study was to investigate whether the application of nano-structured alumina coating to the surface of Y-TZP could enhance the bond strength with resin cement. Materials and methods: A total of 80 zirconia plates were prepared and divided into four groups. : 1) airborne particle abrasion treatment (A) : 2) Rocatec treatment after airborne particle abrasion (R) : 3) nano-structured alumina coating treatment after polishing (PC) and 4) nano-structured alumina coating after airborne particle abrasion (AC). Alumina coating was formed by the hydrolysis of aluminium nitride (AlN) powder and heat treatment at $900^{\circ}C$. Coating patterns were observed with FE-SEM. Resin block was bonded to treated zirconia ceramics using resin cement. The shear bond strengths were measured before and after thermocycling. Results: The FE-SEM images show a dense and uniform nano-structured alumina coating structure, which enhances shear bond strength by increasing micro mechanical interlocking to resin cement. PC and AC groups showed higher shear bond strengths than A and R groups before and after thermocycling. A and R groups displayed significant drops in shear bond strength after thermocycling. However, PC and AC groups did not show any meaningful decreases in shear bond strength after thermocycling. Conclusion: Treatment of Y-TZP ceramics with nano-structured alumina coating could significantly increase their shear bond strength.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.230-230
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• 2010

유기물 반도체 화합물인 Cu-Pc(copper(II)-phthalocyanine)는 우수한 전기적 광학적 특성을 가지며, OLED, MISFET등 소자로서의 활용도가 높다. Cu-Pc 화합물은 $\alpha$-phase, $\beta$-phase, $\gamma$-phase를 포함하는 여러 가지 다결정 polymer로 존재할 수 있다. 가장 잘 알려진 구조로는 열적으로 준안정적인 $\alpha$-phase와 열적으로 안정적인 $\beta$-phase가 있다. Cu-Pc 박막의 구조 및 흡수 특성과 전기적 특성에 대한 기술이 확실히 규명되지 않아 본 연구에서는 두께와 열처리 조건에 따른 결정성 및 방향성을 조사하기 위하여 $\alpha$-phase와 $\beta$-phase의 phase transition 현상 및 전기적 광학적 특성을 규명 하고자 한다. 진공증착 방법 중 하나인 PVD 방법의 thermal evaporation deposition을 이용하여 glass, ITO 기판위에 두께와 열처리에 따른 전기적?광학적 특성을 연구하였다. Cu-Pc 박막의 성장두께는 5nm~50nm 이내로 fluxmeter 및 thickness monitor를 이용하여 제어하였다. 5nm~50nm의 두께에 따른 기판온도를 $200^{\circ}C$로 고정하여 전열 처리 및 후열 처리하여 온도에 따른 박막을 성장한 후, 결정 구조 및 특성 변화와 phase transition 분석하였다. 제작된 Cu-Pc의 박막은 $\alpha$-phase와 $\beta$-phase로 구분할 수 있으며, 열처리에 따른 phase transition 현상이 뚜렷함을 알 수 있다. XRD(X-ray diffraction)를 통하여 박막에 대한 결정 구조 분석 및 FE-SEM(field emission scanning electron microscopy)와 AFM(atomic force microscopy)을 이용하여 Cu-Pc 박막의 구조적 결정성과 방향성 등, 표면 상태와 형상구조에 대해 표면의 특성을 측정하며, 광 흡수도(UV-visible absorption spectra)을 이용하여 phase transition 현상에 따른 I-V 특성을 비교분석 하였다.

• Bulletin of the Korean Chemical Society
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• v.30 no.12
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• pp.3021-3024
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• 2009

$Zn_2Ti_{1-x}Fe_xO_4\;(0\;{\leq}\;x\;{\leq}\;0.7)$ photocatalysts were synthesized by polymerized complex (PC) method and investigated for its physico-chemical as well as optical properties. $Zn_2Ti_{1-x}Fe_xO_4$ can absorb not only UV light but also visible light region due to doping of Fe in the Ti site of $Zn_2TiO_4$ lattice because of the band transition from Fe 3d to the Fe 3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped $Zn_2TiO_4$ samples for hydrogen production under UV light irradiation decreased with an increase in Fe concentration in $Zn_2TiO_4$. Consequently, there exists an optimized concentration of iron for improved photocatalytic activity under visible light (${\lambda}{\leq}$420 nm)

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2009.10a
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• pp.45-52
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• 2009

The research on miniature devices based on non-silicon materials, in particular polymeric materials has been attracting more and more attention in the research field of the micro/nano fabrication in recent years. Lost of applications and many literatures have been reported. However, the study on the micro thermal imprint process of glassy polymer is still not systematic and inadequate. The aim of this research I to obtain a numerical material model for an amorphous glassy polymer, polycarbonate (PC), which can be used in finite element analysis (FEA) of the micro thermal imprint process near the glass transition temperature (Tg). An understanding of the deformation behavior of the PC specimens was acquired by performing tensile stress relaxation tests. The viscoelastic material model based on generalized Maxwell model was introduced for the material near Tg to establish the FE model based on the commercial FEA code ABAQUS/Standard with a suitable set of parameters obtained for this material model form the test data. As a result, the feasibility of the established viscoelastic model for PC near Tg was confirmed and this material model can be used in FE analysis for the prediction and improvement of the micro thermal imprint process for pattern replication.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.22 no.3
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• pp.289-296
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• 2009

Natural frequency is a key parameter to determine the seismic and wind loading of tall flexible structures, and to assess the wind-induced vibration for serviceability check. In this study, natural frequencies and associated mode shapes were obtained from measured acceleration data and system identification technique. Subsequently, finite element(FE) models for a tall reinforced concrete buildings were built using a popular PC-based finite element analysis program and calibrated to match their natural frequencies and mode shapes to actual values. The calibration of the FE model included: 1) compensation of modulus of elasticity considering the mix design strength, 2) flexural stiffness of floor slabs, and 3) major non-structural components such as plain concrete walls. Natural frequencies and mode shapes from the final FE model showed best agreement with the measured values.

• Applied Chemistry for Engineering
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• v.27 no.2
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• pp.153-157
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• 2016

In this study, three different metal-containing ionic liquid catalysts were prepared by metal insertion and characterized by various physicochemical analytic methods. The catalytic performance of the metal containing ionic liquids in the cycloaddition of $CO_2$ with propylene oxide (PO) to produce propylene carbonate (PC) was investigated under the solvent free condition. The order of approximate rate constants ($K_{app}$) for the metal containing ionic liquid catalysts was $(MeIm)_2ZnCl_2$, > $(MeIm)_2FeCl_2$ > $(MeIm)_2CuCl_2$. These results are in accord with the experimentally obtained activity order of the different metal containing ionic liquid catalysts.