Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Synthesis of Propylene Carbonate over Metal containing Ionic Liquid Catalysts

금속 함유 이온성 액체 촉매상에서의 프로필렌 카보네이트의 합성

  • Moon, Ye-Ji (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Ji, Dahye (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Kim, Dong-Woo (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Kim, Hyeon-Gook (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Cho, Deug-Hee (Chemical Industry Development Center, Korea Research Institute of Chemical Technology)
  • 문예지 (화학산업고도화센터 한국화학연구원) ;
  • 지다혜 (화학산업고도화센터 한국화학연구원) ;
  • 김동우 (화학산업고도화센터 한국화학연구원) ;
  • 김현국 (화학산업고도화센터 한국화학연구원) ;
  • 조득희 (화학산업고도화센터 한국화학연구원)
  • Received : 2015.11.30
  • Accepted : 2015.12.29
  • Published : 2016.04.10
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Abstract

In this study, three different metal-containing ionic liquid catalysts were prepared by metal insertion and characterized by various physicochemical analytic methods. The catalytic performance of the metal containing ionic liquids in the cycloaddition of $CO_2$ with propylene oxide (PO) to produce propylene carbonate (PC) was investigated under the solvent free condition. The order of approximate rate constants ($K_{app}$) for the metal containing ionic liquid catalysts was $(MeIm)_2ZnCl_2$, > $(MeIm)_2FeCl_2$ > $(MeIm)_2CuCl_2$. These results are in accord with the experimentally obtained activity order of the different metal containing ionic liquid catalysts.

본 연구에서는 세 가지 형태의 금속을 함유한 이온성 액체 촉매를 제조하고, 다양한 물리화학적 분석법으로 제조된 촉매의 특성분석을 실시하였다. 프로필렌 옥사이드(PO)와 이산화탄소의 부가반응을 통한 프로필렌 카보네이트(PC)의 합성반응에서 세 가지 촉매의 반응활성을 확인하였고 속도론적 연구를 통해 촉매들의 반응성 차이를 비교하였다. 세가지 금속이 다른 촉매에 대한 유사 반응속도 상수($K_{app}$)는 $(MeIm)_2ZnCl_2$, > $(MeIm)_2FeCl_2$ > $(MeIm)_2CuCl_2$의 순서이며, 이 것은 세 가지 촉매의 반응성이 $(MeIm)_2ZnCl_2$ > $(MeIm)_2FeCl_2$ > $(MeIm)_2CuCl_2$의 순서로 실험결과와 잘 일치하였다.

Keywords

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