• 한국진공학회지
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• 제16권1호
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• pp.1-6
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• 2007

우리는 O/Fe(100)의 원자적 구조와 MgO/Fe(100) 표면의 계면의 구조를 LEED I/V curve를 이용하여 분석하였다. 산소를 Fe(100) 표면에 흡착시켰을 때 Fe 표면의 첫 번째 층간 간격은 약 16 % 정도 팽창하는 것을 확인하였다. 1ML MgO를 Fe(100) 표면에 성장하였을 때, MgO의 O가 Fe의 on-top 위치에 자라나는 것을 확인하였고, MgO/Fe 계면의 층간 간격이 확장되는 것을 확인하였다. AIA(average intensity mixing approximation) 계산을 사용하여 단층 MgO 성장한 Fe(100) 계의 계면구조는 MgO/FeO/Fe(100)와 MgO/Fe(100)의 계면구조를 갖는 것을 확인하였다. 이것은 확장된 FeO 층의 존재를 보이고 MgO/FeO/Fe(100)와 MgO/Fe(100) 두가지 계면 구조의 공존을 보인 EELS 실험 결과를 뒷받침 한다.

• 한국세라믹학회지
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• 제32권2호
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• pp.234-238
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• 1995

MgFe2O4 formation, grain growth in Fe2O3, Fe solid-solution limit in MgO for MgO-Fe2O3 mixture were studied by means of investigating the distribution of phases and compositions in reaction area between MgO and Fe2O3. The reaction area at equlibrium was composed with MgO-FexO matrix and MgFe2O4 precipitation, MgFe2O4 was formed by precipitating from MgO-FexO matrix dependent on oxygen partial pressure. Fe contents was exponentially decreased with diffusion distance in MgO single crystal, and thus Fe solid-solution limitation in MgO was about 4mol%. The grain growth rate in Fe2O3 base was increased with Mg contents diffused from MgO single crystal.

• 한국세라믹학회지
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• 제34권7호
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• pp.738-746
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• 1997

MgO clinker and two kinds of dolomite clinkers with different microstructures and CaO contents were used as starting materials, and the effects of Fe2O3 addition on the properties of MgO and dolomite were investigated in the range of 2 to 8 wt% of Fe2O3 content. Secondary phases contributed to densification of MgO-Fe2O3 and dolomite-Fe2O3 were magnesioferrite and dicalciumferrite, respectively. Sinterabilities of MgO-Fe2O3 and dolomite-Fe2O3 were directly proportional to the amount of secondary phases. Also, sinterability of dolomite itself was dependent on the microstructure of starting material including distribution of CaO and MgO as well as the addition amount of Fe2O3. The flexural strength of MgO-Fe2O3 content was almost constant. The hydration resistance of dolomite with large size of MgO and discontinuous distribution of CaO was higher than that of dolomite with small size of MgO and continuous distribution of CaO. Also, the minimum content of Fe2O3 to prevent they hydration of dolomite was about 4wt%. As increasing Fe2O3 content, the penetration resistance of MgO-Fe2O3 was improved by the increment of magnesioferrite. On the other hand, the penetration resistance of dolomite-Fe2O3 was decreased because of the increment of dicalciumferrite having low melting point.

• 대한화학회지
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• 제25권5호
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• pp.318-324
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• 1981

일차입자의 크기와 응집상태가 다른 두 종류의 $Fe_2O_3$를 부분침전법과 ball-mill 혼합법으로 BaCO$_3$와 혼합한 $BaCO_3-Fe_2O_3$계의 고체반응에 있어 $Fe_2O_3$분체의 영향을 조사하였다. TG, XRD, SEM 등을 측정에 사용하였으며, X-선 회절분석결과 Ba-ferrite의 생성과정은 다음과 같은 연속적인 2단계로 이루어진다는 것을 알았다. $BaCO_3 + 6Fe_2O_3\;{\longrightarrow}\;BaFe_2O_3 + 5Fe_2O_3 + CO_2{\uparrow}\;BaFe_2O_4 + 5Fe_2O_3 \;{\longrightarrow}\;BaFe_{12}O_{19}$ 또 $Fe_2O_3$원료분체의 응집상태와 혼합방법은 고체반응에 현저한 영향을 미친다는 것을 확인했다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.366-366
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• 2010

Single crystalline Fe/NiO bilayers were epitaxially grown on Ag(001) and on MgO(001), and investigated by Low Energy Electron Diffraction (LEED), Magneto-Optic Kerr Effect (MOKE), and X-ray Magnetic Linear Dichorism (XMLD). We find that while the Fe film has an in-plane magnetization in both Fe/NiO/Ag(001) and Fe/NiO/MgO(001) systems, the NiO spins switch from out-of-plane direction in Fe/NiO/MgO(001) to in-plane direction in Fe/NiO/Ag(001). These two different NiO spin orientations generate remarkable different effects that the NiO induced magnetic anisotropy in the Fe film is much greater in Fe/NiO/Ag(001) than in Fe/NiO/MgO(001). XMLD measurement shows that the much greater magnetic anisotropy in Fe/NiO/Ag(001) is due to a 90o-coupling between the in-plane NiO spins and the in-plane Fe spins which causes a switching of the NiO spins during the Fe magnetization reversal.

• 한국재료학회지
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• 제22권11호
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• pp.620-625
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• 2012

A general synthetic method to make $Fe_3O_{4-{\delta}}$ (activated magnetite) is the reduction of $Fe_3O_4$ by $H_2$ atmosphere. However, this process has an explosion risk. Therefore, we studied the process of synthesis of $Fe_3O_{4-{\delta}}$ depending on heat-treatment conditions using $FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. The thermal decomposition characteristics of $FeC_2O_4{\cdot}2H_2O$ and the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ were analyzed with TG/DTA in Ar atmosphere. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method using $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$. The concentration of the solution was 0.1 M and the equivalent ratio was 1.0. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed to $H_2O$ and $FeC_2O$4 from $150^{\circ}C$ to $200^{\circ}C$. $FeC_2O4$ was decomposed to CO, $CO_2$, and $Fe_3O_4$ from $200^{\circ}C$ to $250^{\circ}C$. Single phase $Fe_3O_4$ was formed by the decomposition of ${\beta}-FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. However, $Fe_3C$, Fe and $Fe_4N$ were formed as minor phases when ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed in $N_2$ atmosphere. Then, $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by decomposion of CO. The reduction of $Fe_3O_4$ to $Fe_3O_{4-{\delta}}$ progressed from $320^{\circ}C$ to $400^{\circ}C$; the reaction was exothermic. The degree of exothermal reaction was varied with heat treatment temperature, heating rate, Ar flow rate, and holding time. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was greatly influenced by the heat treatment temperature and the heating rate. However, Ar flow rate and holding time had a minor effect on ${\delta}$-value.

• 한국진공학회지
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• 제11권4호
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• pp.240-248
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• 2002

결정성이 좋을 것으로 기대되는 Fe이 도핑된 $Fe_{x}Ti_{l-x}O_2$박막 (x=0.07과 0.16)을 rutile $TiO_2$(110) 기판위에 산소 플라즈마 적층 성장 방법으로 성장시켰다. 도핑되는 Fe의 함량에 따른 표면 특성을 규명하기 위하여 박막 성장은 같은 조건에서 이루어졌다. 여러 가지의 표면분석법을 이용하여 성장된 박막의 표면 특성을 규명하였다. $Fe_{x}Ti_{l-x}O_2$박막에 존재하는 Ti의 산화상태는 +4 이었고 Fe의 경우는 +2와 +3의 산화상태가 섞여있었으며 Fe의 함량이 높은 $Fe_{0.16}Ti_{0.84}O_2$박막에서 $Fe^{3+}$ 이온의 함량이 더 높은 것으로 나타났다. $Fe_{0.07}Ti_{0.93}O_2$박막은 기판과 유사한 평탄한 표면에 막대형과 원통형의 높은 island 형태로 성장되었다. $Fe_{0.16}Ti_{0.84}O_2$박막은 $Fe_{0.07}Ti_{0.93}O_2$ 박막보다는 평탄하지만 적은 island들이 뭉쳐있는 다소 거칠은 표면을 한 다결정성 형태로 성장되어 Fe의 함량에 따라 morphology가 다르게 나타났다.

• 한국세라믹학회지
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• 제31권2호
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• pp.213-219
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• 1994

The formations of spinel and colors of ZnO-Fe2O3-TiO2-SnO2 system have been researched on the basis of ZnO-Fe2O3 system. Specimens were prepared by substituting Fe3+, with Ti4+ or Sn4+ when mole ratios between Fe3+ and Ti4+ or between Fe3+ and Sn4+ were 0.2 mole. The reflectance measurement and X-ray diffraction analysis of the formation of spinel and the colors of there specimens were carried out. ZnO-Fe2O3 system in which Fe2O3 was substituted with SnO2 and TiO2 was formed the spinel structure of 2ZnO.TiO2, 2ZnO.SnO2, ZnO.Fe2O3. The stable stains which were colored with yellow and brown could be manufactured.

• 산업기술연구
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• 제36권
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• pp.77-81
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• 2016

Superparamagnetic $Fe_3O_4$ nanoparticles with particle size from 10 to 20 nm were synthesized by coprecipitation method. Subsequently, the $Fe_3O_4$ nanoparticles were used to fabricate $Fe_3O_4/SiO_2$ core-shell nanoparticles by sol-gel method. The $Fe_3O_4/SiO_2$ nanoparticles synthesized by sol-gel method exhibit the high uniformities of particle size and shape. We also investigated the heating characteristics of $Fe_3O_4$ and $Fe_3O_4/SiO_2$ nanoparticles for biomedical applications. The $Fe_3O_4$ nanoparticles show the faster temperature increase and the higher specific loss power(SLP) value than the $Fe_3O_4/SiO_2$ nanoparticles.

• Elastomers and Composites
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• 제44권4호
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• pp.408-415
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• 2009

졸-겔 방법을 사용하여 Fe-ACF/$TiO_2$ 복합체 광촉매를 제조하였다. 여러 가지 철 전구체를 사용하여 세가지 Fe-ACF/$TiO_2$ 복합체를 제조하고 BET, SEM, XRD 및 EDX를 사용하여 특성화 하였다. UV 조사에서 Rh.B 용액의 분해에 의거하여 Fe-ACF/$TiO_2$ 복합체의 광촉매 특성을 파악 하였다. 실험 결과로부터, Fe-ACF/$TiO_2$ 복합체는 ACF/$TiO_2$ 복합체 보다 Rh.B의 제거 효과가 더 우수함을 나타내었다. 또한 여러 가지 Fe 전구체 사용으로 인한 Fe 원소의 포토-펜톤 효과는 다르게 나타났다. $FeCl_3$을 사용하여 제조된 Fe-ACF/$TiO_2$ 복합체는 가장 우수한 포토-펜톤 효과를 나타내었고, pH 변화에 의존하여 Rh.B 용액 분해에 대하여 영향을 주었다.