• Title/Summary/Keyword: FeMo-co

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The Sensor Response for CO Gas of $LaMO_3$ and $LaFe_{1-x}CO_xO_3$ in Perovskite Type Oxides (Perovskite형 산화물 $LaMO_3$$LaFe_{1-x}CO_xO_3$의 일산화탄소가스에 대한 센서 응답 특성)

  • 임병오;손태원;권동혁
    • Journal of the Korean Society of Safety
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    • v.3 no.1
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    • pp.7-13
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    • 1988
  • The oxides in perovskite type, $LaMO_3$ (M=Ni, Cr, Fe, Co), compared with gas sensors which have been used, were synthesised and then examined sensor response comparatively in order to make a thick film gas sensor having a good gas selectivity, durability and simple manufacturing. The oxides in perovskite type, $LaFe_{1-x}O_3$ (x=0.2, 0.4, 0.6, 0.8), which a part of Fe was replaced with Co, were examined with regard to their electric resistance with variable temperature and sensor response for carbon monoxide gas.

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Manufacture of Pt-transition Metal Alloy Catalyst for PAFC (PAFC용 합금 촉매 제조)

  • Kim, Yeong-Woo;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.692-700
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    • 1993
  • Corrosivities and catalytic activities of platinum-transition metal alloy catalyses loaded on carbon substrate and were studied by electrochemical method using a unit cell. And the analysis of Pt-alloy catalyst was conducted by x-ray diffractometer. Among the catalysts, the Pt-Mo/carbon, Pt-Fe-Co/carbon and Pt-Fe/carbon catalyst showed more excellent cathodic current densities than others. It was found that most of cathodic current density for the Pt-Mo/carbon electrode was $120mA/cm^2$. The current density of the Pt-Fe-Co/carbon was much higher than that of Pt/carbon, reaching $200mA/cm^2$.

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Magnetoresistance Properties of Spin Valves Using MoN Underlayer (MoN 하지층을 이용한 스핀밸브의 자기저항 특성)

  • Kim, Ji-Won;Jo, Soon-Chul;Kim, Sang-Yoon;Ko, Hoon;Lee, Chang-Woo
    • Journal of the Korean Magnetics Society
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    • v.16 no.5
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    • pp.240-244
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    • 2006
  • In this paper, magnetic properties and annealing behavior of spin valve structures using Mo(MoN) layers as underlayers were studied varying the thickness of the underlayers. The spin valve structure was consisted of Si substrate/$SiO_2(2,000{\AA})/Mo(MoN)(t{\AA})/NiFe(21\;{\AA})/CoFe(28\;{\AA})/Cu(22\;{\AA})/CoFe(18\;{\AA})/IrMn(65\;{\AA})/Ta(25\;{\AA})$. Also, MoN films were deposited on Si substrates and their thermal annealing behavior was analyzed. The resistivity of the MoN film increased as the $N_2$ gas flow rate was increased. After annealing at $600^{\circ}C$, XRD results did not show peaks of silicides. XPS results indicated MoN film deposited with 5 sccm of $N_2$ gas flow rate was more stable than the film deposited with 1 sccm of $N_2$ gas flow rate. The variations of MR ratio and magnetic exchange coupling fold were small for the spin valve structures using Mo(MoN) underlayers up to thickness of45 ${\AA}$. MR ratio of spin valves using MoN underlayers deposited with various $N_2$ gas flow rate was about 7.0% at RT and increased to about 7.5% after annealing at $220^{\circ}C$. Upon annealing at $300^{\circ}C$, the MR ratio decreased to about 3.5%. Variation of $N_2$ gas flow rate up to 5 sccm did not change the MR ratio and $H_{ex}$ appreciably.

Dependence of Magnetoresistance on the Underlayer Thickness for Top-type Spin Valve (Top형 스핀밸브 구조의 Si 기판에서의 하지층 두께에 따른 자기저항 특성 연구)

  • Ko, Hoon;Kim, Sang-Yoon;Kim, Soo-In;Lee, Chang-Woo;Kim, Ji-Won;Jo, Soon-Chul
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.95-98
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    • 2007
  • In this paper, the magnetic properties and the annealing behavior of spin valve structures with Mo(MoN) underlayers were studied for various underlayer thickness. The spin valve structure was Si substrate/Mo(MoN)$(t{\AA})/NiFe(21{\AA})/CoFe(28{\AA})/Cu(22{\AA})/CoFe(18{\AA})/IrMn(65{\AA})/Ta(25 {\AA})$. Mo and MoN films were deposited on Si substrates and their thermal annealing behavior was analyzed. The deposition rate of the MoN thin film was decreased and tile resistivity of the MoN thin films were increased as the $N_2$ gas flow was increased. The variations of MR ratio and magnetic exchange coupling field of spin valve structure were smaller with MoN underlayers than that with Mo underlayers up to thickness of $51{\AA}$. MR ratio of spin valves with Mo underlayers was 2.86% at room temperature and increased up to 2.91 % after annealing at $200^{\circ}C$. Upon annealing at $300^{\circ}C$, the MR ratio decreased about 2.16%. The MR ratio of spin valves structure with MoN underlayers for $N_2$ gas flow 1 sccm was 5.27% at room temperature and increased up to 5.56% after annealing at $200^{\circ}C$. Upon annealing at $300^{\circ}C$, the MR ratio decreased about 4.9%.

Effect of Mo-doped LiFePO4 Positive Electrode Material for Lithium Batteries

  • Oh, Seung-Min;Sun, Yang-Kook
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.172-177
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    • 2012
  • Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

Fabrication of Iron-Molybdenum Alloyed Nanoparticle and Nanowire using Chemical Vapor Condensation(CVC) (화학적 기상 응축(CVC)법을 이용한 철-몰리브덴합금 나노 입자와 와이어의 제조)

  • Ha, Jong-Keun;Cho, Kwon-Koo;Kim, Ki-Won;Ryu, Kwang-Sun
    • Journal of Powder Materials
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    • v.17 no.3
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    • pp.223-229
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    • 2010
  • Iron(Fe)-Molybdenum(Mo) alloyed nanoparticles and nanowires were produced by the chemical vapor condensation(CVC) process using the pyrolysis of iron pentacarbonyl($Fe(CO)_5$) and Molybdenum hexacarbonyl($Mo(CO)_6$). The influence of CVC parameter on the formation of nanoparticle, nanowire and size control was studied. The size of Fe-Mo alloyed nanoparticles can be controlled by quantity of gas flow. Also, Fe-Mo alloyed nanowires were produced by control of the work chamber pressure. Moreover, we investigated close correlation of size and morphology of Fe-Mo nanoparticles and nanowires with atomic quantity of inflow precursor into the electric furnace as the quantitative analysis. Obtained nanoparticles and nanowires were investigated by field emission scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction.

Effects of DTPA on Microelements in Soybean and Bush Bean (대두 및 강낭콩내 미량원소의 농도 및 분포에 미치는 DTPA의 영향)

  • 차종환
    • Journal of Plant Biology
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    • v.16 no.3_4
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    • pp.40-44
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    • 1973
  • Hawkeye(Fe-chlorosis resistant) and PI 54619-5-1(Fe-chlorosis sensitive) soybeans were grown with and without DPTA(diethylene triamine pentaacetic acid) in Yolo loam soil. The major purpose of the study was to compare leaf-stem distribution of microelements for different treatments which increase concentrations of microelements in plants to evaluate the role of the chelating agent in increasing translocation of the microelements. Plant responses and yields were recorded and Fe, Mn, Zn, Cu, Al, Co, N, Sn, Pb and Mo contents of leaves and stems were determined by emission spectrography. Sulfur(soil pH4) increased leaf concentrations of Mn, Zn, Cu, CO, Ni, Sn and Pb. DTPA, particularly at 50ppm in soil, increased leaf concentrations of Fe, Mn, Zn, Cu, Co, Ni and Mo. It increased Ti in leaves for the PI 54619-5-1 soybeans only. DTPA increased the ratios of the concentration in leaves to that in stems for Fe, Zn, Cu, Al, Ti, CO, Ni and Mo. Sulfur which increased the microelement concentration in both leaves and stems did not have this effect. DTPA increased the ratio at soil pH 6 and 8.5 in leaves to that in stems of the bush bean plants for Fe, Zn, Cu, Ni, but to a lesser extent in bush beans than in soybeans. PI 54619-5-1 soybeans tended to contain less of most of the metals than did Hawkeye soybeans.

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The characteristics of grown carbon nanotubes by controlled catalyst preparation at the catalytic chemical vapor deposition (촉매제어를 통한 촉매화학기상증착법으로 성장시킨 탄소나노튜브의 특성분석)

  • Kim, Jong-Sik;Kim, Gwan-Ha;Kim, Chang-Il
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1378-1379
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    • 2006
  • Carbon nanotubes (CNTs) with few defects and very small amount of amorphous carbon coating have been synthesized by catalytic decomposition of acetylene in $H_2$ over well-dispersed metal particles supported on MgO. The yield, quality and diameters of CNTs were obtained by control of catalyst metal compositions to be used. The optimization condition of carbon nanotubes with high yield is when Co and Mo are in a 1:1 ratio and Fe metal contents to Co is increased on magnesium oxide support. It is also found that the diameter of the as-prepared CNTs can be controlled mainly by adjusting the molar ratio of Fe-Mo, Co-Fe, and Co-Mo versus the MgO support. Our results indicated that desired diameter distribution of CNTs is obtained by choosing or combining the catalyst to be employed.

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