• 제목/요약/키워드: FeMn/NiFe

검색결과 768건 처리시간 0.026초

Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si 합금의 고온 산화에 미치는 S의 영향 (Effect of Sulfur on the High-temperature Oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si Alloys)

  • 이동복;이경환;배근수;조규철;정재옥;김민정
    • 한국표면공학회지
    • /
    • 제50권5호
    • /
    • pp.386-391
    • /
    • 2017
  • Two kinds of steels whose compositions were Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) were centrifugally cast, and oxidized at $900^{\circ}C$ for 50-350 h in order to find the effect of sulfur on the high-temperature oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) alloys. These alloys formed oxide scales that consisted primarily of $Cr_2O_3$ as the major oxide and $Cr_2MnO_4$ as the minor one through preferential oxidation of Cr and Mn. They additionally formed $SiO_2$ particles around the scale/alloy interface as well as inside the matrices. The high affinity of Mn with S led to the formation of scattered MnS inclusions particularly in the 0.35S-containing cast alloy. Sulfur was harmful to the oxidation resistance, because it deteriorated the scale/alloy adherence so as to accerelate the adherence and compactness of the formed scales.

The Effect of Long-term Administration of Green Juice of Angelica Keiskei Koidz on the Contents of Several Selected Elements of the Mouse Organs

  • Song, Sook-Ja
    • Journal of Nutrition and Health
    • /
    • 제30권9호
    • /
    • pp.1045-1049
    • /
    • 1997
  • In order to study the content of selected elements in the organs of the mice, mice were fed with green juice of Angelica keiskei Koidz for 16 weeks. The results obtained from the experiments are summarized as follows : 1) The element contents(cr, Mn, Ni, Cu, Zn, Cd, Ba, Pb, and Fe) in the whole plant are generally the same as those the previous reports. 2) The element contents(Cr , Mn, Ni, Cu, Zn, Cd, Ba, Pb and Fe) in the green juice did not exceed those of the edible water standard. 3) The element contents (Cr, Mn, Ni, Cu, Zn, Cd, Ba, Pb and Fe) in the brain is slightly higher than those in the whole plants. 4) The element contents(Cr, Ni, Pb and Fe) in the organs of the mice fed green juice for 16 weeks are the same as those of the previous reports.

  • PDF

Fe-Ni-Mn-(Ti)계 마르에이징강에서 역변태 오스테나이트의 거동 (Behavior of Reverted Austenite in Fe-Ni-Mn-(Ti) Maraging Steels)

  • 김성준
    • 분석과학
    • /
    • 제6권1호
    • /
    • pp.141-147
    • /
    • 1993
  • Fe-Ni-Mn-(Ti)계 마르에이징강을 용체화처리한 후 $400^{\circ}C$부터 $550^{\circ}C$ 사이에서 장시간 시효처리할 때 생성되는 역변태 오스테나이트의 거동을 투과전자현미경 및 분석전자현미경을 이용하여 관찰하였다. 시효온도와 시간에 따라 Widmanstatten, granular, lath-like 및 재결정 오스테나이트 등 4 종류의 역변태 오스테나이트가 관찰되었으며, 역변태 오스테나이트들은 기지조직인 마르텐사이트보다 많은 니켈과 망간을 함유하고 있었다. Widmanstatten과 lath-like 오스테나이트는 기지 조직과 일정한 방위관계를 이루고 있으며 방위관계는 시효조건과 합금조성에 따라 달라진다. 재결정 오스테나이트는 $550^{\circ}C$ 이상의 고온에서 시효할 때 생기지만 불안정하여 냉각시 다시 마르텐사이트로 변태되는 경우도 발견되었다.

  • PDF

Fe-Cr-Ni-Mn 2 상 스테인레스강의 인장성질에 미치는 변형온도 및 Mn 함량변화의 영향 (Effect of Deformation Temperature and Manganese Contents on the Tensile Properties of Fe-Cr-Ni-Mn Duplex Stainless Steel)

  • 강창룡;성장현
    • 열처리공학회지
    • /
    • 제4권4호
    • /
    • pp.44-52
    • /
    • 1991
  • The effect of deformation temperature and manganes contents on the tensile properties of duplex stainless steels with the structure of both ferrite and austenite were investigate. For this investigation, Fe-19% Cr-5% Ni-4~8% Mn alloys were prepared. The result obtained from this experiment are summerized as follows. With decreasing deformation temperature, tensile strengths of duplex stainless steel increased. Elongation showd to be increased and then decreased after representing the highest value at specific temperature. Tensile properties of duplex stainless steel were controlled by TRIP behavior in this experimental range of austenite contents. Tensile strengths decreased with increasing Mn contents. With increasing Mn contents, elongation decreased in the high temperature region, but increased in the low temperature region. The peak temperature representing the maximum elongation were changed to low temperature and the width of peak appeared to be broaden with increasing Mn contents.

  • PDF

Ni-MH 2차 전지용 Zr계 수소저장합금전극의 특성에 미치는 치환원소(Co, Cr, Fe)의 영향 (The effect of substitution elements(Co, Cr, Fe) on the properties of Zr-based hydrogen storage alloy electrode for Ni-MH secondary battery)

  • 최승준;정소이;서찬열;최전;박충년
    • 한국수소및신에너지학회논문집
    • /
    • 제10권3호
    • /
    • pp.185-189
    • /
    • 1999
  • Effects of alloy modification with the $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy for an electrode use have been investigated. For the alloy composition, a part of Mn was substituted by Co, Cr and Fe. The experimental results showed that Co accelerated activation of alloy, and Fe and Cr improved the discharge capacity. These results agree with P-C-T curves of each alloy. But substituting Fe for Mn showed the decrease of the discharge capacity when discharged at high rate (60mA, about 1C rate). Considering both the discharge capacity and the high rate discharge property, $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy was found to be the best alloy among the alloys subjected to the test.

  • PDF

대두 및 강낭콩내 미량원소의 농도 및 분포에 미치는 DTPA의 영향 (Effects of DTPA on Microelements in Soybean and Bush Bean)

  • 차종환
    • Journal of Plant Biology
    • /
    • 제16권3_4호
    • /
    • pp.40-44
    • /
    • 1973
  • Hawkeye(Fe-chlorosis resistant) and PI 54619-5-1(Fe-chlorosis sensitive) soybeans were grown with and without DPTA(diethylene triamine pentaacetic acid) in Yolo loam soil. The major purpose of the study was to compare leaf-stem distribution of microelements for different treatments which increase concentrations of microelements in plants to evaluate the role of the chelating agent in increasing translocation of the microelements. Plant responses and yields were recorded and Fe, Mn, Zn, Cu, Al, Co, N, Sn, Pb and Mo contents of leaves and stems were determined by emission spectrography. Sulfur(soil pH4) increased leaf concentrations of Mn, Zn, Cu, CO, Ni, Sn and Pb. DTPA, particularly at 50ppm in soil, increased leaf concentrations of Fe, Mn, Zn, Cu, Co, Ni and Mo. It increased Ti in leaves for the PI 54619-5-1 soybeans only. DTPA increased the ratios of the concentration in leaves to that in stems for Fe, Zn, Cu, Al, Ti, CO, Ni and Mo. Sulfur which increased the microelement concentration in both leaves and stems did not have this effect. DTPA increased the ratio at soil pH 6 and 8.5 in leaves to that in stems of the bush bean plants for Fe, Zn, Cu, Ni, but to a lesser extent in bush beans than in soybeans. PI 54619-5-1 soybeans tended to contain less of most of the metals than did Hawkeye soybeans.

  • PDF

Fe-Ni-Co 코바 합금의 고온변형거동에 미치는 합금원소(Mn, Mo, B) 첨가의 영향 (Effect of Alloying Elements(Mn, Mo, B) on the High Temperature Deformation Behavior of Low Thermal Expansion Fe-Ni-Co Alloy)

  • 이기안;윤애천;박중철;남궁정;김문철
    • 소성∙가공
    • /
    • 제17권4호
    • /
    • pp.240-248
    • /
    • 2008
  • The effect of alloying elements(Mn, S, Mo, B) on the high temperature deformation behavior of Fe-29%Ni-17%Co (Kovar) alloy were investigated. And the effect of high temperature oxidation on the hot ductility was also studied. The hot ductility of Kovar alloy was drastically increased with the addition of Mn and lowering of S content. It has been found that the brittle intergranular fracture at high temperature cracking is closely associated with the FeS sulfide along the grain boundary. When Mn was added, the type of sulfide was changed to MnS from FeS and ductile intergranular fracture and transgranular fracture were promoted. The formation of oxide layer was found to have minimized the hot ductility of the Kovar alloy significantly. Grain boundary micro-cracks in the internal oxide region were noted following deformation due to high temperature, one of which acting as a notch that caused the poor hot workability of the oxidized specimen. The addition of Mo to the Kovar alloy could also retard the decrease in the hot ductility of the oxidized specimen through the prevention of notching due to internal oxidation. Hot ductility was remarkably improved by the addition of Boron. The improvement of hot ductility results from the grain boundary migration mainly due to the dynamic recrystallization at lower temperature range ($900{\sim}1000^{\circ}C$).

물 분해 수소제조를 위한 금속산화물들의 반응특성 (The Properties of the Several Metal Oxides in the Water-splitting for H2 Production)

  • 손현명;박주식;이상호;황갑진;김종원;이진배
    • 한국수소및신에너지학회논문집
    • /
    • 제14권3호
    • /
    • pp.268-275
    • /
    • 2003
  • The water-splitting process by the metal oxides using solar heat is one of the hydrogen production method. The hydrogen production process using the metal oxides (NiFe2O4/NiAl2O4,CoFe2O4/CoAl2O4, CoMnNiFerrite, CoMnSnFerrite, CoMnZnFerrite, CoSnZnFerrite) was carried out by two steps. The first step was carried out by the CH4-reduction to increase activation of metal oxides at operation temperature. And then, it was carried out the water-splitting reaction using the water at operation temperature for the second step. Hydrogen was produced in this step. The production rates of H2 were 110, 160, 72, 29, 17, $21m{\ell}/hr{\cdot}g-_{Metal\;Oxide}$ for NiFe2O4/NiAl2O4, CoFe2O4/CoAl2O4, CoMnNiFerrite, CoMnSnFerrite, CoMnZnFerrite, CoSnZnFerrite respectively in the second step. CoFe2O4/CoAl2O4 had higher H2 production rate than the other metal oxides.