• 제목/요약/키워드: FeAl intermetallic

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Sm 첨가에 따른 Al-Si-Cu 알루미늄 합금의 미세조직 및 열전도도 변화 (Effect of Samarium Addition on Microstructure and Thermal Conductivity of Al-Si-Cu Aluminum Alloy)

  • 최진주;강유빈;임병용;이찬기;김한구;박광훈;김대근
    • 한국재료학회지
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    • 제30권1호
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    • pp.31-37
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    • 2020
  • In this study, the effects of Sm addition (0, 0.05, 0.2, 0.5 wt%) on the microstructure, hardness, and electrical and thermal conductivity of Al-11Si-1.5Cu aluminum alloy were investigated. As a result of Sm addition, increment in the amount of α-Al and refinement of primary Si from 70 to 10 ㎛ were observed due to eutectic temperature depression. On the other hand, Sm was less effective at refining eutectic Si because of insufficient addition. The phase analysis results indicated that Sm-rich intermetallic phases such as Al-Fe-Mg-Si and Al-Si-Cu formed and led to decrements in the amount of primary Si and eutectic Si. These microstructure changes affected not only the hardness but also the electrical and thermal conductivity. When 0.5 wt% Sm was added to the alloy, hardness increased from 84.4 to 91.3 Hv, and electric conductivity increased from 15.14 to 16.97 MS/m. Thermal conductivity greatly increased from 133 to 157 W/m·K.

마찰교반접합한 알루미늄 합금과 스테인리스 강 이종접합부 계면 조직 및 접합부 강도 (Interface Analysis and Mechanical Properties of Friction Stir Welded Dissimilar joints between Stainless steel and AI alloy)

  • 이원배;이창용;연윤모;정승부
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2005년도 추계학술발표대회 개요집
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    • pp.189-191
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    • 2005
  • Dissimilar joining of AI 6013-T4 alloys and austenite stainless steel was carried out using friction stir welding technique. Microstructures near the weld zone and mechanical properties of the joint have been investigated. Microstructures in the stainless steel side and AI alloy were depended on the thermo-mechanical condition which they received. TEM micrographs revealed that the interface region was composed of the mixed layers of elongated stainless steel and ultra-fine grained AI alloy and intermetallic compound layer which was identified as the $Al_{4}Fe$ with hexagonal close packed structure. Mechanical properties were lower than those of 6013 AI alloy base metal, because tool inserting location was deviated to AI alloy from the butt line, which resulted in the lack of the stirring.

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熔融알루미늄 鍍金한 鋼板의 機械的 性質에 關한 硏究 (A Study on Mechanical properties of Aluminized Steel Plate)

  • 김석윤;최종술
    • 한국표면공학회지
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    • 제13권2호
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    • pp.81-86
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    • 1980
  • The mechanical properties of aluminized steel were investigated after the JIS SB 41 plates were dipped in molten aluminum bath. (1) The growth rate of iron-aluminum alloy layer was fast in early stage of alumizing, and then gradually decreased with increasing time. However, over the time period above 10 minutes the growth of alloy layer did not occur. (2) The constituent of alloy layer formed on the steel surface was identified to be intermetallic compound of $Fe_2\;Al_5$. (3) The ultimate tensile strength and elongation of aluminized steel showed a nearly constant value over all thickness below about 0.15 mm. However, both properties decreased rapidly in showed a nearly constant value over all thickness above about 0.20 mm. (4) In case of aluminized steel with greater thickness, crack was formed below yield point of base metal, which is considered to be attributed to the alloy layer failure.

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용융Al-Si도금 강재에 형성한 Cr 막의 고온 환경 중 내식특성 (Corrosion resistance at high temperature condition of Cr Films Formed on hot-dip Al-Si plated steel sheet)

  • 강민주;이승효;이명훈
    • 한국표면공학회지
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    • 제55권6호
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    • pp.448-459
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    • 2022
  • Generally, steel is the most commonly used in the industry because of good strength, processability and cost-effectiveness. Steel can be surface-treated such as coating or used as an alloy by adding elements such as Cr, Ni, Zr, and Al to increase corrosion resistance. However, even if steel is used in same environment corrosion resistance is sharply lowered when it is exposed to a high temperature for a fixed or extended period of time due to an overload or other factors. In particular, the use of hot-dip aluminized plated steel, which is used in high-temperature atmospheres, is increasing due to the surface Al2O3 oxide film. This steel necessitates an urgent solution as issues of corrosion resistance limitations often appear. It is an important issue that not only cause analysis but also the research for the surface treatment method that can be solved. Thus, in this study, Cr in which it is expected to be effective in corrosion resistance and heat resistance attempted to deposit on hot dip aluminized plated steel with PVD sputtering. And it was possible to present the surface treatment application of various types of industrial equipment exposed to high temperature and basic design guidelines for use by confirming the corrosion resistance of hot dip Al-Si plated steel with Cr film deposited at high temperature.

자동차 부품용 내열 알루미늄 합금의 고온 피로 변형 거동 (High Temperature Fatigue Deformation Behavior of Automotive Heat Resistant Aluminum Alloys)

  • 박종수;성시영;한범석;정창렬;이기안
    • 대한금속재료학회지
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    • 제48권1호
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    • pp.28-38
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    • 2010
  • High temperature high cycle and low cycle fatigue deformation behavior of automotive heat resistant aluminum alloys (A356 and A319 based) were investigated in this study. The microstructures of both alloys were composed of primary Al-Si dendrite and eutectic Si phase. However, the size and distribution for eutectic Si phase varied: a coarse and inhomogeneous distributed was observed in alloy B (A319 based). A brittle intermethallic phase of ${\alpha}-Fe\;Al_{12}(Fe,Mn)_3Si_2$ was detected only in B alloy. Alloy B exhibited high fatigue life only under a high stress amplitued condition in the high cycle fatigue results, whereas alloy A showed high fatigue life when stress was lowered. With regard to the low-cycle fatigue result ($250^{\circ}C$) showing higher fatigue life as ductility increased, alloy A demonstrated higher fatigue life under all of the strain amplitude conditions. Fractographic observations showed that large porosities and pores near the outside surface could be the main factor in the formation of fatigue cracks. In alloy B. micro-cracks were formed in both the brittle intermetallic and coarse Si phasese. These micro-cracks then coalesced together and provided a path for fatigue crack propagation. From the observation of the differences in microstructure and fractography of these two automotive alloys, the authors attempt to explain the high-temperature fatigue deformation behavior of heat resistant aluminum alloys.

알루미늄과 마그네슘 첨가가 용융아연 도금강판 도금층의 미세조직과 경도에 미치는 영향 (Effects of Al and Mg on the Microstructure and Hardness of the Coating Layer of Hot-dip Galvanized Steel Sheet)

  • 성윤제;김동규;서준기;한경현;홍범기;김강민;허성욱;박성현;임재택;손승배;이석재;정재길
    • 열처리공학회지
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    • 제36권4호
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    • pp.198-205
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    • 2023
  • We investigated the effects of Al and Mg on the microstructure and hardness of the coating layer of galvanized steel sheets, by thermodynamic calculations, X-ray diffraction, scanning electron microscopy, and Vickers hardness tests of Zn-0.2Al, Zn-6Al-2Mg, and Zn-10Al-5Mg coating layers. Regardless of the alloy composition of the galvanizing bath, a Fe-Al layer was observed between the coating layer and steel sheet. The Zn-0.2Al coating layer consists of major h.c.p. Zn phase and minor f.c.c. Al phase. The fraction of f.c.c. Al phase (containing a significant amount of Zn) of the coating layer increases with increasing the chemical composition of Al of the galvanizing bath. The h.c.p. MgZn2 phase was formed in the Al/Mg-containing Zn-6Al-2Mg and Zn-10Al-5Mg coating layers, forming Zn-Al-MgZn2 eutectic microstructure. The primary MgZn2 phase was additionally formed in the Zn-10Al-5Mg coating layers containing high concentrations of Al and Mg. The Vickers hardness values of Zn-0.2Al, Zn-6Al-2Mg, and Zn-10Al-5Mg coating layers were 59.1 ± 1.2 HV, 161.2 ± 5.7 HV, and 215.5 ± 40.3 HV, respectively. The addition of Al and Mg increased the hardness of the coating layer by increasing the fraction of the Al phase (containing Zn) and MgZn2 intermetallic compound, which were harder than the Zn phase.

Iron Aluminide-$SiC_p$ 혼합 예비성형체를 사용한 Al합금기 복합재료의 내마모 특성 (Wear Resistance of Al Alloy Matrix Composites Using Porous Iron Aluminide-$SiC_p$ Preforms)

  • 차재상;오선훈;최답천
    • 한국주조공학회지
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    • 제23권1호
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    • pp.30-39
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    • 2003
  • Porous hybrid preforms were fabricated by reactive sintering using the compacts consisting of SiC particles, Fe and Al powders. Squeeze casting processing was employed to produce the composite in which the matrix phase is Al-Si7Mg. The microstructural change and wear resistance of the composites were investigated in terms of an amount of SiC particles. The wear loss was increased with increasing the contact pressure in the alloy containing SiC particles coated with Cu. The most drastic change was found to the specimen tested at 2.5 MPa of contact pressure. Concerning the alloys containing SiC particles coated with Ni-P, a drastic increase in the wear loss exhibited at 2 MPa of contact pressure in those alloys containing 4 and 8 wt. % of SiC particles coated with Ni-P. In the alloy containing 16 wt. % a proportional increase in wear loss was observed to the change of contact pressure. With respecting to the sliding velocity, the wear loss of the alloy containing SiC particles coated with Cu increased at the initial stage of wear process and then decreased. Similar result was found in the alloys containing SiC particles coated with Ni-P. On the basis of the present results obtained, it was found that wear resistance of the alloys tested was improved to show in the order of the alloy reinforced by coated SiC particles > by uncoated SiC particles > by intermetallic compound without SiC particles.

Minimizing Zinc Consumption In Hot-Dip Galvanizing Lines

  • Bright, Mark;Ellis, Suzanne
    • Corrosion Science and Technology
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    • 제10권2호
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    • pp.43-46
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    • 2011
  • Zinc consumption in a continuous galvanizing line is one of the highest operating cost items in the facility and minimizing zinc waste is a key economic objective for any operation. One of the primary sources of excessive loss of zinc is through the formation of top dross and skimmings in the coating pot. It has been reported that the top skimmings, manually removed from the bath, typically consist of more than 80% metallic zinc with the remainder being entrained dross particles ($Fe_2Al_5$) along with some oxides. Depending on the drossing practices and bath management, the composition of the removed top skimmings may contain up to 2 wt% aluminum and 1 wt% iron. On-going research efforts have been aimed at in-house recovery of the metallic zinc from the discarded top skimmings prior to selling to zinc recycling brokers. However, attempting to recover the zinc entrapped in the skimmings is difficult due to the complex nature of the intermetallic dross particles and the quality and volume of the recycled zinc is highly susceptible to fluctuations in processing parameters. As such, an efficient method to extract metallic zinc from top skimmings has been optimized through the use of a specialized thermo-mechanical process enabling a continuous galvanizing facility to conserve zinc usage on-site. Also, through this work, it has been identified that filtration of discrete dross particles has been proven effective at maintaining the cleanliness of the zinc. Future efforts may progress towards expanded utilization of filters in continuous galvanizing.

1000MPa급 DP강 MIG 아크 브레이징 접합부의 기계적 성질에 미치는 브레이징 전류의 영향 (Effects of Brazing Current on Mechanical Properties of Gas Metal Arc Brazed Joint of 1000MPa Grade DP Steels)

  • 조욱제;윤태진;곽승윤;이재형;강정윤
    • Journal of Welding and Joining
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    • 제35권2호
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    • pp.23-29
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    • 2017
  • Mechanical properties and hardness distributions in arc brazed joints of Dual phase steel using Cu-Al insert metal were investigated. The maximum tensile shear load was 10.4kN at the highest brazing current. It was about 54% compared to tensile load of base metal. This joint efficiency is higher than that of joint of DP steel using Cu-based filler metals which are Cu-Si, Cu-Sn. Fracture positions can be divided into two types. Crack initiation commonly occurred at three point junction among upper sheet, lower sheet and the fusion zone. However crack propagations were different with increasing the brazing current. In case of the lower current, it instantaneously propagated along with the interface between fusion zone and upper base material. On the other hand, in case of higher current, a crack propagation occurred through fusion zone. When the brazing current is low (60, 70A), the interface shape is flat type. However the interface shape is rough type, when the brazing current is high (80A). It is thought that the interface shapes were the reason why the crack propagations were different with brazing current. The interface was the intermetallic compounds which consisted of $(Fe,Al)_{0.85}Cu_{0.15}$ IMC formed by crystallization at $1200^{\circ}C$during cooling. Therefore the maximum tensile shear load and the fracture behavior were determined by a interface shape and effective sheet thickness of the fracture position.

Effect of Resistance Spot Welding Parameters on AA1100 Aluminum Alloy and SGACD Zinc coated Lap Joint Properties

  • Chantasri, Sakchai;Poonnayom, Pramote;Kaewwichit, Jesada;Roybang, Waraporn;Kimapong, Kittipong
    • International Journal of Advanced Culture Technology
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    • 제3권1호
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    • pp.153-160
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    • 2015
  • This article is aimed to study the effects of resistance spot welding (RSW) on the lap joint properties between AA1100 aluminum alloy and SGACD zinc coated steel and its properties. The summarized experimental results are as follows. The summarized experimental results are as follows. The optimum welding parameters that produced maximum tensile shear strength of 2200 N was a welding current of 95 kA, a holding time of 10 cycles, and a welding pressure of 0.10 MPa. Increasing of welding current, increased the tensile shear strength of the joint and also increased the amount of aluminum dispersion at the joint interface. The lap joint of steel over the aluminum (Type I) showed the higher joint tensile shear strength than a lap joint of aluminum over the steel (Type II). The indentation depth and the ratio of the indentation depth to the plate thickness decreased when the welding current was increased in the type I lap joint and also decreased when the welding current was decreased in the type II lap joint. The interface structure showed the formation of the brittle $FeAl_3$ intermetallic compound that deteriorated the joint strength.