• 동력기계공학회지
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• 제9권4호
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• pp.90-95
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• 2005

The wire-arc process is a low-cost thermal spray method simply utilizes electrical energy to melt the feedstock wire. It is more userful for field applications, especially to coat large surface area. In this paper, a special Fe-based alloy coatings by using the wire-arc process were developed. Nanoscale composite coatings were achieved either during spraying or through a post heat treatment. As-sprayed Fe-based alloy coatings had been an amorphous matrix structure, after heating to $700^{\circ}C$ for 10 minutes a solid state transformation occurred in the some fraction of amorphous matrix which resulted in the formation of nanostructured recrystallized phase. Scanning electron microscopy (SEM) and field emotional scanning electron microscope(FE-SEM) were applied to analyze the microstructure of the coatings. Additionally hardness and bend resistance of the Fe-based alloy coatings were examined, and these results were compared with those of partially stabilized zirconia(PSZ) coatings by using the plasma spray process.

• 한국전기전자재료학회논문지
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• 제32권4호
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• pp.341-348
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• 2019

This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as $Fe_2Al_3Si_3$, $FeSi_2$, and $Fe_{0.42}Si_{2.67}$, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately $700mAh^{g-1}$, and exhibited a high Coulombic efficiency of 99.0~99.6% from the $2^{nd}$ to $70^{th}$ cycles.

• 대한금속재료학회지
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• 제48권1호
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• pp.1-7
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• 2010

Experiments have demonstrated that the addition of a moderate amount of V to $Fe_{52}Co_{(20-x)}B_{20}Si_4Nb_4V_x$ amorphous alloy enhances the plasticity of the alloy. In particular, $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy withstood a maximum of 8.3% strain prior to fracture along with a strength exceeding 4.7 GPa. Energy dispersive x-ray spectroscopy conducted on the $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy exhibited evidence of compositional modulation, indicating that nm-scale phase separation had occurred at local regions. In this study, the role played by nm-scale phase separation on the plasticity was investigated in terms of structural disordering and shear localization in order to better understand the structural origin of the enhanced plasticity shown by the developed alloy.

• 한국재료학회지
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• 제23권3호
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• pp.190-193
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• 2013

Spatial distributions of alloying elements of an Fe-based amorphous ribbon with a nominal composition of $Fe_{75}C_{11}Si_2B_8Cr_4$ were analyzed through the atom probe tomography method. The amorphous ribbon was prepared through the melt spinning method. The macroscopic amorphous natures were confirmed using an X-ray diffractometer (XRD) and a differential scanning calorimeter (DSC). Atom Probe (Cameca LEAP 3000X HR) analyses were carried out in pulsed voltage mode at a specimen base temperature of about 60 K, a pulse to base voltage ratio of 15 %, and a pulse frequency of 200 kHz. The target detection rate was set to 5 ions per 1000 pulses. Based on a statistical analyses of the data obtained from the volume of $59{\times}59{\times}33nm^3$, homogeneous distributions of alloying elements in nano-scales were concluded. Even with high carbon and strong carbide forming element contents, nano-scale segregation zones of alloying elements were not detected within the Fe-based amorphous ribbon. However, the existence of small sub-nanometer scale clusters due to short range ordering cannot be completely excluded.

• 한국재료학회지
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• 제24권1호
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• pp.60-65
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• 2014

Fe-based amorphous coatings were fabricated on a soda-lime glass substrate by the vacuum kinetic spray method. The effect of the gas flow rate, which determines particle velocity, on the deposition behavior of the particle and microstructure of the resultant films was investigated. The as-fabricated microstructure of the film was studied by field emission scanning electron microscopy (FE-SEM) and high resolution transmission electron microscopy (HR-TEM). Although the activation energy for transformation from the amorphous phase to crystalline phase was lowered by severe plastic deformation and particle fracturing under a high strain rate, the crystalline phases could not be found in the coating layer. Incompletely fractured and small fragments 100~300 nm in size, which are smaller than initial feedstock material, were found on the coating surface and inside of the coating. Also, some pores and voids occurred between particle-particle interfaces. In the case of brittle Fe-based amorphous alloy, particles fail in fragmentation fracture mode through initiation and propagation of the numerous small cracks rather than shear fracture mode under compressive stress. It could be deduced that amorphous alloy underwent particle fracturing in a vacuum kinetic spray process. Also, it is considered that surface energy caused by the formation of new surfaces and friction energy contributed to the bonding of fragments.

• 한국주조공학회지
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• 제40권4호
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• pp.113-117
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• 2020

A series of Fe-P-B and Fe-Si-B amorphous alloys with high Fe contents exceeding 90 wt.% was successfully prepared by combining flux treatment and melt-spinning technique. The effects of Fe content and the flux treatment on the thermal and magnetic properties of amorphous alloys were studied. The glass-forming ability and the thermal stability of amorphous ribbons can be improved by a flux treatment, revealing the effective removal of heterogeneous nucleation sites in the ribbons through the flux treatment. It was found that Fe-Si-B ribbons exhibit higher saturation magnetization levels than Fe-P-B ribbons.

• 한국재료학회지
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• 제26권12호
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• pp.671-675
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• 2016

In this study, the glass-forming ability and mechanical properties of newly developed Fe-Mn-Cr-Mo-B-C-P-Si-Al bulk amorphous alloys were investigated, and metalloid elements such as B, C, and P were found to have a strong influence on the properties of the Fe-based amorphous alloys. When the total metalloid content (B, C, and P) is less than 5 %, only the crystal phase is formed, but the addition of more than 10 % metalloid elements enhances the glass forming ability. In particular, the alloys with 10 % metalloid content exhibit the best combination of very high compressive strength (~2.8 GPa) and superior fracture elongation (~30 %) because they consist of crystal/amorphous composite phases.

• Journal of Advanced Marine Engineering and Technology
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• 제32권6호
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• pp.938-946
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• 2008

Fe-base amorphous alloy and two crystalline phases composite were fabricated. The effect of temperature and strain rate on mechanical properties was evaluated utilizing compression test. Mixture of non-crystalline and crystalline phases were found using X-ray diffraction (XRD) and differential thermal analysis (DTA) tests. Based on glass transition temperature and crystallization temperature. compression tests were performed in the temperature ranging from $560^{\circ}C$ to $700^{\circ}C$ with $20^{\circ}C$ interval. Relationship between microstructure, including fracture surface morphology, and mechanical behavior was studied. The peak stress of Fe-base amorphous alloy was over 2GPa and expected to have a good wear resistance, but it is expected hard to deform because of low ductility. The peak stress and elongation of two crystalline phases composite was over 1GPa and about 20%, therefore it is possible to deform high strength wear resistant materials such as engine valve.

• Advances in materials Research
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• 제6권4호
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• pp.343-348
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• 2017

High-pressure gas atomization was employed to prepare the Fe-based $Fe_{50}Cr_{24}Mo_{21}Si_2B_3$ alloy powder. The effect of flow rate of atomizing gas on the median powder diameter was studied. The results show that the powder size decreased with increasing the flow rate of atomizing gas. Fe-based alloy coatings with amorphous phase fraction was then prepared by high velocity oxygen fuel spraying (HVOF) of gas atomized $Fe_{50}Cr_{24}Mo_{21}Si_2B_3$ powder. Microstructural studies show that the coatings present dense layered structure and low porosity of 0.17% in about $200{\mu}m$ thickness. The Fe-based alloy coating exhibits an average hardness of about 1230 HV. Our results show that the HVOF process results in dense and well-bonded coatings, making it attractive for protective coatings applications.

• 열처리공학회지
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• 제15권2호
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• pp.76-81
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• 2002

The melt-spun amorphous $Fe_{77-X}P_{13}C_4B_4Al_2Mo_X$(x=4~10) and $Fe_{82-X}P_XC_4B_4Al_2Mo_8$(x=9~15) alloys were found to exhibit a large supercooled liquid region(${\Delta}T_x$) exceeding 40 K before crystallization. The largest ${\Delta}T_x$ for the glassy alloys containing Mo reaches as large as 65 K for the $Fe_{69}P_{13}C_4B_4Al_2Mo_8$ alloy. The corrosion behavior of the amorphous $Fe_{77-X}P_{13}C_4B_4Al_2Mo_X$(x=4~15) and $Fe_(82-X)P_XC_4B_4Al_2Mo_8$ (x=9~17) alloys were examined by electrochemical measurements in 9M $H_2SO_4$ solution at 303 K. The addition of Mo(or P) for replacing some portion of Fe is effective in improving the corrosion resistance of the investigated Fe-based glassy alloys. They are spontaneously passivated and have a wide passive region with low passive current density.