• Title/Summary/Keyword: Fe-Pt

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Manometer Scale Mark Formation using Thermal Reaction For Storage Application (열 반응을 이용한 나노사이즈 마크형성)

  • Jung, Moon-Il;Kim, Joo-Ho;Hwang, In-Oh;Kim, Hyun-Ki;Bae, Jae-Cheol;Park, In-Sik;Kuwahara, Masashi;Tominaga, Junji
    • Transactions of the Society of Information Storage Systems
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    • v.1 no.2
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    • pp.127-131
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    • 2005
  • We report a nanometer scale mark formation using a $PtO_x$ thin film or a TbFeCo rare-earth transition metal film and the mechanism. The multi-layer samples($ZnS-SiO_2/PtOx/ZNS-SiO_2,\;ZnS-SiO_2/TbFeCo/ZnS-SiO_2$) were prepared with a magnetron sputtering method on a polycarbonate or a glass substrate. By laser irradiation of approximately a few nanoseconds, nanometer scale marks were fabricated. During the fabrication process, the thin films were thermally reacted or inter-diffused during the laser irradiation. 75 nm bubble marks in the PtOx multi-layer sample by an approximately 4-ns laser irradiation. Inside the bubble mark, Pt particles with a few nanometer sizes are distributed. The $50{\sim}100$ nm bubble marks in the TbFeCo multi-layer sample by a few nanosecond laser irradiations. We will report the detail structure of the samples, the bubble mark formation process and the mechanism.

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Current-Driven Domain-Wall Depinning in Pt/CoFe/Pt Nanowires with Perpendicular Magnetic Anisotropy

  • Kim, Kab-Jin;Lee, Jae-Chul;Choe, Sug-Bong
    • Journal of Magnetics
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    • v.14 no.3
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    • pp.101-103
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    • 2009
  • The spin transfer torque efficiency was determined experimentally by observing the current-driven domainwall depinning of Pt/CoFe/Pt nanowires with perpendicular magnetic anisotropy. The depinning time was exponentially proportional to the applied magnetic field, and was well explained by the Neel-Brown formula. The depinning time and threshold magnetic field were varied considerably by injecting current into the nanowire. The spin transfer torque efficiency was estimated to be $(7.2{\pm}0.9){\times}10^{-15}Tm^2$/A from the linear dependence of the threshold current density with respect to the applied magnetic field.

Preparations of SPE Electrocatalysts Modified with Polypyrrole and Its Application for PEMFC (폴리피롤로 개질된 SPE 전극촉매의 제조 및 PEMFC로의 응용)

  • Kim, Jung-Hoon;Oh, Seung-Duck;Kim, Han-Sung;Park, Jong-Ho;Han, Jung-Woo;Lee, Kang Taek;Joe, Yung-Il
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.118-124
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    • 2005
  • In this study, a novel deposition method of Pt catalysts onto Nafion membranes modified with polypyrrole (PPy) has been proposed for PEMFC application. The PPy/Nafion composite membranes were fabricated by chemical polymerization of pyrrole using $FeCl_3$ and $Na_2S_2O_8$ as initiator. The proton conductivity and water uptake of the chemically prepared PPy/Nafion composites were investigated. The ionic conductivity and water uptake of PPy/Nafion composite membrane prepared with $Na_2S_2O_8$ were decreased with polymerization time of pyrrole. In the case of $FeCl_3$, the ionic conductivity was almost retained and the water uptake was decreased with polymerization time of pyrrole. When the Pt particle was deposited on PPy/Nafion composites membrane by chemical reduction of $H_2PtCl_6$, the Pt loading on Nafion membrane was enhanced by polypyrrole due to electronic conduction property. The performance evaluation with membrane electrode assembly composed of Pt/PPy/Nafion composite and diffusion electrode was carried out using a single cell. As a result of fuel cell test, current density of $569mA/cm^2$ at 0.3 V has been obtained for MEA contained with Pt/PPy/Nafion composite. This study shows that direct deposition of Pt catalysts on Nafion impregnated polypyrrole is a promising method to prepare thin catalyst layer for the PEMFC.

Optimal Metal Dose of Alternative Cathode Catalyst Considering Organic Substances in Single Chamber Microbial Fuel Cells

  • Nam, Joo-Youn;Moon, Chungman;Jeong, Emma;Lee, Won-Tae;Shin, Hang-Sik;Kim, Hyun-Woo
    • Environmental Engineering Research
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    • v.18 no.3
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    • pp.145-150
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    • 2013
  • Optimal preparation guidelines of a cathode catalyst layer by non-precious metal catalysts were evaluated based on electrochemical performance in single-chamber microbial fuel cells (MFCs). Experiments for catalyst loading rate revealed that iron(II) phthalocyanine (FePc) can be a promising alternative, comparable to platinum (Pt) and cobalt tetramethoxyphenylporphyrin (CoTMPP), including effects of substrate concentration. Results showed that using an optimal FePc loading of $1mg/cm^2$ was equivalent to a Pt loading of $0.35mg/cm^2$ on the basis of maximum power density. Given higher loading rates or substrate concentrations, FePc proved to be a better alternative for Pt than CoTMPP. Under the optimal loading rate, it was further revealed that 40 wt% of FePc to carbon support allowed for the best power generation. These results suggest that proper control of the non-precious metal catalyst layer and substrate concentration are highly interrelated, and reveal how those combinations promote the economic power generation of single-chamber MFCs.

Energy Harvesting from the Bimorph Actuator using $Fe_2O_3$ Added $Pb(Ni_{1/3}Nb_{2/3})O_3$ - $PbTiO_3$ - $PbZrO_3$ Ceramics ($Fe_2O_3$가 첨가된 $Pb(Ni_{1/3}Nb_{2/3})O_3$ - $PbTiO_3$ - $PbZrO_3$ 세라믹의 바이몰프 액츄에이터를 이용한 에너지 하베스팅)

  • Jeong, Young-Hun;Kim, Chang-Il;Lee, Young-Jin;Paik, Jong-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.330-330
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    • 2008
  • $Fe_2O_3$ added Pb$(Ni_{1/3}Nb_{2/3})O_3-PbTiO_3-PbZrO_3 $ (PNN-PT-PZ) ceramics were produced in order to use them as a bimoph acturator for energy harvesting. Especially, the 0.25 wt% $Fe_2O_3$ added 0.4PNN-0.357PT-0.243PZ, having the composition of morphotropic phase boundary, showed good piezoelectric properties of $d_{33}$ of 810 pC/N, $k_p$ of 77% and $Q_m$ of 55 along with a high Curie temperature of $210^{\circ}C$. A bimorph actuator, composed of the two piezoelectric layers bonded together with a phosphorous bronze layer as a central metallic electrode, was successfully fabricated. The bimorph actuator, vibrated with a 1.3 mm amplitude at 68 Hz, produced high electric power of approximately 60 mW.

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Characteristics of Enhanced Current by Polypyrrole under Illumination (폴리피롤에 빛을 쪼일 때 증가되는 전류의 특성)

  • Chae, Won Seok;Jang, Yeah Suk;Lee, Beom Gyu;Kim, Kang Jin
    • Journal of the Korean Chemical Society
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    • v.39 no.4
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    • pp.294-300
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    • 1995
  • The photoelectrochemical behavior of polypyrrole films on Pt, glassy-C and indium tin oxide(ITO) under illumination was studied in aqueous solution containing a redox couple such as I-/I2 or Fe(CN)64-/Fe(CN)63-. Polypyrrole(PPy) was coated on Pt, glassy-C and ITO electrodes using electrochemical polymerization of pyrrole by potentiostatic method. Illumination of the PPy film results in the increase of cathodic and anodic currents at redox potentials of the redox species. These enhanced currents are caused both by the semiconductor characteristics of PPy and by the photothermal acceleration of redox reaction at PPy-electrode surface, and are dependent on the pH of redox solutions and the dopants in PPy.

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