• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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• pp.896-899
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• 2003

Using hi plasma and Fe-Phthalocyanine, carbon nanofibers have been synthesized a low temperature. The carbon nanofibers had about In nm diameter and up to $10{\mu}m$ length. These were grown in random orientation. There are two shapes in the CNFs, screw and straight line shapes. Furthermore, we found the selective growth of nanofibers on the scratched substrates.

• 한국전기전자재료학회논문지
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• 제17권2호
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• pp.242-247
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• 2004

Using Ar plasama and Fe-phthalocyanine, carbon nanofibers have been synthesized at a low temperature. Fe-phthalocyanine was used as a source material for this process. The carbon nanofibers were grown in random orientation with a diameter of about 100 nm and length up to 10${\mu}{\textrm}{m}$ on Si substrate. The synthesized carbon nanofibers exhibited excellent field emission characteristics. Protrusions with a nanometer size are observed at an angle of 60$^{\circ}$with respect to the nanofiber axis. Furthermore, we found the selective growth of nanofibers on a scratched substrates.

• 한국대기환경학회지
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• 제23권5호
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• pp.575-584
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• 2007

The adsorption capability of iron phthalocyanine derivatives were investigated by means of X-ray diffractometor (XRD), IR (infrared) spectroscopy, scanning electron microscopy (SEM) and temperature programmed desorption (TPD). According to TPD results, iron phthalocyanine derivatives showed two desorption peaks at low temperature ($100{\sim}150^{\circ}C$) and high temperature ($350{\sim}400^{\circ}C$) indicating that there were two kinds of acidities. Tetracarboxylic iron phthalocyanine (Fe-TCPC) have a stronger desorption peak (chemical adsorption) at the high temperature and a weaker desorption peak (physical adsorption) at the low temperature than iron phthalocyanine (Fe-PC). The specific surface areas of Fe-TCPC and Fe-PC were $26.46\;m^2/g\;and\;11.77\;m^2/g$, respectively. The pore volumes of Fe-TCPC and Fe-PC were $0.14\;cm^3/g\;and\;0.06\;cm^3/g$, respectively. The adsorption capability of triethyl amine calculated by breakthrough curve at 220 ppm of equilibrium concentration was 29.2 mmoL/g for Fe-TCPC and 0.8 mmoL/g for Fe-PC. The removal efficiency of dimethyl sulfide of Fe-TCPC and Fe-PC in batch experiment of 225 ppm of initial concentration were 44.9% and 28.9%, respectively. The removal efficiency of trimethyl amine of Fe-TCPC and Fe-PC in batch experiment of 118 ppm of initial concentration were approximately 100.0% and 33.9%, respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.947-950
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• 2001

We report the characteristics of organic light emitting diodes (OLEDS) by controlling the carrier mobility according to the crystalline of Iron(II) Phthalocyanine(Fe-Pc) and metal-free Phthalocyanine (H$_2$-Pc). In order to change the recombination zone, we controlled the hole mobility by changing the crystal structures of Fe-Pc and H$_2$-Pc. OLEDs were constructed with ITO/Fe-Pc/triphenyl-diamine (TPD)/tris-(8-hydroxyquinoline)aluminum (Alq$_3$)/Al and ITO/H$_2$-Pc/triphenyl-diamine (TPD)/tris-(8-hydroxyquinoline)aluminum (Alq$_3$)/Al. The electroluminescent properties were changed according to the heat-treatments of Fe-Pc and H$_2$-Pc. We observed that the recombination zone and the carrier mobility were changed as the higher occupied molecular orbital levels of Fe-Pc and H$_2$-Pc decreased.

• Journal of Electrochemical Science and Technology
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• 제10권3호
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• pp.321-328
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• 2019

A new miniaturized all solid-state contact Fe (III)-selective PVC membrane electrode based on Fe (II) phthalocyanine as a neutral carrier was described. The effects of the membrane composition and foreign ions on the electrode performance was investigated. The best performance was obtained with a membrane containing 32% poly (vinyl chloride), 64% dioctylsebacate, 3% Fe (II) phthalocyanine, and 1% potassium tetrakis (p-chlorophenyl) borate. The electrode showed near Nernstian response of $26.04{\pm}0.95mV/decade$ over the wide linear concentration range $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}M$, and a very low limit of detection $1.8{\pm}0.5{\times}10^{-7}M$. The potentiometric response of the developed electrode was independent at pH 3.5-5.7. The lifetime of the electrode was approximately 3 months and the response time was very short (< 7 s). It exhibited excellent selectivity towards Fe (III) over various cations. The miniaturized all solid-state contact Fe (III)-selective membrane electrode was successfully applied as an indicator electrode for the potentiometric titration of $1.0{\times}10^{-3}M$ Fe (III) ions with a $1.0{\times}10^{-2}M$ EDTA and the direct determination of Fe (III) ions in real water samples.

• 한국안전학회지
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• 제23권1호
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• pp.66-71
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• 2008

$PcFe(4-VP)_2$[Pc: Phthalocyanine, 4-VP: 4-Vinylpyridine]와 $PcFe(VIM)_2$[VIM: 1-Vinylimidazole]의 제조를 재래식 방법인 유기용제 사용에 따른 폭발 및 유해증기 발생 위험성을 차단하기 위해 무용제 방식으로 ligand인 4-VP와 VIM을 반응매체로 하여 PcFe를 밀폐용기에서 용융시키는 새로운 방법을 도입, 제조하여 분말상 진청록색의 물질을 제조하였다. 이들 물질은 $CH_2Cl_2$에 가용성인 $PeFeL_2$형태의 물질이다. 제조된 물질을 ATR-FTIR, UV/Vis, DSC/TGA, Surface Resistivity Meter를 이용하여 분석한 결과 film 상태에서 UV/Vis 차단 특성이 뛰어남과 동시에 대전 방지특성을 나타내며 또한 내열성이 우수한 물질이 제조되어 사용 및 응용이 가능할 것으로 사료된다.

• Journal of Magnetics
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• 제17권4호
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• pp.261-264
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• 2012

Interfacial properties of 5 nm MgO(001)/7 nm Fe(001)/1.8 nm MgO(001)/t nm Cu-phthalocyanine (CuPc) hybrid multilayers with t = 0, 1, 7, and 10 were investigated by using x-ray photoemission spectroscopy (XPS). Rather sharp interfacial properties were observed in the CuPc films grown on an epitaxial MgO/Fe/MgO(001) trilayer than a MgO/Fe(001) bilayer. This work suggests a new way to improve device performance of organic spintronic devices by utilizing an artificially grown MgO(001) thin layer.

• Bulletin of the Korean Chemical Society
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• 제21권6호
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• pp.588-594
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• 2000

Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

• 한국자기학회지
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• 제22권5호
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• pp.162-166
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• 2012

Fe(100)/MgO(100)/CuPc/Co 자성터널접합 소자의 온도에 따른 전압-전류 특성 변화를 관찰하였다. 화학적 열적 안정성이 비교적 우수한 Cu-Phthalocyanine(CuPc)의 유기박막을 에피성장된 2 nm MgO(100) 박막 위에 2~10 nm 두께로 적층하여 두 강자성 Fe(100)와 Co 전극 사이의 무기-유기 복합 절연격벽으로 이용하였다. 저온 77 K에서 측정된 거대자기저항현상은 CuPc의 두께가 증가함에 따라 급격히 감소하여 10 nm의 CuPc 두께의 경우 전하축적에 의한 쌍안정 스위칭 거동(bistable switching behavior)이 관찰되었다. 이 스위칭 거동은 약 240 K의 온도에 이르면서 점차 소멸되어 상온에서는 정류기와 유사한 비대칭적 전압-전류 특성을 보였다. 이 연구에서 우리는 MgO/CuPc 층상구조에대해 유기물 스핀소자의 절연격벽뿐만 아니라 Polymer Random Access Memory(PoRAM)를 위한 응용 가능성에 대해 논하였다.

• 유기물자원화
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• 제23권1호
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• pp.45-51
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• 2015

본 연구에서는 비귀금속 촉매인 iron(II) phthalocyanine (FePc)와 cobalt tetramethoxyphenylporphyrin(CoTMPP)를 환원전극촉매로 이용하여 미생물연료전지의 연속운전을 진행하였다. 연속운전은 유기물 부하 (0.5~3 g COD/L/d)와 HRT (0.25~1 day)의 조건을 달리 운전하여 미생물연료전지의 성능을 평가하였다. 미생물연료전지의 전력밀도는 환원전극의 성능에 크게 영향을 받았으며, 최대전력밀도는 $3.3W/m^3$로 백금을 사용한 미생물연료전지에서 나타났다. 하지만, HRT의 조건을 달리 한 실험에서 FePc를 사용한 미생물연료전지가 백금을 사용한 미생물연료전지와 유사한 성능을 나타냈으며, 연속운전에서 백금 촉매를 대체할 수 있는 적합한 물질로 나타났다. 반면에 CoTMPP를 사용한 미생물연료전지는 연속운전에서 내부 저항의 급격한 증가로 전력밀도가 급격히 감소하였다.