• Title/Summary/Keyword: Fe-Cr

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Corrosion Behavior of Ni 200 and Ni-base Alloys in Hot Lithium Molten salt (고온 리튬용융염에서 Ni 200 및 Ni-base 합금의 부식거동)

  • Cho Soo-Hang;Lim Jong-Ho;Yun Ki-Seok;Park Seung-Won
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.251-259
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    • 2004
  • In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650~800^{\circ}C$ for 24~312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

A Study on the Development of Hot Rolling Process for 18Cr-10Mn-0.44N2 (18Cr-10Mn-0.44N2 고질소강의 열연공정개발에 관한 연구)

  • Kim, Y.D.;Cho, J.R.;Lee, J.W.;Bae, W.B.
    • Transactions of Materials Processing
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    • v.20 no.4
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    • pp.296-302
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    • 2011
  • The objective of this paper is to determine the effect of process parameters on the behavior of a 18Cr-10Mn-$0.44N_2$ nitrogen steel sample deformed by hot rolling. Compression tests were carried out at high temperatures to determine the flow stresses needed for a finite element(FE) analysis. The strain rate, ranging from 0.1 to $1.0s^{-1}$, significantly affected the flow stress at temperatures higher than $1,000^{\circ}C$. Non-isothermal rolling simulations and laboratory rolling tests were performed with plate specimens 14.5mm thick, 135mm wide and 226mm long. A rolling reduction of 15% per pass leading to a cumulative rolling reduction of 60% was determined as optimal. The extension ratio of 176.5% in the length direction was about 30.4 times greater than the extension ratio of 5.8% in the width direction. Isotropic properties for tensile strength, microstructure and grain size were measured after mock-up hot rolling tests. The results from the mockup tests were found to be in good agreement with those of the simulations.

Edge-Cracking Behavior of CoCrFeMnNi High-Entropy Alloy During Hot Rolling

  • Won, Jong Woo;Kang, Minju;Kwon, Heoun-Jun;Lim, Ka Ram;Seo, Seong Moon;Na, Young Sang
    • Metals and materials international
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    • v.24 no.6
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    • pp.1432-1437
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    • 2018
  • This work investigated edge-cracking behavior of equiatomic CoCrFeMnNi high-entropy alloy during hot rolling at rolling temperatures $500{\leq}T_R{\leq}1000^{\circ}C$. Edge cracks did not form in the material rolled at $500^{\circ}C$, but widened and deepened into the inside of plate as $T_R$ increased from $500^{\circ}C$. Edge cracks were most severe in the material rolled at $1000^{\circ}C$. Mn-Cr-O type non-metallic inclusion and oxidation were identified as major factors that caused edge cracking. The inclusions near edge region acted as preferential sites for crack formation. Connection between inclusion cracks and surface cracks induced edge cracking. Rolling at $T_R{\geq}600^{\circ}C$ generated distinct inclusion cracks whereas they were not serious at $T_R=500^{\circ}C$, so noticeable edge cracks formed at $T_R{\geq}600^{\circ}C$. At $T_R=1000^{\circ}C$, significant oxidation occurred at the crack surface. This accelerated edge crack penetration by embrittling the crack tip, so severe edge cracking occurred at $T_R=1000^{\circ}C$.

The Removal of Heavy Metals in Aqueous Solution by Hydroxyapatite (Apatite를 이용한 중금속 제거)

  • 강전택;정기호
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.325-330
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    • 2000
  • The hydroxyapatite (HAp) for the present study was prepared by precipitation method in semiconductor fabrication and the crystallized at ambient to 95$0^{\circ}C$ for 30min in electric furnace. The ion-exchange characteristics of HAp for various heavy metal ions such as $Cd^{2+}, Cu^{2+}, Mn^{2+}, Zn^{2+}, Fe^{2+}, Pb^{2+}, Al^{3+}, and Cr^{6+}$ in aqueous solution has been investigated. The removal ratio of various metal ions for HAp were investigated with regard to reaction time, concentration of standard solution, amount of HAp and pH of solution. The order of the ions exchanged amount was as follws: $Pb^{2+}, Fe^{3+}>Cu^{2+}>Zn^{2+}>Al^{3+}>Cd^{2+}>Mn^{2+}>Cr^{6+}. The Pb^{2+}$ ion was readily removed by the Hap, even in the strongly acidic region. The maximum amount of the ion-exchange equilibrium for $Pb^{2+}$ ion was about 45 mg/gram of HAp. The HAp would seem to be possible agent for the removal of heavy metal ions in waste water by recycling of waste sludge in semiconductor fabrication.

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The Dyeability and Antibacterial Activity of Wool Fabric Dyed with Cochineal

  • Bae, Jung-Sook;Huh, Man-Woo
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.22-29
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    • 2006
  • The purpose of this study was to investigate the dyeability and antibacterial activity on wool fabric dyed with cochineal at variable dyeing conditions. Al, Cr, Fe, Cu and Sn were used as mordants and adsorption was compared with different mordanting methods. The optimum dyeing conditions of wool fabrics were dyeing concentration 2.0%(o.w.s), dyeing temperature $60^{\circ}C$, pH 3 and dyeing time 30 minutes. The pre-mordanting method was preferred for Al and Cr, and the post-mordanting one was preferred for Cu, Sn and Fe to achieve better dyeing. The optimum mordanting conditions of wool fabrics dyed with cochineal were mordanting concentration of 1%(o.w.s), mordanting temperature $60^{\circ}C$, and dyeing time 30 minutes. Wool fabrics dyed with cochineal showed a little antibacterial activity, but it was increased by Cu and Sn mordanting. The light fastness and perspiration fastness of wool fabric treated with cochineal were improved by mordanting.

A Study of Air Pollutants Dry Deposition (대기오염물질의 건성침적에 관한 연구)

  • Lee, Chi-Young;Kang, Dong-Ku
    • Journal of environmental and Sanitary engineering
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    • v.18 no.3 s.49
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    • pp.64-68
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    • 2003
  • Measurement of dried deposition for air pollutant was investigated in Gwang-ju Health college area for a year. The average value of air pollutants was investigated three times a month. Measured heavy metals and concentration of mass are not corelated. Heavy metals were thrown up air as state of large particles and they were moved by wind. Deposition of heavy metals and deposition velocities were high in the order of Fe > n > Cu > Pb > Cr and Pb > Fe > Cr > Zn > Cu, respectively. The pattems of deposition velocity of heavy metals for a year were much the same as each other except that Pb is faster than others.

Characteristics of Electronic, Magnetic Transformation for Environment Change in Magnetic Recording Media (자기기록매체에 있어서 환경변화에 따른 자기 및 전자 변환 특성)

  • Yoon, Man-Youn;Shin, Jong-Soon
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.2
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    • pp.13-22
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    • 2004
  • Selected chemical, physical, mechanical, and magnetic properties of magnetite, Co-${\gamma}-Fe_2O_3$, $CrO_2$ recording tapes were studied, under three sets of temperature and humidity conditions, to accelerate the tapes' aging. The results. obtained indicated that changes in temperature, huminity and magnetic properties were dependent. Changes in the magnetic properties can be used to predict the life expentancy of the information stored in the media. Together, all of these properties can be used to assess the overall storage characteristics of magnetitie, Co-${\gamma}-Fe_2O_3$, $CrO_2$ recording tapes.

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Trace elements analysis in some medicinal plants using graphite furnace-atomic absorption spectroscopy

  • Anal, Jasha Momo H.;Chase, Petevino
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.247-255
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    • 2016
  • Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

Reduction of Stainless Steelmaking Dust by Microwave Heating (마이크로파 가열에 의한 스테인레스강 분진의 환원)

  • 반봉찬;조환종
    • Resources Recycling
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    • v.2 no.4
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    • pp.10-16
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    • 1993
  • Reduction behavior of stainless steelmaking dust by microwave heating process was investigated using coke and charcoal as reducing agents. Pellet dust and stanless steelmaking dust pelletized with reducing agent were reduced by the heating upto $1000^{\circ}C$ in microwave oven. The results showed that charcoal and coke seemed effective in the reduction of metals from stainless steelmaking dust by microwave heating and charocal was found to be better than coke. Degree of reduction seemed similar with the power of 500W and 700W in microwave oven. Dusts were rapidly reduced within 20 minutes. Reducing degree decreased in the order of Fe>Ni>Cr.

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Impurity effect of the textures of Ni substrates in high - Tc YBCO coated conductor application (YBCO 고온초전도체에 사용되는 니켈 기판의 결정성에 미치는 불순물효과)

  • Kim, Ho-Sup;Kim, Hwe-Kyung;Youm, Do-Jun
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.99-101
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    • 1999
  • To improve the texture and the hardness of Ni substrates, we added impurities such as Mn, Fe, Co, Cu and Cr and investigated the effect of impurities on the texture and the hardness of Ni tapes. The Ni tapes with 0.2% Co, Cr, Cu, showed poor in-plane textures. However, the Ni tapes with 0.1 ${\sim}$ O.2% Mn (or Fe), showed much better textures. We'll describe the detailed effects of the amount of Mn impurities.

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