• Title/Summary/Keyword: Fe-Cr

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Pretreatment for Cu electroplating and Etching Property of Cu-Cr Film (Cu-Cr합금 박막의 구리 전기도금을 위한 전처리 및 에칭 특성에 관한 연구)

  • Kim, N. S.;Kang, T.;Yun, I. P.;Park, Y. S.
    • Journal of the Korean institute of surface engineering
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    • v.26 no.3
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    • pp.149-157
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    • 1993
  • In the study of TAB(Tape Automated Bonding)technologies, Cu-Cr sputtered seed layer has been used to improve the adhesion between Polyimide and Cu film and electrical properties. But the Cu electrodeposit on Cu-Cr film had poor adhesion or powder-like form due to the surface Cr oxides on the Cu-Cr film. By means of activating the Cu-Cr film with the oxalic acid and phosphoric acid, the Cu film with the improved adhesion could be coated on the Cu-Cr sputtered film in CuSO4 solution. The etching rate was compared with increasing the Cr content of the sputtered Cu-Cr film, and anodic polarization curve in FeCl3 solution was investigated. With increasing the Cr content, the etching rate was reduced. The clean etching cross section could be obtained with increasing the concentration of FeCl3 solution. But above the 13 w/o Cr content, Cu-Cr sputtered film could not bed etched cleanly only with FeCl3 solution and additives were needed.

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Evaluation of Embrittlement in Isochronal Aged Fe-Cr Alloys by Magnetic Hysteresis Loop Technique

  • Mohapatra, J.N.;Kamada, Y.;Kikuchi, H.;Kobayashi, S.;Echigoya, J.;Park, D.G.;Cheong, Y.M.
    • Journal of Magnetics
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    • v.16 no.2
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    • pp.173-176
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    • 2011
  • Fe-Cr alloys with different Cr contents were prepared by an arc melting technique. The alloys were isochronally aged in the range from $400^{\circ}C$ to $900^{\circ}C$ with $50^{\circ}C$ steps with a holding time of 100 hours. The ageing produced embrittlement in the alloys due to either the formation of a Cr-rich ${\alpha}'$ phase or a $\sigma$ phase at high temperatures. Magnetic Hysteresis Loop (MHL) and Micro-Vickers hardness were measured at each step to correlate the magnetic and mechanical properties. Coercivity and hardness of the alloys were increased and remanence decreased up to 500-$550^{\circ}C$ due to formation of a Cr-rich ${\alpha}'$ phase. Beyond 500-$550^{\circ}C$ range, the coercivity and hardness decreased and remanence increased due to the coarsening or dissolution of the Cr-rich ${\alpha}'$ phase. In the Fe-48% Cr alloy, formation of the $\sigma$ phase at $700^{\circ}C$ reduced the maximum induction of the alloy significantly.

Mössbauer Studies on Magnetoresistance in Chalcogenide Fe0.9M0.1Cr2S4 (M=Co, Ni, Zn) (Chalcogenide Fe0.9M0.1Cr2S4(M=Co, Ni, Zn)의 자기저항에 관한 Mössbauer 분광연구)

  • Park, Jae Yun;Lee, Byoung-Seob
    • Journal of the Korean Magnetics Society
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    • v.23 no.2
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    • pp.43-48
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    • 2013
  • The Jahn-Teller distortion of chalcogenide $Fe_{0.9}M_{0.1}Cr_2S_4$ (M=Co, Ni, Zn) have been investigated by M$\ddot{o}$ssbauer spectroscopy. The crystal structures of $Fe_{0.9}M_{0.1}Cr_2S_4$ (M=Co, Ni, Zn) are cubic spinel at room temperature. Magnetoresistance measurements indicate these system is conducting-semiconducting transistion around $T_C$. Below $T_C$, the asymmetric line broadening is observed and considered to be dynamic Jahn-Teller distortion. Isomer shift value of the samples at room temperature was about 0.5 mm/s, which means that charge state of Fe ions is ferrous in character. The Ni substitutions for Fe occur to increase the Jahn-Teller relaxation. CMR properties could be explained with magnetic polaron due to Jahn-Teller effect, which is different from both the double exchange interactions of manganite system and the triple exchange interactions of chalcogenide $Cu_xFe_{1-x}Cr_2S_4$.

Effects of Alloying Elements on the Surface Characteristics of Fe-38Al Intermetallic Compounds (Fe-38 at.% Al계 금속간화합물의 표면특성에 미치는 합금원소의 영향)

  • 최한철
    • Journal of the Korean institute of surface engineering
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    • v.37 no.2
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    • pp.128-136
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    • 2004
  • Effects of alloying elements on the surface characteristics of Fe-38Al intermetallic compounds were investigated using potentiostat. The specimens were casted by the vacuum arc melting. The subsequent homogenization and the stabilization led to the homogeneous DO$_3$ structure of the specimen. After the corrosion tests, the surface of the tested specimen was observed by the optical microscopy and scanning electron microscopy(SEM). For Fe-38 at.% Al intermetallic compound, the addition of Cr and Mo proved to be beneficial in decreasing the grain boundary attack by decreasing the active current density. Addition of Band Nb resulted in a higher active current density and also a higher passive current density. These results indicated the role of Cr and Mo in improving the pitting corrosion resistance of Fe-38 at.%Al intermetallic compound. Band Nb addition to Fe-38 at.%Al accelerated the granular corrosion. Fe-38 at.%Al containing Cr and Mo showed remarkably improved pitting corrosion resistance in comparison with Band Nb addition to Fe-38 at. %Al.

The Magnetoresistance effects of number of layers and magnetic anisotropic in [NiFe/Cr] Multilayers (NiFe/Cr 다층박막의 층수와 자기이방성에 따른 자기저항특성)

  • 황도근;이상석;박창만;이기암
    • Journal of the Korean Magnetics Society
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    • v.5 no.3
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    • pp.210-215
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    • 1995
  • $Glass\Cr_{40\AA}\{[Cr_{10\AA}\NiFe_{50\AA}]}_N$ multilayers (number of layer N = 1, 2, 3, 4, 5, 6, 10) were made by dc magnetron sputtering under magnetic anisotropy of 200 G. Magnetoresistance curve MR(xx), MR(xy) were measured for the parallel and perpendicular current direction to external magnetic field. MR(xx) curves for the number of layer N=1, 5, 10 were almost became about zero percent, however the curves of other numbers appeared the phenomena of "positive magnetoresistance" that the resistance increased to external magnetic field, and the irregular and reversed curves in the vicinity of H=0 Oe.

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Exchange Bias in Cr2O3/Fe3O4 Core/Shell Nanoparticles

  • Yun, B.K.;Koo, Y.S.;Jung, J.H.
    • Journal of Magnetics
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    • v.14 no.4
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    • pp.147-149
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    • 2009
  • We report the exchange bias in antiferromagnet/ferrimagnet $Cr_2O_3/Fe_3O_4$ core/shell nanoparticles. The magnetic field hysteresis curve for $Cr_2O_3/Fe_3O_4$ nanoparticles after field-cooling (FC) clearly showed both horizontal ($H_{EB}{\sim}$610 Oe) and vertical (${\Delta}M{\sim}$5.6 emu/g) shifts at 5 K. These shifts disappeared as the temperature increased toward the Neel temperature of $Cr_2O_3\;(T_N{\sim}$307 K). The $H_{EB}\;and\;{\Delta}M$ values were sharply decreased between the $1^{st}\;and\;the\;2^{nd}$ magnetic field cycles, and then slowly decreased with further cycling. These results are discussed in terms of the formation of single domains with pinned, uncompensated, antiferromagnetic spin and their evolution into multi-domains with cycling.

Simultaneous Removal of Cd &Cr(VI) by Fe-loaded zeolite in Column System (컬럼실험을 통한 Fe-loaded zeolite의 Cd& Cr(VI) 동시제거 반응성 평가)

  • Lee A-Ra;Lee Seung-Hak;Park Jun-Beom
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.151-154
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    • 2005
  • Laboratory column experiments for simultaneous removal of Cd and Cr(VI) are conducted using newly developed material, referred to as Fe-loaded zeolite, which has both reduction ability of iron and ion exchange ability of zeolite. Breakthrough curves were obtained from each column experiment, and described with advection-dispersion equation. Apparent parameters including $K_{app}\;and\;D_{app}$ were newly introduced for effectively describing the Cr(VI) breakthrough curve. $K_{app}$ decreased with increasing initial contaminant concentration and with decreasing flow rates. Whereas, $D_{app}$ were not significantly affected by initial contaminant concentration or flow rate.

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Solidification Behavior of 3%C-5%Mo-5%W-10%(Cr or V) White Cast Irons (3%C-5%Mo-5%W-10%(Cr or V) 백주철의 응고거동에 관현 연구)

  • Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.10 no.2
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    • pp.144-147
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    • 2000
  • 10%C-5%Mo-5%W-10%Cr 및 10%C-5%Mo-5%W-10%V 백주철의 응고거동을 열분석을 통하여 연구하였다. 15Kg 용량의 고주파 유도옹해로에 선철, 고철, Fe-Mo, Fe-W, Fe-Cr, Fe-V 등을 장입시켜 용해시킨 후 슬래그를 제거시키고 $1550^{\circ}C$에서 Y블럭의 펩 주형에 주입하였다. 응고거동을 조사하기 위하여 50g을 Y블럭에서 채취한 뒤 알루미나 도가니에 넣어 재용해시킨 후 1$0^{\circ}C$/min의 냉각속도로 냉각시키면서 여섯 종류의 다른 온도에서 도중에 급냉시켜 응고조직을 광학현미경으로 관찰하였다. 10%C-5%Mo-5%W-10%Cr 백주철의 경우 초정 오스테나이트, 오스테나이트와 M(sub)7C(sob)3의 공정, 오스테나이트와 M(sub)6C의 공정으로, 10%C-5%Mo-5%W-10%V 백주철의 경우 초정 MC, 오스테나이트와 MC의 공정, 오스테나이트와 M(sub)2C의 공정으로 각각 순차적으로 정출하였다. 정출하였다.

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Characteristics of Ni-based Alloy Bond in Diamond Tool Using Vacuum Brazing Method

  • An, Sang-Jae;Song, Min-Seok;Jee, Won-Ho
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1130-1131
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    • 2006
  • We found that the """interface reaction between Ni-based alloy bond, diamond, and steel core is very critical in bond strength of diamond tool. None element from metal bond diffuses into the steel core but the Fe element of steel core was easily diffused into the bond. This diffusion depth of Fe has a great effect on the bonding strength. The Cr in steel core accelerated the Fe diffusion and improved the bond strength, on the other hand, carbon decreased the strength. Ni-based alloy bond including Cr was chemically bonded with diamond by forming Cr carbide. However, the Cr and Fe in STS304 were largely interdiffused, the strength was very low. The Cr passivity layer formed at surface of STS304 made worse strength at commissure in brazing process.

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LET Calibration of Fe 500 MeV/u Ions using SSNTD (고체비적검출기를 이용한 500 MeV/u 철 이온의 선에너지전이 교정)

  • KIM, Sunghwan
    • Journal of Sensor Science and Technology
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    • v.25 no.1
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    • pp.41-45
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    • 2016
  • In this study, LET (Linear Energy Transfer) calibration of CR-39 SSNTD (Solid State Nuclear Track Detector) was performed using 500 MeV/u Fe heavy ions in HIMAC (Heavy Ion Medical Accelerator) for high LET radiation dosimetry. The irradiated CR-39 SSNDT were etched according JAXA (Japan Aerospace Exploration Agency) etching conditions. And the etched SSNTD were analyzed by using Image J. Determined dose-mean lineal energy ($\overline{y_D}$) of 500 MeV/u Fe is about 283.3 keV/um by using the CR-39 SSNTD. This value is very similar result compare to the results calculated by GEANT4 Monte Carlo simulation and measured with TEPC active radiation detector. We confirmed that the CR-39 SSNTD was useful for high LET radiation dosimetry such as heavy iron ions.