• Title/Summary/Keyword: Fe ion

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Ion Beam Etching으로 에칭한 자성 박막의 자기적 특성 변화 조사

  • Yoon, S.M.;Lee, Y.W.;Hu, Y.K.;Kim, C.G.;Kim, C.O.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.224-225
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    • 2002
  • 강자성체의 스핀 분극을 이용하는 스핀트로닉스에 대한 연구는 매우 활발히 이루어지고 있다. CoFe 합금은 큰 포화자화와 스핀분극 때문에 스핀트로닉스 재료로 널리 이용되고 있다. 본 연구에서는 Ion Beam Etching 방법으로 CoFe 박막을 미세 가공 할 때 에칭 조건에 따른 CoFe 박막의 자기적 특성 변화를 조사하였다. 에칭 변수가 에칭에 미치는 영향을 사전에 조사하기 위하여 Cu 박막에 대하여 에칭시간, 기울임 각도, 가속 전압을 변화시키면서 식각한 후 거칠기 변화를 조사하였다. (중략)

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The Influence of $O_2$ Gas on the Etch Characteristics of FePt Thin Films in $CH_4/O_2/Ar$ gas

  • Lee, Il-Hoon;Lee, Tea-Young;Chung, Chee-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.408-408
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    • 2012
  • It is well known that magnetic random access memory (MRAM) is nonvolatile memory devices using ferromagnetic materials. MRAM has the merits such as fast access time, unlimited read/write endurance and nonvolatility. Although DRAM has many advantages containing high storage density, fast access time and low power consumption, it becomes volatile when the power is turned off. Owing to the attractive advantages of MRAM, MRAM is being spotlighted as an alternative device in the future. MRAM consists of magnetic tunnel junction (MTJ) stack and complementary metal- oxide semiconductor (CMOS). MTJ stacks are composed of various magnetic materials. FePt thin films are used as a pinned layer of MTJ stack. Up to date, an inductively coupled plasma reactive ion etching (ICPRIE) method of MTJ stacks showed better results in terms of etch rate and etch profile than any other methods such as ion milling, chemical assisted ion etching (CAIE), reactive ion etching (RIE). In order to improve etch profiles without redepositon, a better etching process of MTJ stack needs to be developed by using different etch gases and etch parameters. In this research, influences of $O_2$ gas on the etching characteristics of FePt thin films were investigated. FePt thin films were etched using ICPRIE in $CH_4/O_2/Ar$ gas mix. The etch rate and the etch selectivity were investigated in various $O_2$ concentrations. The etch profiles were studied in varying etch parameters such as coil rf power, dc-bias voltage, and gas pressure. TiN was employed as a hard mask. For observation etch profiles, field emission scanning electron microscopy (FESEM) was used.

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Separation of Fe(Ⅱ) from Co(Ⅱ), Ni(Ⅱ), Pb(Ⅱ) Using Amberlite IRA 400 Loaded with Alizarin Red S (Alizarin Red S가 결합된 Amberlite IRA 400 에 의한 Co(Ⅱ), Ni(Ⅱ), Pb(Ⅱ) 중 Fe(Ⅱ)의 분리)

  • Cha, Ki Won;Park, Chan Il;Kang, Ji Soo
    • Journal of the Korean Chemical Society
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    • v.42 no.2
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    • pp.172-176
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    • 1998
  • An anion exchange resin which has Alizarin Red S (ARS) as functional group was prepared by batch method. The resin is stable in acidic solutions below 0.5 M hydrochloric acid, nitric acid and sulfuric acid and adsorption capacity of Fe(Ⅱ) ion on the resin was larger than other metal ions. The preconcentration and the separation of Fe(Ⅱ) ion from the mixture solution were carried out with the pH 4.5 buffer solution and 0.1 M $HNO_{3}$ as eluents.

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Effect of Iron Ion on Cell Division and Microcallus Growth in Mesophyll Protoplast Cultures of Arabidopsis thaliana (철이온이 Arabidopsis thaliana 초기 원형질체배양의 세포분열 및 미세 캘러스 생장에 미치는 효과)

  • 박현용
    • Korean Journal of Plant Tissue Culture
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    • v.22 no.6
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    • pp.339-343
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    • 1995
  • This study was performed to investigate the effect of iron ion on the mesophyll protoplast culture of Arabidopsis thaliana. Mesophyll protoplasts were isolated and cultured in a modified IMH medium supplemented with various concentrations of Fe-EDTA. Relatively low concentration of Fe-EDTA (<0.02 mM) induced the low level (4.8%) of cell division. In addition the cell division and microcallus growth were dose-dependently stimulated by 0 to 1 mM of Fe-EDTA. In 0.5 to 1 mM concentration range of Fe-EDTA, microcolonies were readily formed and the plating deficiency (8.5%) also showed maximal rate. However more than 1 mM of Fe-EDTA inhibited the initial growth of protoplase. The overall results suggest that Fe2+ion concentration plays an important role at the early developmental stage of protoplast regeneration.

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Assessment of exchange bias by Ar ion beam FeMn inter-layer surface etching in Py/FeMn/Py multilayer (NiFe/FeMn/NiFe 다층박막에서 사이층 FeMn의 Ar 이온빔 surface etching에 의한 교환바이어스 평가)

  • 윤상민;임재준;이영우;김철기;김종오
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.233-233
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    • 2003
  • 교환바이어스(exchange bias)현상은 강자성과 반강자성의 접합계면에서 강한 상호 교환결합력에 의해 발생하는 것으로 알려져 있다. 이 현상은 1956년 Meiklejohn과 Bean에 의해 CoO 층으로 둘러싸인 Co 입자에서 발견된 이후, 강자성과 반강자성의 접합계면을 가지는 다층 박막에서의 교환바이어스에 대한 연구가 진행되어왔다. 이는 강자성/반강자성 박막의 교환바이어스 특성을 이용하여, 강자성 박막의 스핀방향을 고정시킬 수 있기 때문이다. 이러한 교환바이어스 특성은 하드드라이브의 고밀도 자기헤드소자 및 비휘발성 자기메모리소자에 응용되어지는 등 경제적 가치를 갖는 기술적인 면과 교환바이어스라는 자기특성의 학문적인 가치로 인해 이 분야에 대한 집중적인 투자와 연구가 이루어지고 있다 최근에는 교환바이 어스 현상의 원인과 형성기구에 대한 연구가 활발히 진행되고 있다. 그러나 강자성과 반강자성 박막의 단거리 상호 교환결합력에 의한 교환바이어스 현상은, 계면의 원자구조, 자기구조 및 각자성층의 여러 가지 인자들에 대해서 지속적으로 연구되고 있다. 본 연구에서는 Helmhertz 코일의 진동샘플형 자력계(VSM)을 이용하여 Si 기판위에 증착된 NiFe(10nm)/FeMn(t)/NiFe(10nm) 다층박막에서 FeMn층의 두께에 대한 각각의 교환바이어스 현상을 조사하고 사잇층 FeMn층의 surface를 Ar ion beam etching하여 etching 조건에 따른 교환바이어스를 비교분석 하고자 한다.

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Effects of Packing Materials and Inorganic Chemicals During the Start Up in Anaerobic Filter Process (혐기성 생물막법의 Start Up에 있어서의 충진제 및 무기염류의 영향)

  • 정경훈;최형일;신대윤
    • Journal of Environmental Health Sciences
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    • v.20 no.2
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    • pp.73-79
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    • 1994
  • The effects of packing materials in the anaerobic reactor and inorganic chemicals in the synthetic wastewater on the anaerobic treatment during the start up period were investigated using anaeroic filter process. The Ringlace and Honeycomb tube as packing materials were used in the anaerobic reactors. The Ca$^{2+}$ and Fe$^{2+}$ ion concentration as inorganic chemicals contained higher 40 times and 100 times as compared to the control synthetic wastewater, respectively. A start up period 104 and 150 days were necessary to achieve loading rate of 0.37 and 0.74 kg-Toc/m$^3$.d in the anaerobic filter process packed by Ringlace and Honeycomb tube, respectively. The loading rates of the reactor using the synthetic wastewater containing Ca$^{2+}$ (40 times) could be increased faster than in the reactors using the synthetic wastewater containing Fe$^{2+}$ ion (100 times) and control synthetic wastewater. The results of XMA analysis that a lot of the Ca$^{2+}$ ion on the surface of the anaerobic sludge in the anaerobic reactor packed by Ringlace which were fed supplied with synthetic wastewater containing Ca$^{2+}$ ion (40 times) observed as compared to the reactors supplied with control synthetic wastewater and containing Fe$^{2+}$ ion (100 times).

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Separation of Ni and Fe from $H_2SO_4$ leaching solution of scrapped Fe-Ni alloy (Fe-Ni 합금(合金) 스크랩의 황산(黃酸) 침출액(浸出液)으로부터 Ni와 Fe의 분리(分離))

  • Yoo, Kyoung-Keun;Jha, Manis Kumar;Kim, Min-Seuk;Yoo, Jae-Min;Jeong, Jin-Ki;Lee, Jae-Chun
    • Resources Recycling
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    • v.17 no.1
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    • pp.80-87
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    • 2008
  • Cementation and solvent extraction processes were studied to separate nickel and iron ions from the $H_2SO_4$ leaching solution with 47 g/L $Fe(Fe^{2+}/Fe^{3+}=1.03),$, 23.5 g/L Ni and 0.90M $H_2SO_4$ which leached from Fe-Ni alloy. Iron powder was used as a reducing agent for the cementation of Ni ion from the leaching solution. The reduction percentage of Ni ion was $17{\sim}20%$ by adding 4 times stoichiometric amount of iron powder at $60{\sim}80$. This may result from the fact that the cementation of Ni ion occurred after the reduction of $Fe^{3+}$ to $Fe^{2+}$ and the neutralization of $H_2SO_4$ with iron powder. The cementation process was proved to be unfeasible for the separation/recovery of Ni ion from the leaching solution including $Fe^{3+}$ as a major component. $Fe^{2+}$ present in the leaching solution was converted to $Fe^{3+}$ for solvent extraction of Fe ion using D2EHPA in kerosene as a extractant. The oxidation of $Fe^{2+}$ to $Fe^{3+}$ was completed by the addition of 1.2 times stoichiometric amount of 35% $H_2SO_4$. 99.6% $Fe^{3+}$ was extracted from the leaching solution (23.5 g/L $Fe^{3+}$) by 4 stages cross-current extraction using 20 vol.% D2EHPA in kerosene. $NiSO_4$ solution with 98.5% purity was recovered from the $H_2SO_4$ leaching solution of scrapped Fe-Ni alloy.

Antioxidative Activities and Nitrite Scavenging Abilities of Extracts from Ulmus devidiana (느릅나무 추출물의 항산화 효과 및 아질산염 소거능)

  • 이영주;한준표
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.5
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    • pp.893-899
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    • 2000
  • To measure antioxidative activities, the various extracts from Ulmus devidiana were examined in oil emulsion. Water, ethanol, methanol and butanol were used as extract solutions. The activity oxygen species ($H_2O_2,-OH,\;KO_2$) bound the extracts for antioxidative activities were excellent. The extracts bound $Fe^{2+}$ ion and $Cu^{2+}$ ion showed effective antioxidative activities and strong chelating effects. The concentration of $Fe^{2+}$ ion and total ion in ethanol and methanol extracts from Ulmus devidiana root parts (Chinese) were higher than those of the other products. The highest superoxide dismutase-like activities showed butanol extracts from Ulmus devidiana root parts (Chinese) and water extracts from Ulmus devidiana bark parts (Korean). Electron donating abilities and nitric scavenging abilities of ethanol, methanol and butanol extracts were higher than those of water extracts. The nitrite scavenging abilities also reached the maximum at pH 1.2 and the minium at pH 6.0.

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The Synthesis and Electrochemical Performance of Microspherical Porous LiFePO4/C with High Tap Density

  • Cho, Min-Young;Park, Sun-Min;Kim, Kwang-Bum;Lee, Jae-Won;Roh, Kwang Chul
    • Journal of Electrochemical Science and Technology
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    • v.3 no.3
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    • pp.135-142
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    • 2012
  • Over the past few years, $LiFePO_4$ has been actively studied as a cathode material for lithium-ion batteries because of its advantageous properties such as high theoretical capacity, good cycle life, and high thermal stability. However, it does not have a very good power capability owing to the low lithium-ion diffusivity and poor electronic conductivity. Reduction in particle size of $LiFePO_4$ to the scale of nanometers has been found to dramatically enhance the above properties, according to many earlier reports. However, because of the intrinsically low tap density of nanomaterials, it is difficult to commercialize this method. Many studies are being carried out to improve the volumetric energy density of this material and many methods have been reported so far. This paper provides a brief summary of the synthesis methods and electrochemical performances of micro-spherical $LiFePO_4$ having high volumetric energy density.

The Thermal Dynamics of Fe Ion on the M-type Ba-ferrite (M형 Ba-Ferrite에서 Fe 이온의 열 진동에 관한 연구)

  • Sur, Jung-Chul;Ghim, Jin-Soo;Choi, Jong-Wan
    • Journal of the Korean Magnetics Society
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    • v.21 no.1
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    • pp.5-9
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    • 2011
  • M$\ddot{o}$ssbauer and Raman spectrum studies have been carried out on the 2b-site Fe ion in the Ba-ferrite (M-type). The thermal dynamics of Fe ion was analyzed by M$\ddot{o}$ssbauer spectra at different angles between the $\gamma$-ray direction and c-axis. The vibration on the 2b-site was more active compare to other direction and had very strong intensity in the Raman spectrum.