• 대한화학회지
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• 제25권5호
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• pp.318-324
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• 1981

일차입자의 크기와 응집상태가 다른 두 종류의 $Fe_2O_3$를 부분침전법과 ball-mill 혼합법으로 BaCO$_3$와 혼합한 $BaCO_3-Fe_2O_3$계의 고체반응에 있어 $Fe_2O_3$분체의 영향을 조사하였다. TG, XRD, SEM 등을 측정에 사용하였으며, X-선 회절분석결과 Ba-ferrite의 생성과정은 다음과 같은 연속적인 2단계로 이루어진다는 것을 알았다. $BaCO_3 + 6Fe_2O_3\;{\longrightarrow}\;BaFe_2O_3 + 5Fe_2O_3 + CO_2{\uparrow}\;BaFe_2O_4 + 5Fe_2O_3 \;{\longrightarrow}\;BaFe_{12}O_{19}$ 또 $Fe_2O_3$원료분체의 응집상태와 혼합방법은 고체반응에 현저한 영향을 미친다는 것을 확인했다.

• Elastomers and Composites
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• 제44권4호
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• pp.408-415
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• 2009

졸-겔 방법을 사용하여 Fe-ACF/$TiO_2$ 복합체 광촉매를 제조하였다. 여러 가지 철 전구체를 사용하여 세가지 Fe-ACF/$TiO_2$ 복합체를 제조하고 BET, SEM, XRD 및 EDX를 사용하여 특성화 하였다. UV 조사에서 Rh.B 용액의 분해에 의거하여 Fe-ACF/$TiO_2$ 복합체의 광촉매 특성을 파악 하였다. 실험 결과로부터, Fe-ACF/$TiO_2$ 복합체는 ACF/$TiO_2$ 복합체 보다 Rh.B의 제거 효과가 더 우수함을 나타내었다. 또한 여러 가지 Fe 전구체 사용으로 인한 Fe 원소의 포토-펜톤 효과는 다르게 나타났다. $FeCl_3$을 사용하여 제조된 Fe-ACF/$TiO_2$ 복합체는 가장 우수한 포토-펜톤 효과를 나타내었고, pH 변화에 의존하여 Rh.B 용액 분해에 대하여 영향을 주었다.

• 한국분말재료학회지
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• 제16권3호
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• pp.191-195
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• 2009

The calcination and hydrogen-reduction behavior of Fe- and Ni-nitrate have been investigated. $Fe_2O_3$/NiO composite powders were prepared by chemical solution mixing of Fe- and Ni-nitrate and calcination at $350^{\circ}C$ for 2 h. The calcined powders were hydrogen-reduced at $350^{\circ}C$ for 30 min. The calcination and hydrogen-reduction behavior of Fe- and Ni-nitrate were analyzed by TG in air and hydrogen atmosphere, respectively. TG and XRD analysis for hydrogen-reduced powders revealed that the $Fe_2O_3$/NiO phase transformed to $FeNi_3$ phase at the temperature of $350^{\circ}$. The activation energy for the hydrogen reduction, evaluated by Kissinger method, was measured as 83.0 kJ/mol.

• Structural Engineering and Mechanics
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• 제32권5호
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• pp.667-683
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• 2009

FE model-based dynamic analysis has been widely used to predict the dynamic characteristics of civil structures. In a physical point of view, an FE model is unavoidably different from the actual structure as being formulated based on extremely idealized engineering drawings and design data. The conventional model updating methods such as direct method and sensitivity-based parameter estimation are not flexible for model updating of complex and large structures. Thus, it is needed to develop a model updating method applicable to complex structures without restriction. The main objective of this paper is to present the model updating method based on the hybrid genetic algorithm (HGA) by combining the genetic algorithm as global optimization method and modified Nelder-Mead's Simplex method as local optimization method. This FE model updating method using HGA does not need the derivation of derivative function related to parameters and without application of complicated inverse analysis methods. In order to allow its application on diversified and complex structures, a commercial FEA tool is adopted to exploit previously developed element library and analysis algorithms. Moreover, an output-level objective function making use of measurement and analytical results is also presented to update simultaneously the stiffness and mass of the analysis model. The numerical examples demonstrated that the proposed method based on HGA is effective for the updating of the FE model of bridge structures.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2008년도 추계학술대회논문집
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• pp.441-446
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• 2008

The source transfer receiver model ('Source $\times$ Transfer = Response' model) which is widely used by NVH development process of vehicle/transport/machinery to analyze effectively and manage efficiently the structural dynamic behavior is also applicable to construction structure. If the evaluation assessment of the vibration level does not meet the target level, there are two methods, one is source treatment or replacement and the other is the reduction treatment on the transfer structure. In case of source treatment, it is done by source supplier and so, the latter is more practical method to reduce the vibration level. In this study, in order to get the accurate Transfer FE model(floor structure FE model), Experimental modal analysis of part of floor structure and FEM modal analysis of full floor structure are performed, then updating of FE model is performed after correlation analysis between these two results and finally, the modal model and FRF are compared between FE and Experimental results.

• Wind and Structures
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• 제10권1호
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• pp.61-82
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• 2007

This paper presents a novel finite element (FE) model for analyzing coupled flutter of long-span bridges using the commercial FE package ANSYS. This model utilizes a specific user-defined element Matrix27 in ANSYS to model the aeroelastic forces acting on the bridge, wherein the stiffness and damping matrices are expressed in terms of the reduced wind velocity and flutter derivatives. Making use of this FE model, damped complex eigenvalue analysis is carried out to determine the complex eigenvalues, of which the real part is the logarithm decay rate and the imaginary part is the damped vibration frequency. The condition for onset of flutter instability becomes that, at a certain wind velocity, the structural system incorporating fictitious Matrix27 elements has a complex eigenvalue with zero or near-zero real part, with the imaginary part of this eigenvalue being the flutter frequency. Case studies are provided to validate the developed procedure as well as to demonstrate the flutter analysis of cable-supported bridges using ANSYS. The proposed method enables the bridge designers and engineering practitioners to analyze flutter instability by using the commercial FE package ANSYS.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.629-632
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• 2013

Many properties of inorganic compounds are sensitive to changes in the point-defect concentrations. In minerals, such changes are influenced by temperature, pressure, and chemical impurities. Olivines form an important class of minerals and are magnesium-rich solid solutions consisting of the orthosilicates forsterite $Mg_2SiO_4$ and the fayalite $Fe_2SiO_4$. Orthosilicates have an orthorhombic crystal structure and exhibit anisotropic electronic and ionic transport properties. We examined the anisotropy of the electrical conductivity of $Fe_2SiO_4$ under the assumption that the electronic conduction in $Fe_2SiO_4$ occurs via a small polaron hopping mechanism. The anisotropic electrical conductivity is well explained by the electron transfer integrals obtained from the spin dimer analysis based on tight-binding calculations. The latter analysis is expected to provide insight into the anisotropic electrical conductivities of other magnetic insulators of transition metal oxides.

• 한국안전학회지
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• 제22권6호
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• pp.27-34
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• 2007

Static or dynamic elastomeric O-ring seals are installed between joining parts, and play key roles of high pressure-tightening. Sealing performance and structural safety of the O-ring are dependent on groove design, plain diameter, squeeze and applications such as pressure and temperature. In this study, to solve O-ring problem squeezed and highly pressurized under laterally one-sided constrained condition, hyperelastic FE analyses are performed, and FE results are compared with measured ones by computer-aided tomography, deformed shape and extrusion depth of the O-ring. Through the comparisons, FE analysis technique was verified. In order to evaluate design sensitivity, Taguchi method was used to select FE analysis cases. Adjustment parameters are clearance gap, groove comer radius, plain diameter and squeeze. By means of verified FE analysis technique, it has been analysed how the parameters have effects on contact stress fields, internal stress fields, and extrusion depths. Sealing performance has been evaluated based on contact stress fields and contact widths, and structural safety on internal stress and strain, extrusion lengths.

• 한국정밀공학회지
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• 제27권8호
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• pp.70-75
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• 2010

The aim of this study is to evaluate the axial residual stress in multi-pass drawn high carbon steel wire by using FE analysis and XRD. When FE analysis is applied to evaluate the residual stress in drawn wire of multi-pass drawing process, obtaining the reliable effective stress-strain curve at high strain is very important. In this study, a model, which can express the reliable effective stress-strain curve at high strain, is introduced based on the Bridgman correction and tensile test for multi-pass drawn high carbon steel wires. By using the introduced model, FE analysis was carried out to evaluate the axial residual stress in the drawn wires. Finally, the effectiveness of the FE analysis with the introduced stress-strain relation was verified by the measurement of residual stress in the drawn wires through XRD. As a result, the evaluated residual stress of FE analysis shows good agreement with the measured residual stress.

• Wind and Structures
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• 제26권2호
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• pp.75-87
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• 2018

A large number of low-rise buildings experienced serious roof covering failures under strong wind while few suffered structural damage. Clay and concrete tiles are two main kinds of roof covering. For the tile roof system, few researches were carried out based on Finite Element (FE) analysis due to the difficulty in the simulation of the interface between the tiles and the roof sheathing (the bonding materials, foam or mortar). In this paper, the FE analysis of a single clay or concrete tile with foam-set or mortar-set were built with the interface simulated by the equivalent nonlinear springs based on the mechanical uplift and displacement tests, and they were expanded into the whole roof. A detailed wind tunnel test was carried out at Tongji University to acquire the wind loads on these two kinds of roof tiles, and then the test data were fed into the FE analysis. For the purpose of validation and calibration, the results of FE analysis were compared with the full-scale performance ofthe tile roofs under simulated strong wind impact through one-of-a-kind Wall of Wind (WoW) apparatus at Florida International University. The results are consistent with the WoW test that the roof of concrete tiles with mortar-set provided the highest resistance, and the material defects or improper construction practices are the key factors to induce the roof tiles' failure. Meanwhile, the staggered setting of concrete tiles would help develop an interlocking mechanism between the tiles and increase their resistance.