• Title/Summary/Keyword: Fast ion

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Purification of type B Staphylococcal enterotoxin (Staphylococcus aureus에서 생성된 Enterotoxin B의 분리 및 정제)

  • 이정희;신현길;김종배;한재수
    • Journal of Food Hygiene and Safety
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    • v.3 no.2
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    • pp.75-81
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    • 1988
  • Various methods such as lel-mtration on Sephadex G-SO, 75, 100 Sephacry, and Ultro gel, and lon-exchanle chromatoaraphy on Amberilte and carboxymethyl (CM)-cellulose, and Fast Protein liquid Chromatolraphy (FPLC) were applied for the purification of enterotoxin B from Staphylococcus aureus ATCC 14458 and compared one another. lon-exchanle chromatography on Amberllte resin was good enough to remove non-entrotoxln materials in culture, convlnient to use and fast although tbe purity was less tban 70%. However, CM-cellulose showed to be better purity and yield tban those of Amberilte resin. The yields of these two resins for ion-exchange cbromatograpby were about 70% and 75%, respectively. When the gel-filtration methods on Sepbadex G-50, 75, 100, Sepbacryl, and Ultro lei were applied, the purities were about 90%. FPLC was found to be tbe most efficient metbod in terms of purity (96%) and speed. For the purification of sample with large volume, particularly, tbe combined metbod, gel-mtration after Amberlite can be also used efficiently. Tbe purified toxin was found to be identical to type B enterotoxin used for reference standard by Oucbterlony immunodiffusion test.

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Anode Properties of TiO2 Nanotube for Lithium-Ion Batteries (리튬이온전지용 TiO2 나노튜브 음전극 특성)

  • Choi, Min Gyu;Lee, Young-Gi;Kim, Kwang Man
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.283-291
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    • 2010
  • In this review, the studies on the electrochemical properties of $TiO_2$ nanotube as an anode material of lithium-ion battery, which was prepared by an alkaline hydrothermal reaction and anneling process, were investigated andanalyzed in terms of charge-dischage characteristics. Up to date, a maximum discharge capacity of $338mAh\;g^{-1}$(x=1.01) was achieved by the nanotube with $TiO_2(B)$ phase, whereas the theoretical capacity of $TiO_2$ anode was $335mAh\;g^{-1}$(x=1) in the basis of $Li_xTiO_2$ as a product of electrochemical reaction between $TiO_2$ and lithium. This was due to fast lithium transport by a shortened diffusion path provided by controlling the nanostructure of $TiO_2$, because the self-diffusion of lithium was slow in a basis of its activation energy as 0.48 eV. Due to an excellent ion storage capabilities in both the surface and the bulk phase, the $TiO_2$ nanotube could be a promising active material as both an anode of lithium-ion battery and an electrode of capacitor with high-rate performances.

Development of Pore Filled Anion Exchange Membrane Using UV Polymerization Method for Anion Exchange Membrane Fuel Cell Application (음이온교환막 연료전지 응용을 위한 UV 중합법을 이용한 세공 충진 음이온교환막 개발)

  • Ga Jin Kwak;Do Hyeong Kim;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.2
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    • pp.77-86
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    • 2023
  • In this study, pore-filled ion exchange membranes with low membrane resistance and high hydroxide ion conductivity was developed. To improve alkali durability, a porous substrate made of polytetrafluoroethylene was used, and a copolymer was prepared using monomers 2-(dimethyl amino) ethyl methacrylate (DMAEMA) and vinyl benzyl chloride (VBC) for pores. divinyl benzene (DVB) was used as the cross-linker, and ion exchange membranes were prepared for each cross-linking agent content to study the effect of the cross-linker content on DMAEMA-DVB and VBC-DMAEMA-DVB copolymers. As a result, chemical stability is improved by using a PTFE material substrate, and productivity can be increased by enabling fast photo polymerization at a low temperature by using a low-pressure UV lamp. To confirm the physical and chemical stability of the ion exchange membrane required for an anion exchange membrane fuel cell, tensile strength, and alkali resistance tests were conducted. As a result, as the cross-linking degree increased, the tensile strength increased by approximately 40 MPa, and finally, through the silver conductivity and alkali resistance tests, it was confirmed that the alkaline stability increased as the cross-linking agent increased.

Effects of Residual Stress and Surface Defect on the Mechanical Properties of the High Carbon Steel Filaments (고 탄소 미세 강선의 기계적 특성에 미치는 잔류 응력과 표면 결함의 영향)

  • Yang, Y.S.;Bae, J.G.;Park, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.134-137
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    • 2008
  • The effects of residual stress and surface defects on the mechanical properties of the high carbon steel filament used for the automotive tire have been experimentally investigated. The samples were fabricated with annealing temperature. The residual stress was measured by focused ion beam and strain mapping software which has advantages, such as data with high accuracy and fast data acquisition time. Mechanical properties, such as tensile strength and fatigue resistance, were gradually increased up to $200^{\circ}C$ and then slightly decreased. From the measurement of residual stress and level of surface defect, it was revealed that the critical factor was varied with different temperature region. That is, the fatigue resistance increased due to decreasing the residual stress and decreased due to increasing the size and distribution of surface defect.

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A High Efficiency Zero Voltage/Zero Current Transition Converter for Series Connected Battery Cell Equalization (영전압/영전류 스위칭을 이용한 고효율의 직렬 접속 배터리 전압 밸런싱 방법)

  • Kim, Tae-hoon;Park, Nam-Ju;Hyun, Dong-seok;Kim, Rae-young
    • Proceedings of the KIPE Conference
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    • 2011.11a
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    • pp.26-27
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    • 2011
  • This paper focuses on the zero-voltage/zero current transition voltage equalization circuit for the series connected battery cell. By adding auxiliary resonant cells at the main switching devices such as MOSFET or IGBT, zero current switching is achieved and turned off loss of switching elements is eliminated and by the voltage/second balancing of the inductor, zero voltage switching can be applied to switching element. Transformer coupling between battery cells and ZVZCT (Zero Voltage Zero Current Transition) switching method allow the fast balancing speed and high frequency operation, which reduces the size and weight of the circuit. The validity of the battery equalization is further verified using simulation involving four lithium-ion battery cell models.

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The Study on Two-color PIV Algorithm for a Measurement of Droplet Velocity (액적의 속도 측정을 위한 이색 PIV 알고리즘 연구)

  • Lee, K.H.;Lee, C.S.;Oh, S.I.
    • Journal of ILASS-Korea
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    • v.4 no.1
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    • pp.13-18
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    • 1999
  • It has been known that spray characteristics have an important effect on the mixture formation and directly influence the engine performances and the emissions. Up to now, the measurement of droplet size is well developed such as PDPA and PMAS though the behavior of small droplets during secondary atomization is not clear. Particle image velocimetry(PIV), a planar measuring technique, is a very efficient tool for studying complicated behavior and a fast and reliable method to track numerous droplets during injection. In this study, two-color scanning PIV is designed to obtain quasi-instantaneous two dimensional velocity data by using he-ion laser, rotating mirror and beam splitter. This PIV method which has high temporal and spatial resolution provides the information about the small complex droplet behavior.

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A Study of Flams Structure and Combustion Characteristics in a Premixed Flame Stabilized by a Stramlined Step(I) (유선형스텝에 의해 안정화된 예혼합 화염의 구조와 연소특성에 관한 연구(I))

  • 이재득;최병륜
    • Journal of the korean Society of Automotive Engineers
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    • v.12 no.3
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    • pp.63-70
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    • 1990
  • In a premixed flame stabilized by a streamlined step, the flame structure and combustion characteristics were investigated to identify the effect of the pressure pulsation in a combustion air. A flame stabilizing limits, visualization, mean temperature, ion current and gas concentration (O$_{2}$, CO$_{2}$, CO, UHC) were measured. With the combustion air of higher pressure pulsation, the development of the mixing layer was fast and wide, the temperature and combustion intensity were higher at arbitrary section. But, the effect was notably decreased with X=150 mm downstream. And a first eddy formation from step edge was earlier. Thus, with the combustion air of higher pressure pulsation, high rate of heat generation was expected.

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Dynamic Characteristics of Ionic-Polymer-Metal-Composite (IPMC의 동적 특성)

  • Jeon, J.H.;Shin, D.G.;Lee, K.H.;Oh, I.K.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.356-359
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    • 2005
  • Ionic-polymer-metal-composite(IPMC), one of new actuation materials of electroactive polymers plated with noble metallic electrodes is known for the fast bending upon electric field. The IPMC strip bends towards anode under electrical field. It has many merits of low driving voltage, quick responsiveness, high durability, possibility of miniaturizability. In this paper, we studied for developing the large deflection of IPMC according several fabricating parameters. We measured the large deflection by the different process of sandpaper and sandblasting in surface treatment, the initial compositing process and the surface electroding process, and the different counter ions in ion exchanging process. In fundamental, the displacement of IPMC strip depends on voltage magnitude and applied signal frequency and its maximum deformation is observed at a critical frequency, resonant frequency.

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Ultra Shallow Junction wish Source/Drain Fabricated by Excimer Laser Annealing and realized sub-50nm n-MOSFET (엑시머 레이져를 이용한 극히 얕은 접합과 소스, 드레인의 형성과 50nm 이하의 극미세 n-MOSFET의 제작)

  • 정은식;배지철;이용재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.562-565
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    • 2001
  • In this paper, novel device structures in order to realize ultra fast and ultra small silicon devices are investigated using ultra-high vacuum chemical vapor deposition(UHVCVD) and Excimer Laser Annealing (ELA). Based on these fundamental technologies for the deep sub-micron device, high speed and low power devices can be fabricated. These junction formation technologies based on damage-free process for replacing of low energy ion implantation involve solid phase diffusion and vapor phase diffusion. As a result, ultra shallow junction depths by ELA are analyzed to 10~20nm for arsenic dosage(2${\times}$10$\_$14//$\textrm{cm}^2$), exciter laser source(λ=248nm) is KrF, and sheet resistances are measured to 1k$\Omega$/$\square$ at junction depth of 15nm and realized sub-50nm n-MOSFET.

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Recent Advances in High-performance Functional Ceramics using 3D Nanostructuring Techniques (3차원 나노구조화 기술을 이용한 고성능 기능성 세라믹 연구개발 동향)

  • Ahn, Changui;Park, Junyong;Jeon, Seokwoo
    • Ceramist
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    • v.22 no.3
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    • pp.230-242
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    • 2019
  • Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based high-performance applications containing photocatalysts, structural materials, energy harvesting and storage devices.