• Title/Summary/Keyword: FTIR spectrometer

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Analysis of sampling noise effect of Interferometer on FTIR Spectrometer (FTIR 분광용 간섭계의 샘플링 잡음 영향 분석)

  • Bae, Hyo-Wook;Park, Do-Hyun;Ra, Sung-Woong;Choi, Seung-Ki
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.4
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    • pp.10-17
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    • 2007
  • FTIR(Fourier Transform Infrared) spectrometry is a useful method to obtain infrared spectra of materials in gas phase by registering the interferogram of a target material using an interferometer, and then performing a Fourier transform on the interferogram to obtain the spectrum. In this paper, sampling noise effect on signal processing of the rapid scan interferometer was studied with relation to sampling the interferogram points at the improper location and empirically verified.

Research on Far-Infrared Optical Spectra of Blood Substances using FTIR-spectrometer (FTIR Spectrometer를 이용한 혈중성분의 원적외선 분광 스펙트럼에 관한 연구)

  • 김건식;최우석;박승한;전계진;윤길원
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.122-123
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    • 2000
  • 혈중 성분, 또는 생체 시료와 빛의 상호작용에 관한 연구는 비침습적 정량분석, 또는 생체 조직의 상태 분석의 가능성을 의미하므로 많은 분야에서 연구가 진행되고 있다. 최근에는 원적외선 검출소자가 급속히 개발됨에 따라 원적외선(8~15$mu extrm{m}$)영역에서의 생체 시료 및 성분들의 정량적인 분석과 영상에 관한 연구가 큰 주목을 받고 있다. 그중 혈중 Glucose 성분의 정량분석에 관한 연구는 여러가지 분광법-특히 NIR 영역에서 흡수, 투과, ATR, NMR 등-으로 활발히 연구되고 있으며$^{1)}$ , 최근에는 FIR 영역에서 혈중 성분들이 특정한 흡수 봉우리를 가지고 있음이 확인되어 이 영역에서의 분광법과 정량 분석에 대한 관심이 고조되고 있다. 본 연구에서는 혈중 성분들의 원적외선 영역에서 빛과의 상호작용인 흡수 spectrum을 측정하여 정량분석에 대한 가능성을 확인하였다. 생체를 이루는 가장 기본인 물에 대한 흡수 spectrum의 연구를 먼저 수행하였고, 혈중 성분중 Glucose, Hb, Albumin 등의 수용액을 농도별로 흡수 spectrum측정을 하였다. (중략)

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The Preparation of Multi-walled CNT-PMMA Nanocomposite

  • Seo, D.W.;Yoon, W.J.;Park, S.J.;Jo, M.C.;Kim, J.S.
    • Carbon letters
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    • v.7 no.4
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    • pp.266-270
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    • 2006
  • Multi-walled carbon nanotube-poly methyl methacrylate (MWNT/PMMA) nanocomposite has been prepared by in situ polymerization of MMA dispersed with MWNTs. The MWNTs were functionalized by nitric acid and sulfuric acid treatment, and this was confirmed by FTIR spectrometer. The solution mixture of MWNTs and MMA was partially polymerized at $80^{\circ}C$, followed by the addition of AIBN and polymerization at $50^{\circ}C$. The MWNT-PMMA composite was prepared by casting the pre-polymer on the glass plate, and the optical properties have been studied using UV-vis spectrometer. The acid treated MWNTs were well dispersed in MMA with fairly good dispersion stability, while flocculation and sedimentation was observed from raw MWNTs in MMA.

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A study on combustion gas toxicity of polymeric materials using FTIR gas analysis (FTIR 가스분석에 의한 고분자재료의 연소가스독성 평가)

  • Lee, Doo-Hyung;Kong, Young-Kun
    • Journal of the Korean Society of Hazard Mitigation
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    • v.5 no.4 s.19
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    • pp.79-84
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    • 2005
  • When polymeric materials are exposed to fire condition, a lot of heat and toxic gases evolved and cause damage to property and human being. Especially toxic gases are major hazard to life safety. This study FTIR(Fourier Transform Infrared) spectrometer analysis was performaed to etermine the gas analysis and the concentration of gases evolved from PVC, FRP, SMC and Ureathane foam using ASTM E 1678 fire model. And FED toxicity index calculated from FTIR data also presented. By the comparison of animal test adopted in KS F 2271 and FTIR gas analysis method, FTIR gas analysis method can replace current animal toxicity test and produce precise and quantitative combustion gas data.

Fourier transform infrared spectroscopy과 Quadrupole mass spectrometer을 이용한 Cyclopentadienyl Tris (dimethylamino) Zirconium의 열분해 특성 연구

  • O, Nam-Geun;An, Jong-Gi;Gang, Go-Ru;Kim, So-Yeon;Kim, Jin-Tae;Yun, Ju-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.99.1-99.1
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    • 2015
  • ALD와 CVD 공정을 진행 하는데 있어서 전구체의 평가 및 실시간 분해과정을 확인 하는 것은 매우 중요하다. 본 실험에서는 고유전 산화막에 쓰이는 Cyclopentadienyl Tris (dimethylamino) Zirconium, CpZr(NMe2)3 전구체의 증기압 특성과 FTIR, QMS를 활용하여 $250^{\circ}C$ 온도구간 에서의 분해과정을 실시간으로 측정 하였다. CpZr(NMe2)3의 Atomic mass 는 288 amu이며 증기압은 $60^{\circ}C$에서 0.075 Torr로 측정되었다. 온도가 증가 함에 따라 FTIR 에서 CH3 symmetric stretch (2776 cm-1), CH3 symmetric stretch (2865 cm-1) intensity가 줄어 들게 되었으며 QMS에서도 15 amu (Methyl)의 신호가 온도가 증가함에 따라 감소함을 확인 할수 있었다. QMS에서 Cp의 이온전류가 사라진 이유는 Cp가 모체인 CpZr에서 모두 다 분리되었고 신호가 없어 졌기 때문이다. 본 연구를 통해서 FTIR 단독으로는 얻을수 없는 온도에 따른 세부적인 분해과정을 QMS로 실시간 측정 함으로서 FTIR의 분석 결과와 산호보완 할수 있게 되었다.

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Application of Photoacoustic Rapid Scan FTIR for the Determination of Kappa Number of Pulp

  • Dang Vinh Q.;Bhardwaj Nishi K.;Nguyen Kien L.
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.167-172
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    • 2006
  • High-yield Pinus radiate kraft pulps with various Kappa number were produced from flow-through laboratory pulping. The samples were prepared and scanned using a rapid scan photoacoustic Fourier transform infrared (PAS-FTIR) spectrometer. A partial-least-squares (PLS) model was established based on the spectral data collected at different mirror velocities. The model was used to predict the Kappa number of the pulps and its robustness was statistically evaluated. The outcomes indicate that the PLS model can be used to predict the Kappa number of Pinus radiata kraft pulps with a high degree of accuracy provided that the moving mirror velocity is ${\leq}\;0.5cm/s$.

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DIAMOND-LIKE CARBON FILMS FOR ANTIREFLECTION COATINGS OF GERMANIUM INFRATED OPTICAL LENSES

  • Kim, Seong-Young;Lee, Sang-Hyun;Lee, Jai-Sung
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.461-466
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    • 1999
  • Diamond-like carbon(DLC) films were directly deposited onto germanium(Ge) witness pieces and lenses by a capacitively coupled 13.56 MHz RF glow discharge plasma with $CH_4$ gas. The characterizations of DLC films were measured using a Raman and FTIR spectrometer. The configuration of Raman and FTIR spectra had a traditional shape. The IR transmittance was measured using an IR spectrophotometer. The maximum values of the IR transmission of Ge with the DLC/Ge/DLC, DLC/Ge/BBAR (broad band antireflection), DLC/Ge, and BBAR/Ge structures are 98%, 93%, 64%, and 63.5%, respectively, which come up to the theoretical values. The uniform DLC films were obtained by a rotation of the cathode at certain conditions.

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Induction Mechanism of Planar Arrangement in Cholesteric Liquid Crystals (콜레스테릭 액정의 Planar 배열 유도 메카니즘)

  • Jung, Gap-Ha;Lee, Mong-Ryong;Seo, In-Seon;Song, Ki-Gook
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.272-276
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    • 2011
  • The induction mechanisms of planar arrangements in cholesteric liquid crystals (CLC) which showed selective reflections of visible light were investigated by measuring the selective reflectivity and FTIR peak intensity of $C{\equiv}N$ stretching band. Although the planar arrangement of CLC was not as perfectly induced as the cases prepared with using alignment layers, it could be also induced by stretching polymer substrate or by applying shear forces. The planar arrangements were induced by forming CLC helical structures on top of liquid crystal molecules which were in contact with the substrate and oriented all in the same direction.

Study on the Curing Properties of Photo-curable Acrylate Resins (광경화성 아크릴 수지의 경화특성에 관한 연구)

  • Kim, Sung-Hyun;Chang, Hyun-Suk;Park, Sun-Hee;Song, Ki-Gook
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.469-473
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    • 2010
  • The curing mechanism and characteristics of UV curable acrylate resins were studied using Photo-DSC, FTIR, and Raman spectroscopy. Effects of chemical structures of acrylate, numbers of functional group, and UV intensity on curing kinetics were investigated with Photo-DSC. FTIR and Raman spectroscopy has been used to understand curing mechanisms and reaction conversion. In order to investigate the effect of oxygen on the photo-curing reaction, the curing process was compared between the acrylate and thiol-ene resins. The reaction conversion was found to be less than 80% for acrylate resins. The photo-curing reaction of the acrylate resin could not proceed to the end because of oxygen which acts as a reaction inhibitor while the thiol-ene resin was hardly affected from oxygen during the curing process.