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Crystal structure of 1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind (1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind의 결정구조해석)

  • 조소라;김문집
    • Korean Journal of Crystallography
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    • v.6 no.1
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    • pp.27-35
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    • 1995
  • The crystal structure of 1-tert-butoxycarbonyl-4-[N-(tert-butoxycarbonyl)-N-(ethoxycarbonylmethyl)amino]-3-phenylsulfonylpyrrolidind [C24H36O8N2S] has been from single crystal x-ray diffraction study ; C24H36O8N2S triclinic, p1, a=11.363(8)Å, b=11.589(6)Å, c=11.013(10)Å,α=95.32(6)°,β=98.64(7)°,γ=79.57(5)°,V=1406.8(18)Å3, t=293K, Z=2, CuKα(λ=1.5418Å). The molecular structure was solved by diredt method and refined by full-matrix least squares to a final R=9.78% for 3621 unique observed [F≥4σ(F)] reflections and 703 paramenters.

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A Study of the Family Caregiver's Burden for the Elderly with Chronic disease in a Rural Area (일부 농촌 지역 노인 만성질환자 가족의 부담감에 관한 연구)

  • Jang, In-Sun
    • Journal of Korean Academic Society of Home Health Care Nursing
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    • v.2
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    • pp.19-34
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    • 1995
  • The purpose of this study was to analysis level on family caregiver's burden for the elderly with chronic disease in a rural area and to choose priority care group, thereby facilitating the development of interventions to reduce the caregiver's burden. For this purpose, data were collected by questionaire from June 10 to October 8, 1994. The instruments for data collection were Caregiver Burden Inventory by Novak(1989) and Zarit et al(1982), severity of dementia by Hughes Scales(1982), ADL by Lawton(1971), patients' family caregiving activity by pre-survey and reference review(Lee, 1993 ; Jang, 1990 ; Yoo, 1982). The subjects were 213 family caregiver of elderly with chronic disease in a rural area. The data was analysed by the use of t-test, ANOVA, correlation and multiple regression. The results were as follows ; 1. Total burden was evaluated below average, the mean of family burden was 46.98. By the diagnostic classification, Hypertension was 27.37, DM 32.46, CVA 62.96, Dementia 61.24. 2. Significant variables which were correlated to the family caregiver's burden were the patient's disease diagnosis (F=33.82, p<0.001), severity of dementia(F=30.52, p<0.001), the status of disease management(F=11.53, p<0.001), ADL(F=10.54, p<0.001), PADL(F=7.50, p<0.001), income(F=7.17, p<0.001), caregiver's health status(F=24.53, p<0.001), a view of patient's prognosis (F=22.17, p<0.001), relationship with the patient(F=33.82, p<0.001), the number of hours per day spent on caregiving(F=77.52, p<0.001), level of intimacy of caregiver and patients(F=8.75, p<0.001), level of helping(F=4.90, p<0.01), the frequency of caregiving activity(F=3.80, p<0.01), the number of admission(F=5.54, p<0.01), the length of caregiving(F=4.43, p<0.01), other chronic patient in family(t=2.81, p<0.01), caregiver's job(F=3.11, p<0.01), the duration of illness(F=2.98, p<0.05), caregiver's religion(F=2.93, p<0.05), medical security(F=3.89, p<0.05), caregiving's helper(t=2.42, p<0.05). 3. PADL was the most important predictor to family caregiver burden(R2=0.6611). In addition to this, IADL, caregiver's health status, the length of caregiving. level of intimacy of caregiver and patients, patient's age, the patient's disease diagnosis and patient's job accounted for 76% of family caregiver burden. 4. The criteria of priority care group were as follows ; the mean of family caregiver burden was above 58, above of moderate ADL, the number of hours per day spent on caregiving above of 8 hours, above of moderate dementia. By the diagnostic classification, number of priority care group, Hypertension was 4 (8.0%), DM 4(8.0%), CVA 34(64.1%), Dementia 45(75.0%).

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Effect of Career Empowerment Program on Career Maturity, Career Decision-making Self-Efficacy, and Employment Stress of Nursing College Students (진로능력강화프로그램이 간호학생의 진로성숙도, 진로결정자기효능감 및 취업스트레스에 미치는 효과)

  • Kim, Yeong-Hee
    • The Journal of the Korea Contents Association
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    • v.13 no.12
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    • pp.817-828
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    • 2013
  • This study was pre-experimental research designed to compare the differences between pre-and post-program on nursing student's career maturity, career decision-making self-efficacy and employment stress. The subjects were 247 junior-year students in nursing school. Mean value for career maturity was from 2.59 to 2.57, career decision-making self-efficacy from score 3.44 to 3.65 in average(t=8.67, p<.001), and employment stress from score 2.94 to 2.83 in average(t=-3.46, p<.001). Career maturity was significantly different according to high employment rate(F=3.15, p=.025), high career preparation(F=2.69, p=.032). Career decision-making self-efficacy and employment stress was significantly different according to high career preparation(F=1.22, p=.031) and low career preparation(F=2.52, p=.030).

ON QUASI-CLASS A OPERATORS

  • Kim, In Hyoun;Duggal, B.P.;Jeon, In Ho
    • Korean Journal of Mathematics
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    • v.19 no.2
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    • pp.205-209
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    • 2011
  • Let $\mathcal{QA}$ denote the class of bounded linear Hilbert space operators T which satisfy the operator inequality $T^*|T^2|T{\geq}T^*|T|^2T$. Let $f$ be an analytic function defined on an open neighbourhood $\mathcal{U}$ of ${\sigma}(T)$ such that $f$ is non-constant on the connected components of $\mathcal{U}$. We generalize a theorem of Sheth [10] to $f(T){\in}\mathcal{QA}$.

Low Temperature Sintering of B2O3 -added (Zn0.8Mg0.2)TiO3 Microwave Dielectric Ceramics (B2O3 가 첨가된 (Zn0.8Mg0.2)TiO3 마이크로파 유전체 세라믹스의 저온소결)

  • Bang, Jae-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.29-34
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    • 2006
  • The effects of $B_2O_3$ addition on the low-temperature sintering behavior and microwave dielectric properties of $(Zn_{0.8}Mg_{0.2})TiO_3$ ceramic system were investigated. Highly dense samples were obtained at the sintering temperatures below $900^{\circ}C$. The $Q{\times}f_o$ values were determined by the microstructures and sintering shrinkages which are affected by the amount of $B_2O_3$ and sintering temperature. Temperature coefficient of resonance frequency($T_f$) changes to a positive value with increasing the amount of $B_2O_3$ due to the increased amount of rutile phase which is one of the reaction products between $(Zn_{0.8}Mg_{0.2})TiO_3$ and $B_2O_3$. For $6.19 moi.{\%}B_2O_3$-added $(Zn_{0.8}Mg_{0.2})TiO_3$ system, it exhibits ${\epsilon}_r$ = 23.5, $Q{\times}f_o$ = 53,000 GHz, and $T_f$ = 0 ppm/$^{\circ}C$ when sintered at $900^{\circ}C$ for 5 h.

Estimation of Nitrate Sources in Cheju Island Groundwater using $\delta$$^{15}$ N ($\delta$$^{15}$ N을 이용한 제주도 지하수 중의 질산염 오염원 조사)

  • 송영철;고용구;유장걸
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.3
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    • pp.107-110
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    • 1999
  • 18 boreholes with nitrate contaminated were selected. Samples were collected 4 times between both 1995 and 1996. Stable nitrogen isotope ratio for them all was measured and the contribution to contamination from several sources like fertilizer, sewage, cropland. and landfill was analysed. Nitrogen source for 11 sampling sites of T-3, L-1. O-1∼O-4, F-2∼F-5, and G-2 considered to come from chemical fertilizer and its contribution was around 60% or more. T-4. T-5 were located downward the downtown, which were influenced bydomestic sewage and its contribution were 70.7% and 54.7%. Nitrate concentration of G-2 was 17.7 mg/L, among which 60.7% was estimated to come from landfill leachate. T-1 and T-2 were located in the small village, in which 42.2 and 43.4% of nitrogen was to come from domestic sewage but 52.8% and 56.0% were from fertilizer sprayed in the cropland. L-2 was near livestock by which it was estimated to be influenced, in which 59.9% of nitrogen was from cropland. F-1 was in the cropland, by which 50.0% was influenced and 49.5% was estimated from organic matter of animals.

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Sexual Knowledge and Attitudes among Middle School Students (중학생의 성 지식과 성 태도)

  • Kim Shin-Jeong;Yang Soon-Ok
    • Child Health Nursing Research
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    • v.10 no.3
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    • pp.350-360
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    • 2004
  • Purpose: To suggest ideas that promote sexual health and useful in planning sex education programs for middle school students. Method: This study surveyed 661 middle school students from three schools in Seoul and Chunchon. Result: The average degree of sexual knowledge was 31.5, while attitude was 32.5. There were statistically significant differences in sexual knowledge in relation to: coeducational environment (t=-5.776, p=.000), grade (F=36.351, p=.000), father's age (t=-2.510, p=.012), mother's age (t=-2.146, p=.032), economical status (F=3.264, p=.039), source of sexual knowledge (F=8.484, p=.000), the degree of interest in the opposite sex (F=16.871, p=.000), sexual discussions with parents (t=3.556, p=.000), sexual discussions with teachers (t=2.847, p=.005), and sex education (t=2.148, p=.032). Likewise, stastically significant differences in sexual attitudes were linked to: coeducational environment (t=-7.646, p=.000), subject's grade (F=32.743, p=.000), parental marriage status (t=2.338, p=.020), mother's age (t=-2.048, p=.041), source of sexual knowledge (F=6.917, p=.000), the degree of interest in the opposite sex (F=15.559, p=.000), sexual discussions with parents (t=3.908, p=.000), and sexual discussions with teachers (t=2.946, p=.003). The students level of sexual knowledge and attitude was significantly correlated (r=.686, p=.000). Conclusion: This study indicates a variety of systematic sexual education programs are needed for middle school student at home and school.

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The Crystal Structure of N-(Diphenylmethylene) aminomethylphosphonate (N-(Diphenylmethylene)aminomethylphosphonate의 결정 구조)

  • 김문집;박호종;김대영
    • Korean Journal of Crystallography
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    • v.13 no.2
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    • pp.86-90
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    • 2002
  • The structure of N-(Diphenylmethylene)aminomethylphosphonate has been determined by X-ray diffraction methods. The crystal system is triclinic, space group P(equation omitted), unit cell constants, a=8.967(2) (equation omitted), b=9.309(2) (equation omitted), c= 10.981(2) (equation omitted), α=101.42(2)°, β=92.22(2)°, γ=92.23(2)°, V=896.8(3) (equation omitted), T=296 K, Z=2, D/sub c/=1.227 Mgm/sup -3/. The intensity data were collected on an Enraf-Nonius CAD-4 Diffractometer with graphite monochromated MoKα radiation (λ=0.7107(equation omitted)). The molecular structure was solved by direct methods and refined by full-matrix least-squares to a final R=7.3% for 979 unique observed F/sub o/>4σ(F/sub o/) refections and 209 parameters.

ON WEYL'S THEOREM FOR QUASI-CLASS A OPERATORS

  • Duggal Bhagwati P.;Jeon, In-Ho;Kim, In-Hyoun
    • Journal of the Korean Mathematical Society
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    • v.43 no.4
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    • pp.899-909
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    • 2006
  • Let T be a bounded linear operator on a complex infinite dimensional Hilbert space $\scr{H}$. We say that T is a quasi-class A operator if $T^*\|T^2\|T{\geq}T^*\|T\|^2T$. In this paper we prove that if T is a quasi-class A operator and f is a function analytic on a neigh-borhood or the spectrum or T, then f(T) satisfies Weyl's theorem and f($T^*$) satisfies a-Weyl's theorem.

Study of the Actual Condition and Satisfaction of Volunteer Activity in Australian Hospital (호주 일 지역의 병원 자원봉사활동 실태와 만족도)

  • Park, Geum-Ja;Choi, Hae-Young
    • Journal of Hospice and Palliative Care
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    • v.9 no.1
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    • pp.17-29
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    • 2006
  • Purpose: This research aimed to investigate the actual condition and satisfaction of volunteer activity in Australian hospital. Methods: Data was collected by self reported questionnaire from 101 volunteers and analyzed by frequency and percentage, t-test, ANOVA and Sheffe and Pearson's correlation coefficients using SPSS 12.0. Results: 1. Years involved in volunteer work were $5{\sim}10$ years (32.7%), above 10 years (30.7%), $2{\sim}3$ years (11.9%) and $3{\sim}5$ years (10.9%). Types of volunteer work were physical care (32.7%), physical and emotional care (14.9%), and others (18.8%). Types of allocation of tasks were by volunteer coordination (55.7%), and by volunteer preference and consent between volunteer and coordinator (both respectively, 20.5%). Main reasons for volunteer work were to help sick people (61.4%) and to make good use of leisure time (22.8%). Routes to start volunteer work were from his (her) own inquiries (43.4%), from hearing from other volunteers (30.7%) and from mass media (13.1%). 80.2% of volunteers had received some kinds of training or preparation for volunteer work. Suitability of volunteer's skill and ability to voluntary work were 'very well' (74.0%) and 'mostly well' (18.0%). Reimbursements or benefits received for volunteer work were token or lunch or group outing (31.7%), and token and lunch or group outing (19.8%). Evaluation frequency for volunteer work was occasionally (372%), frequently (30.9%), always (17.0%) and never (14.9%). Relationship with volunteer work coordinator was very good (85.0%). The relationship with other volunteers was very good (81.2%). The relationship with hospital staffs was very good (69.7%) and mostly good (21.2%). Family and friend's support for volunteer work was very good (83.2%). 2 The mean score of satisfaction for the hospital volunteer activity was $3.09{\pm}0.49\;(range:\;1{\sim}4)$. The highest score domain was 'social contact', $3.48{\pm}0.61$, and the lowest was 'social exchange', $1.65{\pm}0.63$. An item of the highest score was 'I have an opportunity to help other people' ($3.83{\pm}0.40$), and the lowest score item was 'I will receive compensation for volunteer work I have done ($1.10{\pm}0.78$).' 3. The satisfaction from hospital volunteer activity was shown by significant difference according to sex (t=2.038, P=0.044), marital status (F=3.806, P=0.013), years involved in volunteer work (F=3.326), nam reason to do volunteer work (F=2.707, P=0.035), receive any training or preparation for volunteer work (t=-1.982, 0=0.050), frequency of evaluation for volunteer work (F=7.877, P=0.000), suitability of volunteer's skill and ability to voluntary work (t=2.712, P=0.049), relationship with volunteer work coordinators (F=-2.517, P=0.013), relation with hospital staffs (F=5.202, P=0.007), and support of their volunteer work by their family and friends (t=-3.394, P=0.001). Conclusion: The satisfaction of hospice volunteer activity was moderate. The satisfaction for hospice volunteer activity was shown by significant difference according to sex (t=2.038, P=0.044), marital status (F=3.806, P=0.013), years involved in volunteer work (F=3.326), main reason to do volunteer work (F=2.707, P=0.035), receive any training or preparation for volunteer work (t=-1.982, 0=0.050), frequency of evaluation for volunteer work (F=7.877, P=0.000), suitability of volunteer's skill and ability to voluntary work (t=2.712, P=0.049), relationship with volunteer work coordinator (F=-2.517, P=0.013), relation with hospital staffs (F=5.202, P=0.007), and family and friend's support for volunteer work (t=-3.394, P=0.001). Therefore, it is necessary to consider various factors to improve the satisfaction of voluntary work.

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