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Investigation of GaN Negative Capacitance Field-Effect Transistor Using P(VDF-TrFE) Organic/Ferroelectric Material (P(VDF-TrFE) 유기물 강유전체를 활용한 질화갈륨 네거티브 커패시턴스 전계효과 트랜지스터)

  • Han, Sang-Woo;Cha, Ho-Young
    • Journal of IKEEE
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    • v.22 no.1
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    • pp.209-212
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    • 2018
  • In this work, we developed P(VDF-TrFE) organic/ferroelectric material based metal-ferroelectric-metal (MFM) capacitors in order to improve the switching characteristics of gallium nitride (GaN) heterojunction field-effect transistors (HFET). The 27 nm-thick P(VDF-TrFE) MFM capacitors exhibited about 60 ~ 96 pF capacitance with a polarization density of $6{\mu}C/cm^2$ at 4 MV/cm. When the MFM capacitor was connected in series with the gate electrode of GaN HFET, the subthreshold slope decreased from 104 to 82 mV/dec.

Electrochemical Properties of Polyaniline Electrodes Prepared by Chemical Synthesis and Electrodeposition: Revisited with High-Scan-Rate Behaviors

  • Nam, Ji Hyun;Woo, Cho Hyeon;Kim, Kwang Man;Ryu, Kwang Sun;Ko, Jang Myoun
    • Journal of Electrochemical Science and Technology
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    • v.3 no.2
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    • pp.80-84
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    • 2012
  • The polyaniline (PANI) electrodes are prepared by chemical synthesis and electrodeposition methods and their supercapacitive properties are characterized and compared by morphology observation, cyclic voltammetry as a function of scan rate, and impedance spectra analysis. In particular, the supercapacitive properties obtained in the range of higher potential scan rates (e.g., over $200mV\;s^{-1}$) are emphasized to be capable of utilizing adequately the high power capability of supercapacitor. As a result, the PANI electrode by the electrodeposition shows superior specific capacitance (max. $474F\;g^{-1}$ at $10mV\;s^{-1}$ and about $390F\;g^{-1}$ at $500mV\;s^{-1}$) than those by the chemical synthesis method. This is mainly due to highly porous structure obtained by the electrodeposition to yield higher specific surface area.

MnO2 Nanowires Electrodeposited in a Porous Network of Agarose Gel as a Pseudocapacitor Electrode

  • Jin, Sohyun;Ryu, Ilhwan;Lim, Geo;Yim, Sanggyu
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.406-410
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    • 2020
  • Despite a simple preparation of manganese oxide (MnO2) nanowires by electrodeposition, the improvement in specific capacitance (Csp) and voltammetric response of the MnO2 nanowire-based electrodes has been quite limited. This is attributed to the poor electrical conductivity of MnO2 and its dense bulk morphology due to the aggregation of the nanowires. This study investigated the capacitive performance of MnO2 nanowires electrodeposited on agarose thin films. The good ionic conductivity and porous network of the agarose film provided favorable growth conditions for the MnO2 nanowires with suppressed aggregation. A maximum Csp value of 686 F/g measured at a scan rate of 10 mV/s was obtained, which was significantly larger than that of 314 F/g for the agarose-free MnO2 electrode at the same scan rate. The rate capability was also improved. The Csp measured at a high scan rate of 100 mV/s retained 74.0% of the value measured at 10 mV/s, superior to the retention of 71.1% for the agarose-free MnO2 electrode.

$RuO_2$ Related Schottky contact for GaN/AlGaN device

  • Jung, Byung-Kwon;Kim, Jung-Kyu;Lee, Jung-Hee;Hahm, Sung-Ho
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.85-90
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    • 2002
  • $RuO_2$/GaN and related contacts were investigated for Schottky contacts in GaN-Based optical and electronic devices. We demonstrated that an $RuO_2$ film forms a stable Schottky contact on a GaN layer with a barrier height (${\Phi}_B$) of 1.46 eV and transmittance of 70% in the visible and near UV region. $RuO_2$/GaN Schottky diode showed a breakdown at over -50V and leakage current of only 0.3 nA at -5V. The $RuO_2$/GaN Schottky type photodetector had the UV/Visible rejection ratio of over $10^5$ and the responsivity of 0.23 A/W at 330 nm. The $RuO_2$ gate AlGaN/GaN EFET exhibited high drain current ($I_d$) of 689.3 mA/mm and high transconductance ($g_m$) of 197.4 mS/mm. Cut-Off frequency ($f_t$) and maximum operating frequency ($f_{max}$) were measured as 27.0 GHz and 45.5 GHz, respectively.

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Comparison of Vitality among Three Cool-Season Turfgrasses during Summer using Chlorophyll Fluorescence (엽록소형광을 이용한 한지형 잔디 3종의 하절기 활력도 비교 분석)

  • Koh, Seok Chan
    • Journal of Environmental Science International
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    • v.30 no.7
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    • pp.547-555
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    • 2021
  • To compare the vitality among cool-season turfgrasses under summer weather conditions and to obtain information to improve the management of turfgrasses in golf courses and sports fields., the chlorophyll fluorescence of three cool-season turfgrasses commonly planted on golf courses in the Jeju area was measured. The turfgrasses were perennial ryegrass (Lolium perenne L.), Kentucky bluegrass (Poa pratensis L.), and creeping bentgrass (Agrostis palustris Huds.). In perennial ryegrass and Kentucky bluegrass, the chlorophyll index was low in early summer and high in late summer. In creeping bentgrass, it remained low throughout the study. Fo tended to be low in the early summer and high in late summer in the three turfgrasses. However, the difference in Fo between late summer and early summer was markedly higher in perennial ryegrass than in Kentucky bluegrass or creeping bentgrass. Fm tended to be low in early summer and high in late summer, without obvious differences among the three turfgrasses. Fv/Fm, a measure of photochemical efficiency, was also low in early summer and high in late summer in the three turfgrasses. However, Fv/Fm in late summer was mostly higher in Kentucky bluegrass and creeping bentgrass than in perennial ryegrass, indicating that the former are more resistant to the high temperature and humidity of late summer. Furthermore, Kentucky bluegrass had a high chlorophyll index in late summer and would be most resistant to the harsh conditions of late summer.

Simultaneous determinations of anthracycline antibiotics by high performance liquid chromatography coupled with radial-flow electrochemical cell (고성능 액체 크로마토그래피/방사흐름 전기화학전지를 이용한 안트라사이클린계 항생제의 동시 정량)

  • Cho, Yonghee;Hahn, Younghee
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.308-314
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    • 2007
  • The analytical method of HPLC with the radial-flow electrochemical cell (RFEC) has been developed to determine doxorubicin, epirubicin, nogalamycin, daunorubicin and idarubicin simultaneously by employing a reversed-phase chromatography. Anthracyclines were detected at -0.74 V vs. a Ag/AgCl (0.01 M NaCl) reference electrode, a potential of diffusion current plateau in the mobile phase. At a $V_f$ of 1.0 mL/min doxorubicin, epirubicin, daunorubicin and idarubicin appeared at a retention time ($t_r$) of 6.4 min, 7.4 min, 12.7 min and 18.4 min, respectively, while at a $V_f$ of 0.6 mL/min, doxorubicin, epirubicin, nogalamycin, daunorubicin and idarubicin appeared at a $t_r$ of 9.9 min, 11.5 min, 13.5 min, 19.6 min and 28.7 min, respectively. The linearity between each anthracycline injected ($2.40{\times}10^{-7}M{\sim}1.42{\times}10^{-5}M$) and peak area (charge) was excellent with the square of the correlation coefficient ($R^2$) higher than 0.999. The detection limits were $1.0{\times}10^{-8}M{\sim}1.5{\times}10^{-7}M$ for the five anthracyclines. Within-day precision for the five anthracyclines were in reasonable relative standard deviations less than 3 % ($1.00{\times}10^{-6}M{\sim}1.42{\times}10^{-5}M$) except the lower concentrations less than $0.7{\mu}M$. Solid phase extractions of $1.00{\times}10^{-5}M$ epirubicin, $0.48{\times}10^{-5}M$ nogalamycin and $1.52{\times}10^{-5}M$ daunorubicin from human serum with a $C_{18}$ cartridge resulted in 97 %, 100 % and 90 % of recoveries, respectively.

STudies on the Cellulolytic Enzymes of Stachybotrys atra (Stachybotrys atra에서 추출한 섬유소분해효소에 관한 연구 II)

  • 김영민;김은수
    • Korean Journal of Microbiology
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    • v.14 no.3
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    • pp.117-127
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    • 1976
  • A cellulase fraction (F IV-1) purified to about 8-folds was obtained from crude cellulase prepared from the wheat bran culture of S.atra. The partial purification of the enzyme was made by DEAE Sephadex and Sephdex cloumn chromatography in conjuction with ammonium sulfate precipitation. After stading at various pH's for 22 hours at $20^{\circ}C$, F IV-1 was most stable at pH 5.0 but when the enzyme fraction was stood for 74 hours, the point of pH stability was raised to around pH 6.0-7.0. After heating at various temperatures for 1 hour, F IV-1 was most stable at $20^{\circ}C$. The optimal enzyme activities of F IV-1 were seen at pH 6.0 and $50^{\circ}C$. The optimal concentrations of $Zn^{++}\;and\;Ca^{++}$ for the activities of crude cellulase were 6 and 4 mM respectively, but $Ca^{++}$ inhibited the enzyme activity at concentrations below 2 mM and above 6mM. Both $Cu^{++}\;and\;Mn^{++}$ ions inhibited cellulase activities and a ocmplete inactivation of crude cellulase was achieved at concentratioins of 5 and 2 mM of ions respectively. When Na-CMC was used as substrate, the Km values of crude cellulase and F IV-1 were calculated to be $5{\times}10^{-4}\;and\;2{\times}10^{-5}mM$, and V values 32 and 1.35 mmoles/hour, respectively. The Ki values of $Mn^{++}$ for crude cellulase and F IV-1 were found to be $8{\times}10^{-2}\;and\;3{\times}10^{-2}\;mM\;while\;those\;of\;Cu^{++}\;were\;at\;2{\times}10^{-1}\;and\;1{\times}10^{-1}\;mM\;respectively.\;Both\;Mn^{++}\;and\;Cu^{++}$ showed competitive inhibition with substrate.

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Thin Film Energy Storage Device with Spray-Coated Sliver Paste Current Collector

  • Yoon, Seong Man;Jang, Yunseok;Jo, Jeongdai;Go, Jeung Sang
    • ETRI Journal
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    • v.39 no.6
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    • pp.874-879
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    • 2017
  • This paper challenges the fabrication of a thin film energy storage device on a flexible polymer substrate specifically by replacing most commonly used metal foil current collectors with coated current collectors. Mass-manufacturable spray-coating technology enables the fabrication of two different half-cell electric double layer capacitors (EDLC) with a spray-coated silver paste current collector and a Ni foil current collector. The larger specific capacitances of the half-cell EDLC with the spray-coated silver current collector are obtained as 103.86 F/g and 76.8 F/g for scan rates of 10 mV/s and 500 mV/s, respectively. Further, even though the half-cell EDLC with the spray-coated current collector is heavier than that with the Ni foil current collector, smaller Warburg impedance and contact resistance are characterized from Nyquist plots. For the applied voltages ranging from -0.5 V to 0.5 V, the spray-coated thin film energy storage device exhibits a better performance.

1V 2.56-GS/s 6-bit Flash ADC with Clock Calibration Circuit (클록 보정회로를 가진 1V 2.56-GS/s 6-bit Flash ADC)

  • Kim, Sang-Hun;Lee, Han-Yeol;Jang, Young-Chan
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.10a
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    • pp.436-439
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    • 2011
  • 본 논문은 클록 보정회로를 가진 1V 2.56-GS/s 6-bit flash analog-to-digital converter (ADC) 제안한다. 제안하는 ADC 구조에서 아날로그 블록은 단일 T/H와 2단의 프리앰프, 그리고 비교기를 사용된다. 2단의 프리앰프와 비교기의 출력에 옵셋의 크기를 줄이기 위하여 저항 평균화 기법을 적용하였다. 디지털 블록은 quasi-gray rom base 구조를 사용한다. 3입력 voting 회로로 flash ADC에서 발생하기 쉬운 bubble error를 제거하였으며, 고속 동작을 위해 단일 클록을 사용하는 TSPC F/F로 구현한다. 제안하는 flash ADC는 클록 듀티 비를 조절할 수 있는 클록 보정회로를 사용한다. 클록 보정 회로는 비교기 클록 듀티 비를 조절하여 리셋 시간과 evaluation 시간의 비율을 최적화함으로 dynamic 특성을 확보한다. 제안한 flash ADC는 1V 90nm의 CMOS 공정에서 설계되었다. Full power bandwidth인 1.2 GHz 입력에 대하여 ADC 성능을 시뮬레이션을 통해 확인하였다. 설계된 flash ADC의 면적과 전력소모는 각각 $800{\times}400\;{\mu}m^2$와 193.02mW 이다.

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Metal Vapor Laser Research II. (금속증기레이저 연구 II)

  • 이재경;정환재;임기건;이형종;정창섭;김진승
    • Korean Journal of Optics and Photonics
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    • v.3 no.3
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    • pp.178-182
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    • 1992
  • An air-cooled discharge-heated copper-vapor laser system with its inter-electrode distance of 45 cm has been developed by utilizing an alumina ceramic plasma tube of 1.6 cm in diameter and 50 cm in lengih. For operating the laser, a dc high voltage power supply with output rating of 6 kV and 500 mA, a resonant charging circuitry consisting partly of an 1.8 H inductor assembly and a 5 nF storage capacitor, and a thyratron driver operating up to 7 kHz have also been developed. The present laser system starts lasing at the tube temperature of about $1350^{\circ}C$ and an maximum average output power of 0.7 W has been obtained at 12 kV, 4.5 kHz. 50 mbar of Ne buffer gas pressure, and at the tube temperature of $1460^{\circ}C$.

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