• Mass Spectrometry Letters
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• v.1 no.1
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• pp.9-12
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• 2010

Trimethylboroxine (TMB) is a six-membered ring compound containing Lewis acidic boron and Lewis basic oxygen atoms that can bind halide anion and alkali metal cation, respectively. We employed Fourier transform ion cyclotron resonance spectroscopy to study the gas-phase binding of $LiBrLi^+$ and $F^-(KF)_2$ to TMB. TMB forms association complexes with both $LiBrLi^+$ and $F^-(KF)_2$ at room temperature, providing direct evidence for the ditopic binding. Interestingly, the $TMB{\cdot}F^-(KF)_2$ anion complex is formed 33 times faster than the $TMB{\cdot}Li^+BrLi$ cation complex. To gain insight into the ditopic binding of an ion pair, we examined the structures and energetics of $TMB{\cdot}Li^+$, $TMB{\cdot}F^-$, $TMB{\cdot}LiF$ (the contact ion pair), and $Li^+{\cdot}TMB{\cdot}F^-$ (the separated ion pair) using Hartree-Fock and density functional theory. Theory suggests that $F^-$ binds more strongly to TMB than $Li^+$ and the contact ion-pair binding ($TMB{\cdot}LiF$) is more stable than the separated ion-pair binding ($Li^+{\cdot}TMB{\cdot}F^-$).

• The korean journal of orthodontics
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• v.15 no.1
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• pp.55-66
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• 1985

The study was undertaken to ascertain the speech defect of patients with malocclusion, especially of openbite patients, by means of the spectral analysis method. The experimental group was composed of ten female openbite patients and their mean age was 13.8 yrs. The control group was also composed of ten female girls and their mean age was 13.7 yrs. As for the speech material, eight Korean monophthrongs and two Korean fricatives and two affricatives were used. Speeches were recorded and then analyzed by a Kay 7800 digital sonagraph. Formant frequency level or range was used as a phonemic parameter. The results were as follows: 1. Among Vowels /a:/ : $F_1,\;F_3\;and\;F_1/F_2$ showed abnormality. /o:/ and $/w:/:F_2,\;F_2-F_1\;and\;F_1/F_2$ showed abnormality. 2. Among Consonants /S/ and /h/ : The upper and lower borders of the frequency range showed abnormality. (equation omitted) : The lower border of the frequency range showed abnormality. $/C^{h}/$ : The upper and lower borders of the frequency range and concentration point showed abnormality.

• Proceedings of the KIEE Conference
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• 2000.07b
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• pp.1426-1428
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• 2000

A new block system - MAS (Moving Autoblock System) whose efficiency is higher than FAS(Fixed Autoblock System) in the loading capacity is required to accomodate the increasing transport volume. That MAS has higher efficiency has already been verified through various studies, especially in a line with different types of travelling trains. The efficiency of MAS for Korean high speed line with two different train model is analyzed by computer simulation. The results show that MAS is more efficient than FAS in the loading capacity.

• Journal of the Korea Convergence Society
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• v.13 no.3
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• pp.33-41
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• 2022

In this article, we proposed to predict natural gas (NG) leakage levels through feature selection based on a factor analysis (FA) of the integrating the Korean Meteorological Agency data and natural gas leakage data for considering complex factors. The paper has been divided into three modules. First, we filled missing data based on the linear interpolation method on the integrated data set, and selected essential features using FA with OrdinalEncoder (OE)-based normalization. The dataset is labeled by K-means clustering. The final module uses four algorithms, K-nearest neighbors (KNN), decision tree (DT), random forest (RF), Naive Bayes (NB), to predict gas leakage levels. The proposed method is evaluated by the accuracy, area under the ROC curve (AUC), and mean standard error (MSE). The test results indicate that the OrdinalEncoder-Factor analysis (OE-F)-based classification method has improved successfully. Moreover, OE-F-based KNN (OE-F-KNN) showed the best performance by giving 95.20% accuracy, an AUC of 96.13%, and an MSE of 0.031.

• Korean Journal of Social Welfare
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• v.61 no.3
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• pp.55-76
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• 2009

This study tested the psychometric properties of the Korean version of the Capacity-to-Consent Screen: K-CCS) scale. A total of 404 South Korean older adults were e Cruited using the purposive sampling method. The participants were asked to res-Cod to a structured questiConaire which included older adults' characteristics, ADLs, IADLs, cognitive impairments and creen: K-CCS) scale. A total of. Item analysis, explonalory factor analysis(EFA), and ) sfirmalory factor analysis(CFA) were cCoducted to verifK-Che psychometric properties of the Korean Version of CCS. The sample was divided into two groups: one group for EFA(n=202) alysis(Eois(r group for CFA(n=202). The totults revealeysisae. he final version of the 8-item K-CCS with two dimensions had a excellent internof. Itemstencyonofpha value=.f) alysa CFA) sfirmed the acceptaas diviof the modef.fdi(RMSEA=.057, NNFI=.f4, IFI=.f6, CFI=.f6) to twaddition, claims for the convergent and criterion-related validdiviwere demItetnaled. Ity-tnclusion, the K-CCS can be rmed for professi sams to asersioolder participants' capacity to consent to clinical or survey research.

• Analytical Science and Technology
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• v.10 no.5
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• pp.378-385
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• 1997

In order to clarify the functional role of Tyr7 in human glutathione S-transferase P1-1, we extensively investigated the effect of mutation of Tyr7 on the substrate specificity and inhibition characteristics. The mutational replacement of Tyr7 with phenylalanine lowered the specific activities with 1,2-dichloro-4-nitrobenzene and 1,2-epoxy-3-(p-nitrophenoxy) propane for GSH-conjugation reaction to 3~5% of the values for the wild-type enzyme. The pKa of the thiol group of GSH bound in Y7F was about 2.4 pK units higher than that in the wild-type enzyme. The $I_{50}$ of hematin for Y7F was similar to that for the wild-type enzyme and those of benastatin A and S-(2,4-dinitrophenyl)glutathione were only moderately decreased. These results suggest that Tyr7 is considered to be important the catalytic activities not only for GSH-chloronitrobenzene derivatives but also for GSH-epoxide conjugation reaction, rather than to binding of the substrates.

• Research in Plant Disease
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• v.18 no.4
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• pp.310-316
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• 2012

Gibberellea fujikuroi species (Gf) complex comprises at least 15 species, most of which not only causes serious plant diseases, but also produces mycotoxins including fumonisins. Here, we focused on the abilities of the field isolates belonging to the Gf complex associated with rice and corn, respectively in Korea to produce fumonisin, all of which were confirmed to carry FUM1, the polyketide synthase gene essential for fumonisin biosynthesis. A total of 88 Gf complex isolates (55 F. fujikuroi, 10 F. verticillioides, 20 F. proliferatum, 2 F. subglutinans, and 1 F. concentricum), and 4 isolates of F. commune, which is a non-member of Gf complex, were grown on rice substrate and determined for their production levels of fumonisins by a HPLC method. Most isolates of F. verticillioides and F. proliferatum, regardless of host origins, produced fumonisin $B_1$ and $B_2$ at diverse ranges of levels ($0.5-2,686.4{\mu}g/g$, and $0.7-1,497.6{\mu}g/g$, respectively). In contrast, all the isolates of F. fujikuroi and other Fusarium species examined produced no fumonisins or only trace amounts ($<10{\mu}g/g$) of fumonisins. Interestingly, the frequencies of relatively high fumonisin-producers among the F. proliferatum and F. fujikuroi isolates derived from corn were higher than those among the fungal isolates from rice. In addition, it is a first report demonstrating the ability of the FUM1-carrying F. commune isolates from rice to produce fumonisins.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.562-574
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• 2012

Simulation validation techniques which have been employed in most studies are statistical analysis, which validate a model with mean or variance of throughput and resource utilization as an evaluation object. However, these methods have not been able to ensure the reliability of individual elements of the model well. To overcome the problem, the weighted F-measure method was proposed, but this technique also had some limitations. First, it is difficult to apply the technique to complex system environment with numerous values of interarrival time because it assigns a class to an individual value of interarrival time. In addition, due to unbounded weights, the value of weighted F-measure has no lower bound, so it is difficult to determine its threshold. Therefore, this paper propose weighted F-measure technique with cluster analysis to solve these problems. The classes for the technique are defined by each cluster, which reduces considerable number of classes and enables to apply the technique to various systems. Moreover, we improved the validation technique in the way of assigning minimum bounded weights without any lack of objectivity.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.8 no.2
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• pp.76-81
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• 1983

PCM-NRZ/FM Telemetry system is constructed on the basis of RF link with FM modulatedand NRZ-L binary coded PCM data are assumed to transmit through 5th-order Bessel filter. Upon demodulated by the limiter-discriminator at the receiver, the probability of bit error, which is important for performance estimation of digital system, is analyzed against SNR. The analysis based on the following parameters, that is bit rate 140kHz, frequency of pre-modulation filter f-100kHz, maximum frequency deviation of transmitter 2f=300kHz, was performed. As a result, when the telemetry system with the parameters above is designed, the probability of bit error is obtained as 10 along with fT=0.7 and h=2, T=2.

• Horticultural Science & Technology
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• v.31 no.5
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• pp.626-632
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• 2013

In the course of a developing screening method for resistant radish to Fusarium oxysporum f. sp. raphani, we found that the fungus produces phytotoxic compound against Raphanus sativus. The culture filtrate of F. oxysporum f. sp. raphani KR1 represented the strongest phytotoxicity when the fungus was incubated in the malt extract broth with 150 rpm at $25^{\circ}C$ for 14 days. Under bioassay-guided purification, we isolated a substance from liquid culture of F. oxysporum f. sp. raphani KR1, with phytotoxic effect against R. sativus. The compound was identified as fusaric acid by mass and nuclear magnetic resonance spectral analyses. Phytotoxicity of the compound against cruciferous vegetable crops, including radish, cabbage, and broccoli, was investigated. Fusaric acid represented phytotoxicity on radish seedlings by concentration dependant manner. And the phytotoxin demonstrated strong phytotoxicity on the resistant cultivars as well as susceptible cultivars of radish to F. oxysporum f. sp. raphani. In addition, fusaric acid isolated from the fungus also showed a potent phytotoxic efficacy against non-host Brassicaceae crops of the fungus such as cabbage and broccoli. The results demonstrate that fusaric acid produced by F. oxysporum f. sp. raphani is non-host-specific toxin and for screening of resistant radish to the fungal pathogen, spore suspension of the fungus without the phytotoxin has to be used.