• Title/Summary/Keyword: Extraction solvent

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Purification and Characterization of Antibiotics KG-1167A & KG-1167B Produced by Clostridium sp. (Clostridium sp.가 생산하는 항생물질 KG-1167A와 KG-1167B의 정제 및 특성)

  • 홍수형;류재호;하지홍;박용복
    • Microbiology and Biotechnology Letters
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    • v.18 no.3
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    • pp.286-291
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    • 1990
  • The antibiotics KG-1167A and KG-1167B were isolated from the fermentation broth of the bacterial strain KH-1167, identified as Cloetridium sp. The individual antibiotics, KG-1167A & KG-1167B were separated and purified by solvent extraction followed by silica gel column chromatography. These antibiotics showed antibacterial activities against broad spectrum of gram positive and gram negative bacteria. The physico-chemical properties and UV spectra suggest that they possess aromatic moiety in their structures.

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Analysis of the Volatile Components in Red Bean (Vigna angularis)

  • Kim, Joo-Shin;Chung, Hau-Yin
    • Journal of Applied Biological Chemistry
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    • v.50 no.3
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    • pp.120-126
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    • 2007
  • Volatile components in red bean (Vigna angularis) were investigated. Extracts prepared by simultaneous steam distillation and solvent extraction were analyzed by gas chromatography/mass spectrometry. One hundred and forty-two components including alkanes/alkenes (17), aromatics (5), furans (15), miscellaneous compounds (2), other nitrogen-containing compounds (11), aldehydes (11), naphthalenes (11), alcohols (34), ketones (23), sulfur-containing compounds (5) and esters (8) were identified. Some of these components, e.g. hexanal, were known to contribute to the "beany" odor in other beans. Due to the presence of such odor, red beans may not be acceptable to some consumers.

Removal of the Bittering Substances from Brewer's yeast by Supercritical Carton Dioxide (초임계 이산화탄소를 이용만 맥주효모로부터 고미성분 제거)

  • 전병수;윤성옥;김석규;최승태
    • KSBB Journal
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    • v.17 no.1
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    • pp.68-72
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    • 2002
  • Supercritical Carbon Dioxide was evaluated and optimized for the enrichment and fractionation of the essential oil and the bitter principles of hops, both of which contribute to the flavor of beer, Selected conditions of extraction(pressure, temperature and co-solvent) influenced the composition, the olfactory results and the colour of the extract. Optimal extraction conditions were 30 min, 1800 psia and $ >45^{\circ}C $ with co-solvent. Under these conditions, yield was 65% from brewer's yeast. The bittering substances from brewer's yeasts almost were removed.

Suppression Effect in Some Solvent Extration System (특정용매 추출계의 억제효과)

  • Chin Taik Rhee;Young Sam Jung
    • Nuclear Engineering and Technology
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    • v.14 no.3
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    • pp.110-115
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    • 1982
  • The mechanism of the suppression effect of the extraction of microquantities of an element in the presence of microquantities of another element in some solvent extraction systems is considered. For the system of metal halide complex acids, it has been revealed that the principal cause of the suppression phenomenon is due to the dissociation of the compounds extracted into the organic phase. The various factors, such as relative value of distribution ratios of the individual micro and macroelements, stability of halide complex anion are discussed, and a equation relating those factors are derived.

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Overview on Ionic Liquid Application Technologies for Back-end Fuel Cycle Processes (핵주기 공정에서의 이온성 액체 활용 기술 개요)

  • Kim, Ki-Sub;Park, Byung Heung
    • Journal of Institute of Convergence Technology
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    • v.3 no.2
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    • pp.1-6
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    • 2013
  • The ionic liquids are known to potential alternative solvents capable of replacing the commercial solvents in various processes including those in nuclear fuel cycle. As to the material, a number of studies have already reviewed the interesting results and addressed the spectroscopic as well as electrochemical behaviors of metal elements included in spent nuclear fuels. It has found that the important properties of metal ions in TBP dissolved ILs have led the development of alternative technologies to traditional solvent extraction processes. On the other hand, the electrochemical deposition of metal ions in ILs have been investigated for the application of the solvents to aqueous as well as to non-aqueous processes. In this work, a review on the application of ILs in nuclear fuel cycle is briefly presented to understand the notable researches on ILs focusing on aqueous processes.

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Saikosaponin Contents and cAMP Phosphodiesterase Inhibitory Activities in Bupleuri Radix Extracts According to Extraction Conditions (추출조건에 따른 시호건근 추출액 중의 Saikosaponin함량 및 cAMP Phosphodiesterase 저해활성)

  • 김남수;박인선;강은미;박영현
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.2
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    • pp.329-334
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    • 2000
  • Two major oleananesaponins in Bupleuri radix, saikosaponin $\alpha$ and d, were extracted at various solvent compositions and leaching temperatures. Solvent composition was varied at 0 to 100%(v/v) of ethanol-water and methanol-water, whereas leaching temperature was adjusted to te range of 25~45$^{\circ}C$. The most effective extractant and leaching temperature were 70% ethanol and 45$^{\circ}C$, respectively. However, no major differences in saikosaponin content and cAMP phosphodiesterase inhibition were found at various leaching times. The cAMP phosphodiesterase inhibitions were alo the highest when 70% ethanol was used as the extractant.

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Drop formation at submerged nozzles: Comparison of aqueous dispersed and organic dispersed cases for TBP-dodecane and nitric acid system

  • Roy, Amitava;Darekar, Mayur;Singh, K.K.;Shenoy, K.T.
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.761-768
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    • 2019
  • Understanding the phenomena of formation of single drops is necessary to understand the hydrodynamics in solvent extraction equipment which are used for separation of nuclear materials. In this work, the phenomena of aqueous phase and organic phase drop formation at submerged nozzles are compared by conducting experiments with 30%TBP (v/v) in dodecane as the organic phase and nitric acid as the aqueous phase. Two different nozzles and three different nitric acid concentrations are used. For each nozzle and nitric acid concentration, velocity of the dispersed phase is varied. Drops of aqueous phase formed at downward oriented nozzles submerged in organic phase are observed to be smaller than the drops of organic phase formed at upward oriented nozzles submerged in aqueous phase. Correlations to estimate drop diameter are proposed.

Separation and purification of elements from alkaline and carbonate nuclear waste solutions

  • Alexander V. Boyarintsev ;Sergei I. Stepanov ;Galina V. Kostikova ;Valeriy I. Zhilov;Alfiya M. Safiulina ;Aslan Yu Tsivadze
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.391-407
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    • 2023
  • This article provides a survey of wet (aqueous) methods for recovery, separation, and purification of uranium from fission products in carbonate solutions during the reprocessing of spent nuclear fuel and methods for removal of radionuclides from alkaline radioactive waste. The main methods such as selective direct precipitation, ion exchange, and solvent extraction are considered. These methods were compared and evaluated for reprocessing of spent nuclear fuel in carbonate media according to novel alternative non-acidic methods and for treatment processes of alkaline radioactive waste.

Solvent Extraction Study for 4f Series Elements by bis(2-ethylhexyl) Phosphoric Acid

  • Rhee, C.T.;Cho, H.M.;Kim, S.H.
    • Nuclear Engineering and Technology
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    • v.7 no.3
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    • pp.199-206
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    • 1975
  • A solvent extraction technique, using bis (2-ethylhexyl) phosphoric acid, (HDEHP), as the extractant, was employed to examine some characteristical difference between lighter and heavier parts of 4f series. Some difference in temperature dependencies of the distribution ratios between the two groups were observed for the aqueous systems of H$_2$SO$_4$ and HCI. This experimental results were tentatively assigned as the difference in the ability of formation of inner coordination complex with HDEHP derived from the lanthanon contraction.

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Separation of Rh(III) from the Mixed Chloride Solutions Containing Pt(IV) and Pd(II) by Extraction with Alamine336

  • Sun, Panpan;Lee, Myung-Ho;Lee, Man-Seung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1945-1950
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    • 2010
  • Solvent extraction experiments of Pt(IV), Pd(II) and Rh(III) by Alamine336 were performed from the mixed chloride solutions. In the HCl concentration range from 1 to 5 M, most of Pt and Pd were extracted from the mixed solutions. However, the extraction percentage of Rh was much smaller than that of Pt and Pd. Lower concentration of Alamine336 in strong HCl solution led to higher separation factor of Rh from Pt and Pd. Adding $SnCl_2$ to the mixed solutions increased the extraction percentage of Rh, while the extraction percentage of Pt and Pd was little affected. Our results showed that selective separation of Rh or coextraction of the three platinum group metals from the mixed solution would be possible by adjusting the extraction conditions.