• Title/Summary/Keyword: Extraction efficiency

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Chemical and Absorption Characteristics of Water-soluble Organic Carbon and Humic-like Substances in Size-segregated Particles from Biomass Burning Emissions

  • Yu, Jaemyeong;Yu, Geun-Hye;Park, Seungshik;Bae, Min-Suk
    • Asian Journal of Atmospheric Environment
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    • v.11 no.2
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    • pp.96-106
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    • 2017
  • In this study, measurements of size-segregated particulate matter (PM) emitted from the combustion of rice straw, pine needles, and sesame stem were conducted in a laboratory chamber. The collected samples were used to analyze amounts of organic and elemental carbon (OC and EC), water-soluble organic carbon (WSOC), humic-like substances (HULIS), and ionic species. The light absorption properties of size-resolved water extracts were measured using ultraviolet-visible spectroscopy. A solid-phase extraction method was first used to separate the size-resolved HULIS fraction, which was then quantified by a total organic carbon analyzer. The results show that regardless of particle cut sizes, the contributions of size-resolved HULIS ($=1.94{\times}HULIS-C$) to PM size fractions ($PM_{0.32}$, $PM_{0.55}$, $PM_{1.0}$, and $PM_{1.8}$) were similar, accounting for 25.2-27.6, 15.2-22.4 and 28.2-28.7% for rice straw, pine needle, and sesame stem smoke samples, respectively. The $PM_{1.8}$ fraction revealed WSOC/OC and HULIS-C/WSOC ratios of 0.51 and 0.60, 0.44 and 0.40, and 0.50 and 0.60 for the rice straw, pine needle, and sesame stem burning emissions, respectively. Strong absorption with decreasing wavelength was found by the water extracts from size-resolved biomass burning aerosols. The absorption ${\AA}ngstr{\ddot{o}}m $ exponent values of the size-resolved water extracts fitted between 300 and 400 nm wavelengths for particle sizes of $0.32-1.0{\mu}m$ were 6.6-7.7 for the rice straw burning samples, and 7.5-8.0 for the sesame stem burning samples. The average mass absorption efficiencies of size-resolved WSOC and HULIS-C at 365 nm were 1.09 (range: 0.89-1.61) and 1.82 (range: 1.33-2.06) $m^2/g{\cdot}C$ for rice straw smoke aerosols, and 1.13 (range: 0.85-1.52) and 1.83 (range: 1.44-2.05) $m^2/g{\cdot}C$ for sesame stem smoke aerosols, respectively. The light absorption of size-resolved water extracts measured at 365 nm showed strong correlations with WSOC and HULIS-C concentrations ($R^2=0.89-0.93$), indicating significant contribution of HULIS component from biomass burning emissions to the light absorption of ambient aerosols.

Evaluation of the Feasibility of Oyster-Shell and Eggshell Wastes for Stabilization of Arsenic-Contaminated Soil (농축수산 폐기물(굴껍질 및 달걀껍질)을 이용한 비소 오염토양의 안정화 효율 평가)

  • Lim, Jung-Eun;Moon, Deok-Hyun;Kim, Dong-Jin;Kwon, Oh-Kyung;Yang, Jae-E.;Ok, Yong-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1095-1104
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    • 2009
  • The objective of this research was to evaluate the feasibility of using oyster-shell and eggshell wastes for the stabilization of arsenic-contaminated soil. Artificial As(V) contaminated soil was mixed with 0~5% oyster-shell and eggshell wastes and each sample was incubated for 30 days in a controlled environment. The efficiency of each treatment was evaluated using various single extractants (1 N HCl, 0.1 N NaOH and 0.5 N $H_2SO_4$). The concentration of As(V) was reduced by 10% upon a 5% oyster-shell or eggshell waste treatments based on the Korea Standard Test method (1 N HCl extraction). Analogous trends were observed in the 0.1 N NaOH or 0.5 N $H_2SO_4$ extractions. In addition, the oyster-shell and eggshell waste treatments increased the pH of each soil from 6.54 (Control) to 7.62~7.94. The exchangeable Ca in each soil also sharply increased from 6.87 cmol(+)/kg (Control) to 12.77~20.18 cmol(+)/kg. Further research is needed to increase the effectiveness of the oyster-shell and eggshell waste for the stabilization of As(V) in the contaminated soil.

Development of Protocol for the Effective Detection of Feline Calicivirus as Norovirus Surrogate in Oyster and Lettuce (굴과 상추에서 노로바이러스의 대체모델 feline calicivirus의 효율적 검출법 개발)

  • Lee, Soo-Yeon;Jang, Keum-Il;Woo, Gun-Jo;Kwak, Hyo-Sun;Kim, Kwang-Yup
    • Korean Journal of Food Science and Technology
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    • v.39 no.1
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    • pp.71-76
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    • 2007
  • Foodborne illness caused by Noroviruses (NVs) is increasing rapidly in Korea. This study developed an effective detection protocol for NVs found in contaminated oysters and lettuce through an investigation using the major steps of virus particle separation, concentration and RT-PCR. As a surrogate model for NVs, the cultivable feline calicivirus (FCV) that belongs to the same Caliciviridae family was used. Instead of using a time-consuming ultracentrifugation method, efficient methods based on solvent extraction and PEG precipitation procedure were applied. Direct homogenization of a 25g sample of whole oyster and lettuce in 175mL PBS provided the simplicity that would be needed in the actual field of food product examination. The overnight PEG precipitation step at $4^{\circ}C$ was reduced to 3 h by placing the reaction tube in ice and by adjusting the PEG concentrations. The application of the use of chloroform and 0.2 ${\mu}m$ syringe filtration together showed a better detection efficiency than the use of chloroform alone in removing PCR inhibitors for both oyster and lettuce samples. Also, dilution of the extracted RNA solution before PCR provided increased sensitivity. The improved detection protocol developed in this study could be efficiently applied to detect FCV and most likely NVs from oysters and lettuce.

A Study on the Optimal Phosphorus Recovery Conditions from Sewage Sludge Ash by pH Control and Reuse of Extracts (하수슬러지 소각재 추출액의 pH 조절 및 재사용에 따른 최적의 인(P) 회수 조건 산정 연구)

  • Liu, Qi;Lim, Sung Hyun;Yoon, Seok-Pyo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.3
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    • pp.15-26
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    • 2020
  • To recover phosphorus from incinerated sewage sludge ash(ISSA), ISSA were extracted with sulfuric acid solution, and the optimal phosphorus recovery conditions were experimented by comparing the recovered phosphorus contents and heavy metals by raising pH. Also the phosphorus recovery efficiency was compared when acid extract was reused or classified by particle size of ISSA. The optimal conditions for recovering phosphorus from ISSA were 1N sulfuric acid solution with an L/S ratio of 10, and an extraction time of 30 minutes. Considering the addition of alkali substances and the content of heavy metals in the recovered sediment, it is concluded to recover phosphorus under pH 5. Reuse of the ISSA extract increased the recovery rate of phosphorus by 14~21% depending on the reuse rate (100 and 50%), but it also increased zinc contents to 33 and 21%, and copper contents to 35 and 20%, respectively. The experiment of ISSA divided into four sections by particle size showed that there was no distinct advantage of phosphorous recovery by classification of certain particle size of ISSA. The removal of heavy metals from extracts through EDTA and cation exchange resin showed no definite effect.

Improvement of Review System on Sea Area Utilization-Impact by Marine Environmental Management Law (해양환경관리법상 해역이용영향 검토기관의 발전방향)

  • Lee, Dae-In;Eom, Ki-Hyuk;Kim, Gui-Young;Jang, Ju-Hyoung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.1
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    • pp.55-62
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    • 2008
  • This study investigated the status and problems of marine-related environmental impact assessment and a utilization-consultation system in Korea and suggested improvement of the review organization. Also, it conducted SWOT analysis based on evaluation of functions, roles and performance of the marine environmental impact assessment center and proposed development strategies of the center through introduction of expert opinions and advanced systems. The performance statement-review by the center in 2007 included 358 cases in total; 165 (46.1%) for consultation on utilization of sea area, 104 for environmental impact assessment (29.0%), and 89 (24.9%) for prior environmental review. The consultation on utilization of sea area can be divided into that for public water surface-use (41%) and reclamation (32%), and sea aggregate extraction process (21%). Although bad impacts on marine environment are reducing under the current system, there are some limits and problems to supplement it in terms of content, system and operation. Review system on sea area utilization-impact(marine environmental impact assessment center) by marine environmental management law needs to obtain expertise, fairness and efficiency and, to do so, have operational supports and institutional improvement to maximize its own functions and roles. At the same time, it is necessary for the center to establish identity and the status as a professional review organization by setting active development strategies inside the center. Finally, it should strengthen an consultation system of marine environmental impact assessment led by the related ministry to achieve effective coastal management.

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A Study on ACFBD-MPC in 8kbps (8kbps에 있어서 ACFBD-MPC에 관한 연구)

  • Lee, See-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.7
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    • pp.49-53
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    • 2016
  • Recently, the use of signal compression methods to improve the efficiency of wireless networks have increased. In particular, the MPC system was used in the pitch extraction method and the excitation source of voiced and unvoiced to reduce the bit rate. In general, the MPC system using an excitation source of voiced and unvoiced would result in a distortion of the synthesis speech waveform in the case of voiced and unvoiced consonants in a frame. This is caused by normalization of the synthesis speech waveform in the process of restoring the multi-pulses of the representation segment. This paper presents an ACFBD-MPC (Amplitude Compensation Frequency Band Division-Multi Pulse Coding) using amplitude compensation in a multi-pulses each pitch interval and specific frequency to reduce the distortion of the synthesis speech waveform. The experiments were performed with 16 sentences of male and female voices. The voice signal was A/D converted to 10kHz 12bit. In addition, the ACFBD-MPC system was realized and the SNR of the ACFBD-MPC estimated in the coding condition of 8kbps. As a result, the SNR of ACFBD-MPC was 13.6dB for the female voice and 14.2dB for the male voice. The ACFBD-MPC improved the male and female voice by 1 dB and 0.9 dB, respectively, compared to the traditional MPC. This method is expected to be used for cellular telephones and smartphones using the excitation source with a low bit rate.

Functional Cosmetic Effect of Porcine Placeta (Porcine Placenta의 기능성 화장품소재 특성)

  • Kim, Bo Young;Kim, Tagon;Kang, Whan Yul;Baek, Hyun;Cheon, Hae Young;Kim, Donguk
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.327-331
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    • 2010
  • Porcine placenta was treated with alkali, acid and enzyme treatment to obtain extracts. Heavy metal contents such as Pb, As, and Hg were low enough to satisfy cosmetic agent standard. As a result of safety test(MTT assay), porcine placenta extracts showed over 80% of cell viability at $50{\mu}g/ml$, and cell toxicity was relatively lower. From antioxidation test using DPPH free radical scavenging assay, antioxidation effect was highest as 63% at $50{\mu}g/ml$ when porcine placenta was treated with alkali in pH 9. From whitening effect test using tyrosinase inhibition assay, tyrosinase inhibition effect was 30% at $50{\mu}g/ml$ concentration in alkali treated procine placenta, however, the efficiency was lower compared with arbutin or vitamin C. In anti-wrinkle effect test from elastase inhibition assay, elastase inhibition effects were 20~30% at $50{\mu}g/ml$ for 5 kinds of porcine placenta treatments, which was superior to standard, and especially, protease treated extracts showed best results. Skin formulation including 1% porcine placenta was made and the formulation was very stable for temperature and storage period. From this research, porcine placenta extract showed high potential for anti-wrinkle functional cosmetic agent.

Development of Machine Learning-Based Platform for Distillation Column (증류탑을 위한 머신러닝 기반 플랫폼 개발)

  • Oh, Kwang Cheol;Kwon, Hyukwon;Roh, Jiwon;Choi, Yeongryeol;Park, Hyundo;Cho, Hyungtae;Kim, Junghwan
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.565-572
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    • 2020
  • This study developed a software platform using machine learning of artificial intelligence to optimize the distillation column system. The distillation column is representative and core process in the petrochemical industry. Process stabilization is difficult due to various operating conditions and continuous process characteristics, and differences in process efficiency occur depending on operator skill. The process control based on the theoretical simulation was used to overcome this problem, but it has a limitation which it can't apply to complex processes and real-time systems. This study aims to develop an empirical simulation model based on machine learning and to suggest an optimal process operation method. The development of empirical simulations involves collecting big data from the actual process, feature extraction through data mining, and representative algorithm for the chemical process. Finally, the platform for the distillation column was developed with verification through a developed model and field tests. Through the developed platform, it is possible to predict the operating parameters and provided optimal operating conditions to achieve efficient process control. This study is the basic study applying the artificial intelligence machine learning technique for the chemical process. After application on a wide variety of processes and it can be utilized to the cornerstone of the smart factory of the industry 4.0.

Growth of $ZnGa_2O_4:Mn^{2+}$ Thin Film Phosphors by RF Magnetron Sputtering (박막 형광체 $ZnGa_2O_4:Mn^{2+}$의 RF Magnetron Sputtering법을 이용한 생장)

  • Kim J.S.;Lee S.H.;Park J.H.;Park H.W.;Choi J.C.;Park H.L.
    • Journal of the Korean Vacuum Society
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    • v.15 no.4
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    • pp.404-409
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    • 2006
  • Thin-film $ZnGa_2O_4 : Mn^{2+}$ phosphors of spinel structure were grown on quartz substrate by RF magnetron sputtering method at room temperature. As an increase of post-annealing temperatures, crystallinity, surface roughness and stoichiometry of thin films were varied. At the post-annealing temperatures of $500^{\circ}C$ and $600^{\circ}C$, the luminescence intensity was poor due to the poor crystallinity. The smallest surface roughness was observed at the sample post-annealed at $700^{\circ}C$ leading to low external extraction efficiency, and poor luminescence intensity. The highest luminescence intensity was shown at the sample post-annealed at $800^{\circ}C$. It was because both the surface roughness and crystallnity were optimized. On the other hand, at $900^{\circ}C$, the luminescence intensity was poor due to the violation of stoichiometry.

Application of the Developed Pre- and Post-Processing System to Yongdamdam Watershed using PRMS Hydrological Model (수문학적 유역특성자료 자동화 추출 및 분석시스템 적용 (II) -PRMS 모형을 이용한 용담댐 유역을 대상으로-)

  • Kwon, Hyung-Joong;Hwang, Eui-Ho;Lee, Geun-Sang;Yu, Byeong-Hyeok;Koh, Deuk-Koo
    • Journal of the Korean Association of Geographic Information Studies
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    • v.11 no.3
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    • pp.13-22
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    • 2008
  • The objective of this study is to evaluate the applicability of extracted PRMS input parameters by KGIS-Hydrology over Yongdam-Dam watershed. KGIS-Hydrology is a system for automatic extraction and analysis of watershed characteristic data. Input parameters of PRMS were generated from GIS data (DEM, soil, forest type, etc.) using KGIS-Hydrology. Multi-temporal meteorological data from Jangsu station of KMA (Korea Meteorological Administration) were used for all simulation periods. Input parameters of PRMS were optimized using observed runoff data of Yongdam-Dam station (1966-2001) and validated using observed runoff data of Yongdam-Dam station (2002-2006, Yongdam-Dam watershed). The results showed that the simulated flows were much closed to the observed flows of Yongdam-Dam (2002-2006) and Donghyang (2001-2004) station by 0.49~0.83 and 0.57~0.75 model efficiencies, respectively.

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