• Title/Summary/Keyword: Extraction constant

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Extraction of Soybean Oil Using Supercritical Carbon Dioxide and Its Characteristics (초임계 탄산가스를 이용한 대두유의 추출과 추출대두유의 성질)

  • Kim, In-Hwan;Yoon, Suk-Hoo
    • Korean Journal of Food Science and Technology
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    • v.23 no.6
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    • pp.677-682
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    • 1991
  • Extraction of soybean oil from full tat soybean flour was performed using a supercritical carbon dioxide extraction system. Extraction pressure and temperature of the process were 3,000-7,000 psig and $40-70^{\circ}C$, repectively. For the extraction of lg of soybean oil, 25l of carbon was consumed at 7,000 psig and $60^{\circ}C$, whereas more than 2501 of carbon dioxide was consumed at 3,000 psig and $60^{\circ}C$. The solubility of soybean oil in supercritical carbon dioxide decreased with the increase in temperature below 6,000 psig, and the reverse trend was observed above 6,000 psig. At 6,000 psig the solubilities were shown to be, constant regardless of extraction temperature. Soybean oils , extracted with supercritical carbon dioxide were lighter in color and contained less phosphorus than those extracted with hexane.

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A Study on Solvent Extraction of Metal by Salicylaldoxime (Salicylaldoxime에 의한 금속 추출에 관한 연구)

  • Shin, Jeong-Ho;Park, Sang-Wook;Park, Dae-Won;Lee, Kyung-Soo;Jeong, Kap-Seop
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.46-53
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    • 1993
  • The kinetic and equilibrium characteristics of copper extraction by salicylaldoxime in chloroform and benzene were investigated. Equilibrium constants such as dissociation constant, distribution coefficient of salicylaldoxime and stability constant, distribution coefficient and molar extinction coefficient of oxime-Cu chelate were determined from absorbance. Extracted species of Cu-chelate were found to be ${\bar{CuR_2}}$. Overall initial extraction rate of copper by salicylaldoxime in chloroform was expressed by the following equation : $R=k[Cu^{2+}]{\bar{[HR]}}^{0.5}/[H^+]^{0.4}$.

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Zirconium Titanate Thin FIlm Prepared by Surface Sol-Gel Process and Effects of Thickness on Dielectric Property

  • Kim, Chy-Hyung;Lee, Moon-Hee
    • Bulletin of the Korean Chemical Society
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    • v.23 no.5
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    • pp.741-744
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    • 2002
  • Single phase of multicomponent oxide ZrTiO4 film could be prepared through surface sol-gel route simply by coating the mixture of 100 mM zirconium butoxide and titanium butoxide on $Pt/Ti/SiO_2Si(100)$ substrate, following pyro lysis at $450^{\circ}C$, and annealing it at 770 $^{\circ}C.$ The dielectric constant of the film was reduced as the film thickness decreased due to of the interfacial effects caused by layer/electrode and a few voids inside the multilayer. However, the dielectric property was independent of applied dc bias sweeps voltage (-2 to +2 V).The dielectric constant of bulk film, 31.9, estimated using series-connected capacitor model was independent of film thickness and frequency in the measurement range, but theoretical interfacial thickness, ti, was dependent on the frequency. It reached a saturated ti value, $6.9{\AA}$, at high frequency by extraction of some capacitance component formed at low frequency range. The dielectric constant of bulk ZrTiO4 pellet-shaped material was 33.7 and very stable with frequency promising as good applicable devices.

Extraction Equilibria and Analytical Application of Metal-Dithizone Complexes(II) Partition and Extraction Equilibria into Chloroform (디티존 금속착물의 용매추출평형과 분석적 응용(제2보) 클로로포름 용매에 대한 분배 및 추출평형)

  • Choi, Yoon-Seok;Choi, Hee-Seon;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.10 no.5
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    • pp.370-377
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    • 1997
  • The several fundamental parameters on the solvent extraction of Co(II), Cu(II) and Zn(II) with dithizone were investigated. The value of $K_{a1}/K_p$ of dithizone(at $25^{\circ}C$) between an aqueous phase and a chloroform was found to be $4.72{\times}10^{-11}$. And the mole ratios of metal ion to dithizone in its metal complexes were determined by mole ratio method. The extractibilities(%) for metal-dithizone chelates were obtained from the extraction equilibria of metal-dithizone complexes between an aqueous phase and a chloroform as follows. Co(II) : 92.3% at pH 8.0 : Cu(II) : 97.1% at pH 4.0 and Zn(II) : 99.0% at pH 7.0. And also, in optimum experimental conditions the extraction constants of Co(II), Cu(II) and Zn(II) were examined.

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Influence Factor on Remediation of PAHs-Contaminated Soil by Using Flowing Subcritical Water (흐름식 아임계수를 이용한 PAHs 오염토양 정화 영향인자)

  • Jo, Young-Tae;Islam, Mohammad Nazrul;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.18 no.4
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    • pp.1-7
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    • 2013
  • Subcritical water which acts as organic solvent with increasing temperature and pressure because dielectric constant and viscosity decrease can be used to remediate PAHs-contaminated soil. Factors influencing on extraction were studied with varying the water temperature $200{\sim}275^{\circ}C$, extraction time 0~90 min, flow rate 10~100 mL/min and pressure 3.9~10MPa. 300 g of soil sample which was contaminated with PAHs(naphthalene, phenanthrene, fluoranthene and pyrene; 423, 420, 539 and 428 mg/kg of initial concentration) was packed into the cell and placed to reactor and then the subcritical water was pumped through the cell for PAHs extraction. Naphthalene was removed almost 100% at relatively low temperature ($200^{\circ}C$). The removal rate of phenanthrene, fluoranthene, and pyrene increased by 8, 26, and 23% when the temperature increased from 200 to $275^{\circ}C$; and it was gradually increased as extraction time increased from 0 to 90 min. Decreasing removal rate when water flow rate increased from 10 to 30 mL/min, but there was no significant change after 30 mL/min. This is supposed due to channeling phenomenon. The pressure was not an effective factor for extraction of PAHs in this study. Based on the results, the importance of effective factor was in following sequence: temperature >> time > flow rate.

High Durability of Stack for Automobile (차량용 스택 고출력 내구성능)

  • Kim, Young-Min;Lee, Jong-Hyun;Yoon, Jong-Jin;Cho, Jang-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.557-560
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    • 2007
  • The durability of 80 kW class stack module was tested in hydrogen recirculation and non-recirculation systems with the condition of 300Amps (constant current mode) and hydrogen pulse purging (10 seconds close/0.8 seconds open). A localized membrane failure in the interfacial area between membrane and sub-gasket, carbon corrosion in cathode electrode, and Pt dissolution/extraction have been found through the post mortem analysis such as CV, Impedance, SEM, and so on. The main reason of these mechanisms will be discussed in this study.

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An approach to visual pattern recognition by neural network system

  • Hatakeyama, Yasuhiro;Kakazu, Yukinori
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10b
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    • pp.61-64
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    • 1992
  • In this paper, a visual pattern recognition system is proposed, which can recognize both a pattern and its location. This system, referred to as the expanded neocognitron, has the following capabilities: (1) A higher performance in extraction of features, and (2) A new capability for recognizing the locations of patterns. This system adopts the learning and recognizing mechanism of the neocognitron. First, the ability to classify pattern is enhanced by improving the mechanisms of feature extraction and learning algorithm. Second, the function of detecting the location of each pattern is realized by developing an architecture which does not reduce structure, i.e., the unit density is constant all the way from the input stage to the output stage.

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Dynamic coefficients of A High-Speed Rotor Supported by A Slotted ER Squeeze Film Damper (ER 스퀴즈 필름 댐퍼로 지지된 고속 회전 로터의 동적 계수에 관한 연구)

  • Lee, Yong-Bok;Kim, Chang-Ho;Seok, Ki-Young;Lee, Nam-Soo;Choi, Dong-Hoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1286-1291
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    • 2000
  • A new electro-rheological squeeze film damper (ER SFD) has been sealed with slotted piston rings which have electrodes at the inside of the constant gap. The slotted ER SFD can prevent the problem of electric discharge which might be occurred in the previous configuration of an ER SFD. The current paper presents the extraction of linearized dynamic coefficients within small orbit where these coefficients are controlled by the application of electric strength. Test rig has been modified to isolate the damper section for dynamic coefficient extraction. The results show that rotordynamic coefficients, damping and inertia terms, increase with increasing supply voltages, while stiffness coefficients decrease with increasing supply voltages. Rotating speed of rigid Shaft does not affect these coefficients.

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Dynamic Coefficients of a High-Speed Rotor Supported by a Slotted ER Squeeze Film Damper (ER 스퀴즈 필름 댐퍼로 지지된 고속 회전 로터의 동적 계수에 관한 연구)

  • 이용복;김창호;정시영;이남수;최동훈
    • Journal of KSNVE
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    • v.10 no.6
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    • pp.1029-1034
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    • 2000
  • A new electro-rheological squeeze film damper (ER-SFD) has been sealed with slotted piston rings which have electrodes at the inside of the constant gap. The slotted ER-SFD can prevent the problem of electric discharge which might be occurred in the previous configuration of an ER-SFD. The current paper presents the extraction of linearized dynamic coefficients within small orbit where these coefficients are controlled by the application of electric strength. Test rig has been modified to isolate the damper section for dynamic coefficient extraction. The results show that rotordynamic coefficients, damping and inertia terms, increase with increasing supply voltages, while stiffness coefficients decrease with increasing supply voltages. notating speed of rigid shaft does not affect these coefficients.

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The Activity Coefficients of Tri-n-butylphosphate and Europium Complex in the Extraction of Europium by Tri-n-butylphosphate in Nitric Acid Solution (질산유로퓸을 TBP 로 추출할때 TBP와 유로퓸착물의 활동도계수간의 관계)

  • Gang, Ik Gyun
    • Journal of the Korean Chemical Society
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    • v.18 no.4
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    • pp.272-277
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    • 1974
  • A relationship between the activity coefficients of tri-n-butylphosphate(TBP) and europium complex was studied in the extraction of europium by TBP in nitric acid solution. Diluents chosen are cyclohexane, toluene, benzene and chlorobenzene. Concentrations of TBP were varied from 5 to 50 by volume percent and the composition of inorganic layer was kept constant. A method of estimating the solubility parameter of TBP is suggested.

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