• Computers and Concrete
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• v.16 no.6
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• pp.847-864
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• 2015

This study aimed to develop models of sulfate diffusion and ettringite content profile in cement paste for the predication of the damage behavior in cement paste subject to external sulfate. In the models, multiphase reaction equilibrium between ions in pore solution and solid calcium aluminates phases and the microstructure changes in different positions of cement paste were taken into account. The distributions of expansive volume strain and expansion stress in cement paste were calculated based on the ettringite content profile model. In addition, more sulfate diffusion tests and SEM analyses were determined to verify the reliability and veracity of the models. As the results shown, there was a good correlation between the numerical simulation results and experimental evidences. The results indicated that the water to cement ratio (w/c) had a significant influence on the diffusion of sulfate ions, ettringite concentration profile and expansion properties in cement paste specimens. The cracking points caused by ettringite growth in cement paste specimens were predicted through numerical methods. According to the simulation results, the fracture of cement paste would be accelerated when the specimens were prepared with higher w/c or when they were exposed to sulfate solution with higher concentration.

• Geomechanics and Engineering
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• v.38 no.4
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• pp.353-366
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• 2024

Organic soils pose significant challenges in geotechnical engineering due to their high compressibility and low stability, which can result in issues like differential settlement, rutting, and pavement deformation. This study explores effective methods for stabilizing organic soils. Rather than conventional ordinary Portland cement (OPC), the focus is on using environmentally friendly calcium sulfoaluminate (CSA) cement, known for its rapid setting, high early strength development, and environmental benefits. Mechanical behavior is analyzed through 1-D free swell, unconfined compressive strength (UCS), and bender element (BE) tests. Microstructural analyses, including Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), characterize the soil mixed with CSA cement. Experimental results demonstrate improved soil properties with increasing cement dosage and curing periods. A notable strength increase is observed in soil samples with 15% cement content, with UCS doubling after 7 days. This trend aligns with shear wave velocity results from the BE test. SEM and FTIR spectroscopy reveal how CSA cement hydration forms hydrated calcium silicate gel and ettringite, enhancing soil properties. CSA cement is recommended for reinforcing organic subgrade soil due to its eco-friendly nature and rapid strength gain, contributing to improved durability.

• Journal of the Korean Ceramic Society
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• v.27 no.5
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• pp.589-596
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• 1990

In this study, the freezing and thawing resistance in sea-water of hardened cement paste was investigated by adding slag, diatomaceous earth and fly ash as blending materials and air entraining agent and superplasticizer as admixtures to the cement paste. The structure of hardened cement pate was densified by potential hydraulic properties and pozzolan reactivities of materials and the freezing and thawing resistance of the paste was improved with the effect blending materials and admixtures. As the blending materials were added to the paste, the quantity of C3A was relatively reduced and the formation of expansive ettringite was suppressed to decrease the penetration of sea-water or Cl-, SO42-ion, and then freeze-thaw resistance was enhanced. Particulary, when 40% of slag was mixed, the resistance was excellent.

• Journal of the Korea Concrete Institute
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• v.13 no.4
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• pp.314-320
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• 2001

In this paper, the properties of an expansive agent (CaO-CaS $O_4$) for dry shrinkage compensation were investigated by a series of experimental program, which might be used at On-Dol heating system as mortar type. The expansion principle of the CaO-CaS $O_4$ was mainly verified. As a result of this study, the correlation between the content of the expansive agent and the compressive strength was obtained in the form of exponential function(Y = A $e^{-x}$), showing that as the content of expansive agent increased as the expansion performance with the compressive strength increased by only a certain amount. Also, as a results of the analysis of a correlation between the expansive performance and the chemical properties which generally accompanied a part of quality management in manufacturing the expensive cement, the expansive performance was relative to only the contents of the F-CaO among chemical properties(Blaine, +44$\mu\textrm{m}$R, F-CaO, S $O_3$,L.O.I). And it was clarified that the results were relative to the second order function, showing that if the contents of the F-CaO increased the expansive performance Increased.d.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.139-144
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• 1998

This study is intended to devolop the self waterproof agents for high performance concrete by analyzing the properties of fresh and hardened mortar with various addition ratios of the inorganic admixture and zinc stearate. As the results of the test, the flow and air content increase with the addition of expansive additives. When the replacement rate of silica fume increases, the flow decreases for the increased viscidity. And the flow and sir content decrease with the addition of zinc stearate. At hardened state, the compressive strength, tensile strength and flexual strength decrease with the addition of expansive additives and zinc stearate. With the increase of silica fume's replacement, they show a little decrease at early age and then increase gradually. Also, absorption and permeability show a steep decrease when zinc stearate is added, and a slack decrease with the replacement of silica fume.

• Journal of the Korean Ceramic Society
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• v.38 no.2
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• pp.183-192
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• 2001

산업부산물을 이용하여 3CaO.3Al$_2$O$_3$.CaSO$_4$(C$_4$A$_3$S) 클링커를 합성하였다. 이때, 원료 물질은 산업부산물로 플라이 애쉬, 고로 수쇄 및 괴재슬래그를 $Al_2$O$_3$원으로 그리고 부산석고를 SO$_3$원으로 이용하였으며, CaO원으로 천연석회석을 사용하였다. 제조된 $C_4$A$_3$S 클링커를 CaSO$_4$, CaO를 배합하여 CSA계 팽창재를 제조하였으며, 일반 포틀랜드 시멘트(OPC)에 10 wt.% 첨가하여 수화 및 물성 특성을 조사하였다. 주요 수화생성상은 에트링자이트 및 수산화칼슘이었다. 수화시 에트링자이트의 생성으로 인해 팽창 및 경화체가 치밀화되어 건조수축이 감소되었고, 강도(압출, 인장, 휨)가 향상되었다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.67-70
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• 2005

Ultra high strength concrete, nowadays, has been widely applied to construction of high-rise building. To improve ductility and mechanical properties, steel fiber is employed in UHSC. This study investigates practical application of expansive additives(EA) and shrinkage reducing agent(SRA), in order to secure volumetric stability and improved mechanical properties, such as autogenous shrinkage and dry shrinkage of steel-fiber-reinforced-ultra-high-strength-comet-mortar(FHSM). According to the test, individual addition of steel fiber does not affect shrinkage reduction, as expected. However FHSM, with combined addition of 5$\%$ of EA and 1$\%$ of SRA decreased 60$\%$ of autogenous shrinkage. It is considered that Proper combination of EA and SRA can secure the shrinkage resistance of FHSM.

• Journal of the Korea Institute of Building Construction
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• v.3 no.4
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• pp.135-138
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• 2003

The purpose of this study was to design the self-compaction concrete mixture, having not only high strength but also compensation of shrinkage without thermal crack under 4 sides outer restraint of the member. In the experimental mix, replacement ratio of limestone Powder, CSA expansive additives, and unit water were selected as parameters, using portland blast-furnace slag cement. And, bleeding test, expansibility test, hydration heat analysis were performed. As a results, when 35% of limestone Powder, 6% CSA expansive additives are replaced at unit water 175kg/$\textrm{m}^3$, demanded performances of fresh and hardened self-compaction concrete are accomplished.

• Journal of the Korea Institute of Building Construction
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• v.4 no.1
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• pp.85-88
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• 2004

The purpose of this study was to design the self-compaction concrete mixture, having not only high strength but also compensation of shrinkage without thermal crack under 4 sides outer restraint of the member. In the experimental mix, replacement ratio of limestone Powder, CSA expansive additives, and unit water were selected as parameters, using portland blast-furnace slag cement. And, bleeding test, expansibility test. hydration heat analysis were performed. As a results, when 35% of limestone Powder, 6% CSA expansive additives are replaced at unit water 175kg/$\textrm{m}^3$, demanded performances of fresh and hardened self-compaction concrete are accomplished.

• Journal of the Korea Concrete Institute
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• v.24 no.3
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• pp.233-240
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• 2012

Hybrid SHCC is being researched actively for its excellent performance in controlling macro and micro cracks using macro and micro fibers, respectively. However, a significant autogenous shrinkage of SHCC is expected since it possesses high unit cement volume in its mix proportion, resulting in autogenous shrinkage cracks. Therefore, this study was performed to evaluate mechanical property of shrinkage-reducing type hybrid SHCC mixed together with steel fiber and PE fiber with excellent micro/macro crack controlling performance. In order to evaluate mechanical property of shrinkage-reducing type hybrid SHCC, replacement ratios of 0% and 10% of expansive admixture and water to binder ratios of 0.45, 0.3, and 0.2 were considered as variables. Then, shrinkage, compressive, flexural, and direct tensile tests were performed. The test results showed that mix proportion with W/B 0.3 significantly improved mechanical performance by using 10% replacement of expansive admixture.