• Title/Summary/Keyword: Expansion Method

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Fabrication of SiOx Anode Active Materials Using Spherical Silica Powder and Shape Control Technology (구형 단분산 실리카 분말을 이용한 SiOx 음극활물질 제조 및 형상조절 기술)

  • Ju-Chan Kwon;Bok-Hyun Oh;Sang-Jin Lee
    • Korean Journal of Materials Research
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    • v.33 no.12
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    • pp.530-536
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    • 2023
  • The theoretical capacity of silicon-based anode materials is more than 10 times higher than the capacity of graphite, so silicon can be used as an alternative to graphite anode materials. However, silicon has a much higher contraction and expansion rate due to lithiation of the anode material during the charge and discharge processes, compared to graphite anode materials, resulting in the pulverization of silicon particles during repeated charge and discharge. To compensate for the above issues, there is a growing interest in SiOx materials with a silica or carbon coating to minimize the expansion of the silicon. In this study, spherical silica (SiO2) was synthesized using TEOS as a starting material for the fabrication of such SiOx through heating in a reduction atmosphere. SiOx powder was produced by adding PVA as a carbon source and inducing the reduction of silica by the carbothermal reduction method. The ratio of TEOS to distilled water, the stirring time, and the amount of PVA added were adjusted to induce size and morphology, resulting in uniform nanosized spherical silica particles. For the reduction of the spherical monodisperse silica particles, a nitrogen gas atmosphere mixed with 5 % hydrogen was applied, and oxygen atoms in the silica were selectively removed by the carbothermal reduction method. The produced SiOx powder was characterized by FE-SEM to examine the morphology and size changes of the particles, and XPS and FT-IR were used to examine the x value (O/Si ratio) of the synthesized SiOx.

Utilization of Immersion-Drying Method for Measuring Damage Depth of Fire-Damaged High-Strength Concrete (화재로 손상된 고강도 콘크리트의 손상 깊이 측정을 위한 수중침지 건조방법의 활용)

  • Kim, Jong;Lim Gun-Su;Beak, Seung-Bok;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.3
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    • pp.297-308
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    • 2024
  • This study presents a novel approach for evaluating fire-induced damage depth in concrete. The methodology leverages the principle that exposure to high temperatures causes internal expansion within concrete, leading to increased voids and microcracks in the damaged zones. This heightened porosity results in greater absorption rates compared to undamaged areas. By immersing fire-damaged concrete samples in water and subsequently monitoring the drying process, the depth of damage can be assessed. Differences in drying rates and color variations between damaged and undamaged areas serve as visual indicators for determining the extent of the damage. Experimental results from this water immersion method revealed damage depths of 38.7mm and 37.5mm for two different concrete mixtures. These measurements notably surpass the damage depths estimated using traditional phenolphthalein-based methods. This discrepancy suggests that utilizing the absorption rate principle, which is directly linked to the physical changes caused by thermal expansion, offers a more accurate and sensitive assessment of fire damage depth compared to methods relying solely on the presence of Portlandite for colorimetric indication.

Effects of Horseshoe Expander (Horseshoe Expander의 확장 효과에 관한 연구)

  • Chung, Kyu-Rhim;Park, Young-Guk;Lee, Young-Jun;Kim, Hong-Suk
    • The korean journal of orthodontics
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    • v.30 no.5 s.82
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    • pp.553-563
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    • 2000
  • Horseshoe Expander is one of Slow Maxillary Expansion(SME) which aims to accommodate the contra- lateral expansion and midpalatal suture expansion or the palate. The appliance consists of skeleton type strew embedded in split Horseshoe appliance. It is the objectives of the presentation to manifest the changes in dental & craniofacial components subsequent to the application of Horseshoe Expander. The subjects for this study consisted of 32 patients (mean age : 12.7). frontal, lateral cephalometric headfilm were taken and study casts were fabricated before and after expansion. 24 items were measured, compared preexpansion with postexpansion. Especially, palatal volume was measured by means of 'Hydro-measurement method'. Tooth axis measurement on the dental casts were made with Universal bevel protractor, and Horseshoe Expander group were compared with RME group. This study of changes to maxillary expansion with Horseshoe Expander revealed the following significant results. 1. Triangular-shaped expansion pattern appeared in frontal cephalometric headfilm. 2. Palatal plane, occlusal plane, mandibular plane and upper incisor to FH increased in lateral cephalometrir headfilm. 3. Palatal volume increased significantly. A slight bite opening, reduction of occlusal contact points showed in dental casts. 4. A 2.2:1 ratio of the amount of intermolar width in maxilla(orthodontic movement) to maxillary width (orthopedic movement) was determined. 5. Horseshoe Expander group has less buccal tipping tendency than RME group, by taking high correlation coefficients in the upper second premolar and first molar. It was suggested that Horseshoe Expander showed less orthodontic changes, less buccal tipping tendency. In addition, it was effective in maxillary expansion.

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Robust Design of a Driver-Side Airbag Using the Taguchi Method (다구찌법을 이용한 운전석 에어백의 강건설계)

  • 이권희;주원식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.2
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    • pp.131-138
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    • 2004
  • In the proto design stage of a new car, the performances of an occupant protection system can be evaluated by CAE even though the real test should be carried out. The number of the real test is reduced by the exact predictions followed by the appropriate design recommendation. However, the existing researches using CAE in predicting the performances do not consider the uncertainties of parameters. That often leads to inconsistency between test and CAE. In this research, the robust design of a protection system such as airbag and load limiter is suggested considering the frontal crash. The parameter design scheme of the Taguchi method is introduced to obtain the robust design of arbitrary airbag and load limiter. It is performed based on the frontal crash test condition of US-NCAP with an arbitrary passenger car. The variances of the performances such as HIC, chest acceleration and probability of combined injury are calculated by the outer array and the Taylor series expansion. Through the analysis of the Taguchi method, the robust optimum is determined.

Free Vibration Analysis of Perforated Plate Submerged in Fluid

  • Jhung, Myung-Jo;Jo, Jong-Chull;Jeong, Kyeong-Hoon
    • Journal of Mechanical Science and Technology
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    • v.20 no.9
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    • pp.1323-1338
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    • 2006
  • An analytical method to estimate the coupled frequencies of the circular plate submerged in fluid is developed using the finite Fourier-Bessel series expansion and Rayleigh-Ritz method. To verify the validity of the analytical method developed, finite element method is used and the frequency comparisons between them are found to be in good agreement. For the perforated plate submerged in fluid, it is almost impossible to develop a finite element model due to the necessity of the fine meshing of the plate and the fluid at the same time. This necessitates the use of solid plate with equivalent material properties. Unfortunately the effective elastic constants suggested by the ASME code are found to be not valid for the modal analysis. Therefore in this study the equivalent material properties of perforated plate are suggested by performing several finite element analyses with respect to the ligament efficiencies.

An Implementation of FM-extended Stereo System via Application of Quadrature Modulation and Companding Method (직교 변조 및 압신 방식을 이용한 확장형 FM 스테레오 방식의 구현)

  • Heo, Dong-Kyu;Kim, Kee-Keun;Kim, Ju-Koang;Ryu, Heung-Gyoon
    • The Journal of the Acoustical Society of Korea
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    • v.10 no.2
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    • pp.44-51
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    • 1991
  • In this paper, we have studied the FM-extended broadcasting which makes the enhancement of stereo signal-to-noise ration by utilizing the compression technique and quadrature moduation method of standard subcarrier signal in transmitter station, and corresponding demodulation method and expansion technique in receiver system. The proposed system is completely compatible with the conventional FM stereo system. We have confirmed the validity of the proposed method by implementation of transmitter/receiver system including quadrature modulation/demodulation and companding system.

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A natural frequency sensitivity-based stabilization in spectral stochastic finite element method for frequency response analysis

  • Lee, Gil-Yong;Jin, Seung-Seop;Park, Yong-Hwa
    • Structural Engineering and Mechanics
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    • v.75 no.3
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    • pp.311-325
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    • 2020
  • In applying the spectral stochastic finite element methods to the frequency response analysis, the conventional methods are known to give unstable and inaccurate results near the natural frequencies. To address this issue, a new sensitivity based stabilized formulation for stochastic frequency response analysis is proposed in this paper. The main difference over the conventional spectral methods is that the polynomials of random variables are applied to both numerator and denominator in approximating the harmonic response solution. In order to reflect the resonance behavior of the structure, the denominator polynomials is constructed by utilizing the natural frequency sensitivity and the random mode superposition. The numerator is approximated by applying a polynomial chaos expansion, and its coefficients are obtained through the Galerkin or the spectral projection method. Through various numerical studies, it is seen that the proposed method improves accuracy, especially in the vicinities of structural natural frequencies compared to conventional spectral methods.

A New Probabilistic Generation Simulation Considering Hydro, Pumped-Storage Plants and Multi-Model (수력,양수 및 다중모델을 고려한 새로운 확률론적 발전시뮬레이션)

  • 송길영;최재석
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.40 no.6
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    • pp.551-561
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    • 1991
  • The probabilistic generation simulation plays a key role in power system expansion and operational planning especially for the calculation of expected energy, loss of load probaility and unserved energy expected. However, it is crucial to develop a probabilistic generation simulation algorithm which gives sufficiently precise results within a reasonable computation time. In a previous paper, we have proposed an efficent method using Fast Hartley Transform in convolution process for considering the thermal and nuclear units. In this paper, a method considering the scheduling of pumped-storage plants and hydro plants with energy constraint is proposed. The method also adopts FHT techniques. We improve the model to include multi-state and multi-block generation. The method has been applied for a real size model system.

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A SCHWARZ METHOD FOR FOURTH-ORDER SINGULARLY PERTURBED REACTION-DIFFUSION PROBLEM WITH DISCONTINUOUS SOURCE TERM

  • CHANDR, M.;SHANTHI, V.
    • Journal of applied mathematics & informatics
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    • v.34 no.5_6
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    • pp.495-508
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    • 2016
  • A singularly perturbed reaction-diffusion fourth-order ordinary differential equation(ODE) with discontinuous source term is considered. Due to the discontinuity, interior layers also exist. The considered problem is converted into a system of weakly coupled system of two second-order ODEs, one without parameter and another with parameter ε multiplying highest derivatives and suitable boundary conditions. In this paper a computational method for solving this system is presented. A zero-order asymptotic approximation expansion is applied in the second equation. Then, the resulting equation is solved by the numerical method which is constructed. This involves non-overlapping Schwarz method using Shishkin mesh. The computation shows quick convergence and results presented numerically support the theoretical results.

Advanced 1D Structural Models for Flutter Analysis of Lifting Surfaces

  • Petrolo, Marco
    • International Journal of Aeronautical and Space Sciences
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    • v.13 no.2
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    • pp.199-209
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    • 2012
  • An advanced aeroelastic formulation for flutter analyses is presented in this paper. Refined 1D structural models were coupled with the doublet lattice method, and the g-method was used for flutter analyses. Structural models were developed in the framework of the Carrera Unified Formulation (CUF). Higher-order 1D structural models were obtained by using Taylor-like expansions of the cross-section displacement field of the structure. The order (N) of the expansion was considered as a free parameter since it can be arbitrarily chosen as an input of the analysis. Convergence studies on the order of the structural model can be straightforwardly conducted in order to establish the proper 1D structural model for a given problem. Flutter analyses were conducted on several wing configurations and the results were compared to those from literature. Results show the enhanced capabilities of CUF 1D in dealing with the flutter analysis of typical wing structures with high accuracy and low computational costs.