• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 춘계학술대회 논문집
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• pp.46-51
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• 2008

In this study, evaluation system of the thermal properties of the exothermic agents was investigated. Exothermic agents property evaluation system was developed by metering variation of power supply. Thermal properties of exothermic agents was affected by material mixture condition of exothermic agents, however, it was not affected by temperature. It is possible to make various exothermic agents by means of regulating thermal properties which is based on property evaluation system of exothermic agents.

• 소성∙가공
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• 제18권5호
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• pp.401-409
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• 2009

The change of the thermal properties of exothermic and insulating materials with the mixing condition of raw materials which is the most important factor for exothermic & insulating materials was investigated by using the evaluation system of the thermal properties of exothermic and insulating materials. In this study, the effect of the thermal properties of the exothermic & insulating materials such as exothermic properties, endothermic properties, insulating properties, maximum temperature of molten metal, ignition time of exothermic & insulating materials and temperature recovery time on the mixing ratio of reductant and oxidant, types of reductant, and particle sizes of reductants was examined. It could be expected to design the mixing condition of raw materials for various exothermic and insulating materials.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 춘계학술대회 논문집
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• pp.118-126
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• 2009

The change of the thermal properties of exothermic & insulating materials with mixing condition of raw materials which is the most important factor for exothermic & insulating materials was investigated by using the evaluation system of the thermal properties of exothermic & insulating materials. In this study, the effect of the thermal properties of the exothermic & insulating materials such as exothermic properties, endothermic properties, insulating properties, maximum temperature of molten metal, ignition time of exothermic & insulating materials and temperature recovery time on the mixing ratio of reductant and oxidant, types of reductant, and particle sizes of reductants was examined. It could be expected to design the mixing condition of raw materials for various exothermic & insulating materials.

• 소성∙가공
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• 제17권5호
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• pp.356-363
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• 2008

An evaluation system of the thermal properties of exothermic & insulating materials was developed. By measuring the power supply of the induction furnace, the thermal property of exothermic & insulating materials could be evaluated with high reproducibility at elevated temperature of molten steel. The thermal properties of exothermic & insulating materials were affected by mixing condition of raw materials. The effect of main components of exothermic & insulating materials such as metallic aluminum and $Fe_2O_3$ powder on the exothermic and insulating properties was examined. It could be expected to design and develop various exothermic & insulating materials by means of the evaluation system of the thermal properties.

• 한국건축시공학회지
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• 제16권1호
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• pp.25-34
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• 2016

부도체로 알려져 있는 기존의 콘크리트에 전기 전도성 재료를 혼입하여 발열 콘크리트로서 개발하려는 연구가 90년대 이후 진행되어 왔다. 하지만 콘크리트 시험체의 발열 재현성 확보가 어려워 활발한 연구가 이루어지지 못했다. 이에 따라 본 연구에서는 융설용 재료로써 활용 가능한 발열 콘크리트 개발을 목적으로, 흑연, 금속분말, 혼화제를 혼입한 시멘트 페이스트 및 모르타르를 제작하여 $-2^{\circ}C$의 저온환경에서의 발열특성과 재현성을 평가하였다. 또한 미세화학분석을 통해 발현 재현성의 원인을 규명하고자 하였다. 실험 결과, 흑연과 고성능 AE감수제를 혼입한 시험체가 가장 우수한 발열 성능 및 재현 가능성을 보였다. 이에 따른 미세화학분석 결과, 고성능 AE 감수제 내의 폴리머 혹은 메타크릴산 성분이 흑연과 전기화학적 반응을 일으켜 발열 재현성능을 부여한 것으로 판단된다.

• Computers and Concrete
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• 제19권6호
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• pp.659-666
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• 2017

Based on the Arrhenius equations, several hydration exothermic models that precisely calculate the influence of concrete's self-temperature duration on its hydration exothermic rate have been presented. However, the models' convergence is difficult to achieve when applied to engineering projects, especially when the activation energy of the Arrhenius equation is precisely considered. Thus, the models' convergence performance should be improved. To solve this problem and apply the model to engineering projects, the relationship between fast iteration and proper expression forms of the adiabatic temperature rise, the coupling relationship between the pipe-cooling and hydration exothermic models, and the influence of concrete's self-temperature duration on its mechanical properties were studied. Based on these results, the rapid convergence of the hydration exothermic model and its coupling with pipe-cooling models were achieved. The calculation results for a particular engineering project show that the improved concrete hydration exothermic model and the corresponding mechanical model can be suitably applied to engineering projects.

• 한국건축시공학회지
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• 제16권3호
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• pp.247-255
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• 2016

콘크리트에 전기전도성을 부여하여 확보한 발열 성능을 통해 주택의 난방이나 터널, 도로 또는 교량 상판에 눈녹이는 것이 가능하다. 본 연구는 전기전도 발열 콘크리트 개발을 위한 선행 연구로써 탄소계 전도성 재료인 흑연을 치환한 모르타르의 역학적 특성과 함께 전기저항 및 발열 특성에 대한 실험을 실시한 후 다음과 결과를 얻었다. 토상 흑연 치환율이 증가할수록 압축강도는 감소하는 것으로 나타났으나 전기 저항은 크게 낮아지는 것으로 나타났다. 발열특성을 보이기 위해서는 흑연의 혼입이 모르타르 전체 체적의 15%이상 이루어져야 하는 것으로 나타났다. 흑연의 혼입이 일정수준이상 이루어져 낮은 전기저항 및 발열특성을 확보한 경우에는 작용하는 전압과 발열량은 높은 상관관계를 가지며 전압의 제곱과 발열온도는 비례관계에 있는 것으로 나타났다.

• 한국안전학회지
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• 제17권2호
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• pp.39-44
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• 2002

This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

• 한국안전학회지
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• 제16권2호
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• pp.75-79
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• 2001

For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 추계 학술논문 발표대회
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• pp.131-132
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• 2014

In this study, an experiment was carried out using graphite, conductive nickel powder, copper bar, carbon fiber for evaluate the exothermic properties and heating reproducibility of the cement mortar containing conductive material. As a result, the conductive materials that interfere with heating reproducibility are present, and the optimal conductive materials exist in each input voltage.