• Transactions of the Society of Information Storage Systems
• /
• v.8 no.2
• /
• pp.56-60
• /
• 2012

Graphene oxide, which is exfoliated by oxidant from graphite, is the material for solving the problem of mass production and positioning. We made graphene oxide based devices by dielectrophoresis, studied and controlled factors which can affect the characteristic of graphene oxide channel. Graphene oxide channel assembled by dielectrophoresis can be constructed differently by various frequency options. We confirmed the change of gate characteristics and I-V characteristics in the range from 80K to 300K temperature.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.233.1-233.1
• /
• 2016

화학적 방법에 의한 NTE graphite의 박리 또는 전도도 개선을 위한 도핑공정을 수행할 경우, 결함 및 불순물 생성에 의해 재결정화 공정 및 순도 개선을 위한 별도의 공정을 필요로한다. 본 연구에서는 건식 방법으로써 10,000K 이상의 초고온 RF 열플라즈마를 이용하여 in-situ 방법으로 흑연의 박리, 결함 제거, 결정성 향상 및 도핑 공정을 수행하고, 도핑특성을 평가하였다. 질소 도핑을 위하여 암모니아 가스를 첨가하여 NTE graphite를 도핑 처리하였으며, 시뮬레이션을 통하여 반응기 내부의 온도분포를 파악하고, 도핑을 위한 암모니아가스가 분해되어 도핑공정이 수행될 수 있는 투입위치를 결정하였다. 질소 도핑율은 암모니아 가스의 주입위치에서의 온도 및 가스 주입 유량 등의 공정조건에 따라 변화됨을 확인하였고, XPS 분석결과 최대 14.87 atomic%의 도핑율의 결과를 얻었다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.336-336
• /
• 2016

We have investigated magneto-transport properties in a MoS2 lateral spin-valve structures for different ferromagnetic CoFe electrode shapes and MoS2 channel lengths. For these devices, high quality and large-scale MoS2 thin films were synthesized through sulfurization of epitaxial MoO3 films and these sulfurized-MoO3 thin films properties are in good agreements with measurements on exfoliated MoS2 film. Magneto-transport measurements show a clear rectangular magnetoresistance signal of 0.16% and a spin polarization of 0.00012%. By using the one-dimensional spin diffusion equation, we extracted the spin diffusion length and coefficient, finding them to be 12 nm and $1.44{\times}10-3cm2/s$, respectively. These small values of magnetoresistance and spin polarization could be enhanced by appeasement of conductivity mismatch between the ferromagnet and semiconductor interface.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.120.1-120.1
• /
• 2015

We investigate the degradation pattern of Black phosphorus (BP) field effect transistor (FETs) investigated by using an mechanically exfoliated BP that react O2 and water vapor in ambient condition, degradation. The BP FETs was electrically measured every 20 minutes (1cycle) in the air, the total cycle is 100. We show electrical changes with Mobility, On/off ratio, Current and a significant positive shift in the threshold voltage. We extracted the current level at Vgs-Vth = 0, -10, -20 and fitting with Swiss-cheese model. This model suggested that Swiss-cheese model is well fitted with degradation pattern of BP FETs.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.167.1-167.1
• /
• 2015

We investigate the degradation pattern of Black phosphorus (BP) field effect transistor (FETs) was investigated by using an mechanically exfoliated BP that react O2 and water vapor in ambient condition, degradation. The BP FETs was electrically measured every 20 minutes (1cycle) in the air, the total cycle is 100. We show electrical changes with Mobility, On/off ratio, Current and a significant positive shift in the threshold voltage. We extracted the current level at Vgs-Vth = 0, -10, -20 and fitting with Swiss-cheese model. This model suggested that Swiss-cheese model is well fitted with degradation pattern of BP FETs.

• Macromolecular Research
• /
• v.11 no.6
• /
• pp.418-424
• /
• 2003

Exfoliated poly(methyl methacrylate-co-styrene) [P(MMA-co-ST)]/silicate nanocomposites were synthesized through a multistep emulsion polymerization. The methyl methacrylate monomers were polymerized first and then the styrene monomers were polymerized. The nanocomposites had core-shell structures consisting of PMMA (core) and PS (shell); these structures were confirmed by $^1$H NMR spectroscopy and TEM, respectively. P(MMA-co-ST) copolymers showed two molecular weight profiles and two glass transition temperatures (T$_{g}$) in GPC and DMA measurements. At 30 $^{\circ}C$, the nanocomposites exhibited 83 and 91 % increases in their storage moduli relative to the neat copolymer because the silicate layers were dispersed uniformly in the polymer matrix.x.

• Macromolecular Research
• /
• v.11 no.6
• /
• pp.425-430
• /
• 2003

Two types of poly(n-butyl acrylate) copolymer/silicate nanocomposites have been produced: poly(n-butyl acrylate-co-methyl methacrylate) [P(BA-co-MMA)]/silicate nanocomposites and poly(n-butyl acrylate-co-styrene) [P(BA-co-ST)]/silicate nanocomposites. The P(BA-co-MMA)/silicate nanocomposites shows the exfoliated structures but a P(BA-co-ST)/silicate nanocomposites have intercalated structures, because the BA/MMA comonomer has a higher polarity (e-value in Q-e scheme) than the BA/ST comonomer. The BA/MMA comonomer expanded the interlayer space of the silicate wider than did the BA/ST comonomer. The thermal degradation onset point of the P(BA-co-MMA)/silicate nanocomposites was 43$^{\circ}C$ higher than that of pure P(BA-co-MMA). P(BA-co-MMA)T5%, P(BA-co-MMA)T10%, and P(BA-co-MMA)T20% exhibit 134,302, and 195% increases, respectively, in their storage moduli at -20$^{\circ}C$ relative to the pure copolymer.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2003.03a
• /
• pp.226-226
• /
• 2003

일반적으로, 고분자 매트릭스에 층상 점토광물이 분산되어 얻어지는 복합재료는 세가지 형태를 이룬다. 첫째 통상의 복합재료는 고분자 매트릭스 내에 점토입자가 고루게 분산된 상태를 말하며, 둘째 점토 층 사이에 고분자 모노머나 올리고머가 일부분 삽입된 삽입형 복합재료(intercalated composite)이며, 셋째 점토 층 사이에 삽입된 모노머나 올리고머의 경화 또는 중합반응을 통해 점토내의 한층 한층 균일하게 매트릭스 내에 분산된 박리형 나노복합소재(exfoliated nanocomposite) 이다. 이들 복합재료들 중 박리형 나노복합소재는 적은 양의 점토가 단위 층으로 고분자 매트릭스에 완전히 분산되어 다양한 물성의 향상이 기대되는 재료이다. 따라서 최근 고분자의 기계적 강도, 팽윤 저항성 그리고 차폐특성 둥 전반적인 물성을 향상시키는 방법으로 층상 점토광물의 층 사이에 다양한 유기물을 삽입하여 층간거리를 확장시킨 유기 점토광물을 제조하고 이를 고분자 소재에 첨가하여 박리형 나노복합소재를 제조하는 방법이 많은 연구가 수행되고 있다.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.05a
• /
• pp.292-295
• /
• 2004

Recently, polymer-clay hybrid materials have received considerable attention from both a fundamental research and application point of view. This organ-inorganic hybrid, which contains a nanoscale dispersion of the layered silicates, is a material with greatly improved thermal and mechanical characteristics. Two classes of nanocomposites were synthesized using an unsaturated polyester resin as the matrix and sodium montmorillonite as well as an organically modified montmorillonite as the reinforcing agents. X -ray diffraction pattern of the composites showed that the interlayer spacing of the modified montmorillonite were exfoliated in polymer matrix. The mechanical properties also supported these findings, since in general, tensile strength, modulus with modified montmorillonite were higher than the corresponding properties of the composites with unmodified montmorillonite. Adding organically modified clay improved the tensile strength of unsaturated polyester by $22\%$ and the tensile modulus of unsaturated polyester was also improved by $34\%$.

• Transactions on Electrical and Electronic Materials
• /
• v.14 no.5
• /
• pp.278-281
• /
• 2013

The effects of electric field frequency on the AC electrical treeing phenomena in an epoxy/layered silicate (1.5 wt%) were investigated in a needle-plate electrode arrangement. A layered silicate was exfoliated in an epoxy-base resin with AC electric field apparatus. To measure the treeing initiation and propagation- and the breakdown rate, a constant alternating current (AC) of 10 kV with three different electric field frequencies (60, 500, and 1,000 Hz) was applied to the specimen in the needle-plate electrode specimen in an insulating oil bath at $130^{\circ}C$. At 60 Hz, the treeing initiation time was 12 min, the propagation rate was $0.24{\times}10^{-3}$ mm/min, and the morphology was a dense branch type. As the electric field frequency increased, the treeing initiation time decreased and the propagation rate increased. At 1,000 Hz, the treeing initiation time was 5 min, the propagation rate was $0.30{\times}10^{-3}$ mm/min, and the morphology was a dense bush type.