• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.118-122
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• 1993

The 77 K luminescence and excitation spectra, room-temperature FT-infrared and visible absorption spectra of a newly prepared complex cis-[Cr(cyclam)(pn)]$(ClO_4)_3$, where cyclam and pn represent 1,4,8,11-tetraazacyclotetradecane and 1,2-propanediamine respectively, have been measured. Absorption maximum of the first spin-allowed transition in the electronic absorption spectra of cis-[Cr(cyclam)(pn)]$^{3+}$ and cis-[Cr(cyclam)(en)]$^{3+}$ appears at nearly the same position. The two spin-allowed and six spin-forbidden electronic transitions are assigned from the visible absorption and excitation spectra. It is also shown that the zero phonon line in the excitation spectrum splits into two components by 50 cm$^{-1}$.

• Bulletin of the Korean Chemical Society
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• 제13권1호
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• pp.17-20
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• 1992

Photoionization processes of TMPD in $H_2O$ and $D_2O$ were studied, by measuring steady-state absorption, emission, fluorescence excitation spectra, and fluorescence lifetimes on picosecond time scale. The steady-state absorption spectra showed that there exists a cation-ion pair (Wurster's Blue) in $H_2O$ and in $D_2O$ in the electronic ground state. Temperature and excitation wavelength dependence were also studied and the results show that the photoionization reaction in water is an activated process and the fluorescence lifetime is independent of the vibrational excess energy in the uv excitation range of 283-310 nm.

• Bulletin of the Korean Chemical Society
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• 제19권10호
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• pp.1063-1068
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• 1998

The nature of F electronic excitation energy transfer to OH- vibrational levels in KCl crystals is the exchange interaction, although the transfer process exhibits three temporally distinguishable components depending on the distance between excited F center and OH-. The critical distance as well as rate of the major energy transfer process in randomly distributed samples increases rapidly as OH- librational motions become active with temperature rise. The excited state character introduced into the OH- ground electronic state by perturbation is essential for the exchange interaction. The perturbation is brought about by the expanded electron cloud of excited F center for OH- associated to F center, whereas by librations and lattice vibrations perpendicular to the bond axis for isolated OH- . F excitation quenching efficiency by OH- is dependent on the variation of the critical distance rather than the rate as the rate is much faster than the normal F bleach recovery rate.

• Journal of international Conference on Electrical Machines and Systems
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• 제2권4호
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• pp.394-398
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• 2013

This paper presents output characteristics of a linear switched reluctance motor (LSRM) with excitation windings wound by using high-temperature superconducting (HTS) tapes. In a double-sided LSRM, Bi-2223 or YBCO tape conductors are used for the excitation windings. The characteristics of the LSRM are obtained by a finite element method analysis. We can obtain large thrust compared with a conventional LSRM by using YBCO tape conductors. Also, the effect of a configuration of the YBCO coil on the thrust is calculated. We discuss a suitable coil configuration for the average thrust upgrading.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.453-460
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• 1997

In order to investigate the electrical conduction properties of polyethylene thin film for power cable with manufacturing methods, the thickness of specimen was the 30, 100[${\mu}{\textrm}{m}$] of LDPE and 200[${\mu}{\textrm}{m}$] of XLPE were manufactured. The experimental condition for conduction properties was measured until the breakdown occurs at temperature ranges from 30 to 110[$^{\circ}C$] and the electric field from 1$\times$10$^3$to 5$\times$10$^{6}$ [V/cm]. As for increase of temperature, the current density of LDPE was increased with constant ratio in low field, but changes with exponential function in high electric field. The tunnel current of pre-breakdown region is shifted toward low field as much as thermal excitation energy. At low electric field, the XLPE showed dominant electrical conduction properties by thermal excitation, and transformation of the electron was resisted by the crystal at high electric field.

• International Journal of Aeronautical and Space Sciences
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• 제13권3호
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• pp.332-348
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• 2012

The present study deals with the parametric resonance behaviour of laminated composite curved shell panels in a hygrothermal environment using Bolotin's approach. A simple laminated model is developed using first order shear deformation theory (FSDT) for the vibration and dynamic stability analysis of laminated composite shells subjected to hygrothermal conditions. A computer program based on the finite element method (FEM) in a MATLAB environment is developed to perform all necessary computations. Quantitative results are presented to show the effects of curvature, ply-orientations, degree of orthotropy and geometry of laminates on the parametric instability of composite curved shell panels for different temperature and moisture concentrations. The excitation frequencies of laminated composite panels decrease with the increase of temperature and moisture due to reduction of stiffness for all laminates.

• Journal of Photoscience
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• 제4권3호
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• pp.121-125
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• 1997

The 77 K emission and excitation, and room-temperature visible spectra of cis[Cr(cyclam)Br$_2$]Br (cyclam=1,4,8,11-tetraazacyclotetradecane) are reported. The mid- and far-infrared spectra at room-temperature are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. It is found that nitrogen atoms of the cyclam ligand have strong $\sigma$-donor characters, but bromide ligand has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion. The zerophonon line in the excitation spectrum splits into two components by 172 cm$^{2-}$, and the large $^2E_g$ splitting can be reproduced by the ligand field theory.

• 한국소음진동공학회논문집
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• 제23권7호
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• pp.654-661
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• 2013

The dynamic characteristics of a free-piston stirling engine(FPSE) with regard to the working frequency is investigated from theoretical and experimental studies. The FPSE is modeled as a two degree-of-freedom linear vibration system. A theoretical expression on the working frequency is derived from the instability condition for self-excitation based on the linear vibration model. A ${\gamma}$-type free-piston stirling engine is fabricated for experimental studies, and its working frequency is measured on various heater temperatures. Comparisons between the theoretical and experimental results reveal that the working frequency of the test FPSE depends on both the temperature of the compression space and the temperature difference between the expansion and compression spaces.

• Bulletin of the Korean Chemical Society
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• 제15권2호
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• pp.145-150
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• 1994

The low temperature luminescence and excitation, room-temperature UV-visible and infrared spectra of [Cr(${\pm})chxn_3]Cl_3$ (chxn=trans-1,2-cyclohexanediamine) have been measured. It is found that the zero-phonon line in the excitation spectrum splits into two components by $47\;cm^{-1}$. The eight electronic transitions due to spin-allowed and spin-forbidden are assigned. As expected, nitrogen atoms of chxn ligand have strong ${\sigma}-donor $properties toward chromium(Ⅲ). The positions and splittings of sharp-line transitions are analyzed as a function of the Cartesian bite (${\alpha}$) and twist (${\beta}$) angles to predict the metal-ligand geometry.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.878-883
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• 2001

The effects of external excitation with various frequencies and amplitudes on the flame behavior and pollution emission characteristics from a laminar jet flame are experimentally investigated. Measurements of $NO_{x}$ emission indices($EINO_{x}$), performed in unconformed and vertical lifted flame at resonance frequency by strong excitation, have been conducted experimentally. It was also conducted to investigate the effects of excited frequency on $NO_{x}$ emissions with a various frequency ranged 0Hz to 2kHz. From the vertical lifted flame like turbulent of the excited jet with resonance frequency was shown that the dependence of $NO_{x}$ emission could be categorized into three groups: Group 1 of intermediate flame length and relative narrow flame volume yielding low $NO_{x}$ emission, Group 2 of short flame length but large flame volume yielding high $NO_{x}$ emission and Group 3 of long flame length with low temperature contours yielding high $NO_{x}$ emission.