• Title/Summary/Keyword: Excitation energies

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A Study on the PES Estimation for Developing High-TPI HDD (High TPI HDD 구현을 위한 PES Estimation에 관한 연구)

  • J. S. Koh;S. W. Kang;Y. S. Han;Kim, Y. H.;T. Y. Hwang
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11a
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    • pp.319.1-319
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    • 2002
  • A frequency-domain PES estimation and its prediction method are proposed for the tightly-coupled servo/mechanical design of high-TPI HDD system above 100kTPI. The major two disturbance energies which are related with mechanical vibrations inside of HDD are used to predict the drive-level PES, while considering closed-loop servo dynamics. One is the torque disturbance which mainly comes from aerodynamic excitation of HSA system and the other is the displacement disturbance from disk-spindle dynamics. (omitted)

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A Comparison of the Density Functional Theory Based Methodologies for the Triplet Excited State of 𝛑-Conjugated Molecules: Time-Dependent DFT (TD-DFT), TD-DFT within Tamm-Dancoff Approximation (TDA-DFT), and Spin-Unrestricted DFT (UDFT) (𝛑-공액계 분자의 삼중항 여기 상태에 대한 Density Functional Theory (DFT)에 기반한 계산 방법들의 비교: 시간-의존 DFT (TD-DFT), Tamm-Dancoff 근사법을 적용한 DFT (TDA-DFT), 스핀-비제한 DFT (UDFT))

  • Ahn, Chang Hwan;Kim, Dongwook
    • Journal of the Korean Chemical Society
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    • v.63 no.2
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    • pp.73-77
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    • 2019
  • We compared methodologies based on the density functional theory (DFT), e.g., time-dependent DFT (TD-DFT), TD-DFT within Tamm-Dancoff approximation (TDA-DFT), and spin-unrestricted DFT (UDFT), that are usually employed to optimize the geometries of ${\pi}$-conjugated molecules in their lowest lying triplet excited ($T_1$) state. As a model system for ${\pi}$-conjugated molecules, we employed 1,2,3,4,5-pentacyano-6-phenyl-benzene. In conjunction with 6-31G(d) basis sets, we made use of gap-tuned range-separated ${\omega}B97X$ functional which is often employed recently in the calculations of molecular excited states. Near the equilibrium geometries, we found that the important difference between the geometries derived at UDFT level and those at TD-DFT or TDA-DFT methods: more stable ground-state energies but higher triplet excitation energies for UDFT derived geometries. In the studies, we discuss such differences in more detail.

Effect of Annealing Temperature on the Properties of NaNbO3:Eu3+ Phosphor Thin Films Deposited on Quartz Substrates (석영 기판 위에 증착된 NaNbO3:Eu3+ 형광체 박막의 특성에 열처리 온도가 미치는 영향)

  • Cho, Shinho
    • Journal of the Korean institute of surface engineering
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    • v.54 no.2
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    • pp.96-101
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    • 2021
  • NaNbO3:Eu3+ phosphor thin films were grown on quartz substrates by radio-frequency magnetron sputtering at a growth temperature of 100 ℃, with subsequent annealing at temperatures of 800, 900, and 1000 ℃. The effects of annealing temperature on the structural, morphological, and optical properties of the thin films were investigated. The NaNbO3:Eu3+ sputtering target was synthesized by a solid-state reaction of raw materials Na2CO3, Nb2O5, and Eu2O3. The X-ray diffraction patterns exhibited that the thin films had two mixed phases of NaNbO3 and Eu2O3. Surface morphologies were investigated by using field emission-scanning electron microscopy and indicated that the grains of the thin film annealed at 1000 ℃ showed irregular shapes with an average size of approximately 300 nm. The excitation spectra of Eu3+-doped NaNbO3 thin film consisted of a strong charge transfer band centered at 304 nm in the range of 240-350 nm and two weak peaks at 395 and 462 nm, respectively, resulting from the 7F05L6 and 7F05H2 transitions of Eu3+ ions. The emission spectra under excitation at 304 nm exhibited an intense red band centered at 614 nm and two weak bands at 592 and 681 nm. As the annealing temperature increased from 800 ℃ to 1000 ℃, the intensities of all the emission bands and the band gap energies gradually increased. These results indicate that the higher annealing temperature enhance the luminescent properties of NaNbO3:Eu3+ thin films.

Laser Acceleration of Electron Beams to the GeV-class Energies in Gas Jets

  • Hafz, Nasr A.M.;Jeong, Tae-Moon;Lee, Seong-Ku;Choi, Il-Woo;Pae, Ki-Hong;Kulagin, Victor V.;Sung, Jae-Hee;Yu, Tae-Jun;Cary, John R.;Ko, Do-Kyeong;Lee, Jong-Min
    • Journal of the Optical Society of Korea
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    • v.13 no.1
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    • pp.8-14
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    • 2009
  • In a laser-plasma wakefield accelerator, the ponderomotive force of an ultrashort high intensity laser pulse excites a longitudinal wave or plasma bubble in a way similar to the excitation of a wake wave behind a boat as it propagates on the water surface. Electric fields inside the plasma bubble can be several orders of magnitude higher than those available in conventional RF-based particle accelerator facilities which are limited by material breakdown. Therefore, if an electron bunch is properly phase-locked with the bubble's acceleration field, it can gain relativistic energies within an extremely short distance. Here, in the bubble regime we show the generation of stable and reproducible sub GeV, and GeV-class electron beams. Supported by three-dimensional particle-in-cell simulations, our experimental results show the highest acceleration gradients produced so far. Simulations suggested that the plasma bubble elongation should be minimized in order to achieve higher electron beam energies.

A Study on the PES Estimation for Developing High-TPI HDD (HIGH-TPI HDD 구현을 위한 PES ESTIMATION에 관한 연구)

  • Koh, Jeong-Seok;Kang, Seong-Woo;Han, Yun-Sik;Kim, Young-Hoon;Hwang, Tae-Yeon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11b
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    • pp.122-127
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    • 2002
  • A frequency-domain PES estimation and its prediction method are proposed for the tightly-coupled servo/mechanical design of high-TPI HDD system above 100 kTPI. The major two disturbance energies which are related with mechanical vibrations inside of HDD are used to predict the drive-level PES, while considering closed-loop servo dynamics. One is the torque disturbance which mainly comes from aerodynamic excitation of HSA system and the other is the displacement disturbance from disk-spindle dynamics. In order to obtain the accurate error transfer function of closed-loop servo control, the plant model is measured by accurate experiment. The measured PES is compared with predicted one in terms of frequency-domain PES spectrum and its standard variation value. It is proved that the proposed frequency-domain PES estimation/prediction method is capable of predicting drive-level PES of high-TPI hard disk drive.

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Estimation of Piezoelectric Fields built in InxGa1-XGaN Quantum Well Structures using Numerical Analysis (InxGa1-XN/GaN 양자우물 구조의 수치 해석을 이용한 압전장 평가)

  • 김경찬;김태근
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.1
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    • pp.89-93
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    • 2004
  • Piezoelectric fields built in I $n_{x}$G $a_1$$_{-x}$N/GaN (x=0.06∼0.1) quantum wells (QWs) have been estimated by comparing the transition energies, both calculated and measured by photoluminescence (PL). The calculation was numerically carried out with a rectangular QW model, where the effective bandgap considering a bowing facto, energy levels quantized for the lowest lying electrons and heavy holes (1e-lhh), and biaxial compressive strain were included except for the piezoelectric fields. The calculated values were observed to be larger (9∼15 meV) than the measured values by PL, which was considered to be caused by the piezoelectric fields built in InGaN/GaN QW interface. In addition, we observed the energy shift by measuring the EPDPL (excitation power-dependent PL), which was compared with the energy difference caused by the piezoelectric fields.

Physicochyemical Properties of $ZrF_4-Based$ Fluoride Glasses Containing Rare-Earth Ions

  • Ishioka, Noriyuki;Ogawa, Kouji;Arakawa, Tsuyoshi
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.375-378
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    • 1999
  • In tho XRD study of $56ZrF_4 \cdot34BaF_2 \cdot4AIF_3 \cdot(6-x)LaF_3 \cdotxLnF_3$ glassdLn=Ce, Nd, Gd, Th), halo pattern charactarktic fo an amorphous sample appeared. When the halo peak angle ($\theta_p$) was converted into a wavenumber with $Qp=4\pi sinG\pi/\lambda(\lambda$ is the wavolongth of the radialion used), it was found that the Qp values varied almost liuearly with the concentration 01 $LnF_3$. The emissiou spect1.a of $Ce^{3-}$-containing fluoride glasses nnder 273 nm excitation had a peak maximum at ea. 300 nm $(Ce^{3+}$ 5d-4f- transition). The maximal intensity of the fluorescence was observed when the $CeF_3$, content was extremely low (ca. 1 mol%j. DTA measurement revealed tbat these fluoride glasses had two crystallization temperatures. In $56ZrF_4. 34BaF_2. 4NF_3. (6-x)LaF_3 .xNdF_3$ glasses, the actmation energies of crystallization obtained from a Kssinger plot were 1.7 and 5.0 eV for the glass with x=2, and 1.9 and 5.6 eV for the glass with x=4.

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Optical Characteristics of Ge0.99Sn0.01/Si and Ge/Si Using Photoreflectance Spectroscopy

  • Jo, Hyun-Jun;Geun, So Mo;Kim, Jong Su;Ryu, Mee-Yi;Yeo, Yung Kee;Kouvetakis, J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.378.2-378.2
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    • 2014
  • We have investigated optical characteristics of $p-Ge_{0.99}Sn_{0.01}$ and Ge films grown on Si substrates using photoreflectance (PR) spectroscopy. The $Ge_{0.99}Sn_{0.01}$ and Ge films were grown by using an ultra-high vacuum chemical vapor deposition and molecular beam epitaxy methods, respectively. PR spectra were measured at 25 K and an extended InGaAs detector was used. By comparing $Ge_{0.99}Sn_{0.01}/Si$ and Ge/Si spectra, we observed the signals related to direct transition and split-off band of $Ge_{0.99}Sn_{0.01}$. The transition energies of $Ge_{0.99}Sn_{0.01}$ and Ge films were approximately 0.74 and 0.84 eV, respectively. Considering the shift of split-off band transition of $Ge_{0.99}Sn_{0.01}$, we suppose that the transition at 0.74 eV is attributed to direct transition between ${\Gamma}$ band and valence band. The temperature- and excitation power-dependent PR spectra were also measured.

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An Investigation of Power Flow Mechanism in Beam-plate Built-up Structures with an Energy-absorbing Plate (보-판 결합 구조물에서 에너지 흡수체로 작용하는 판의 특성에 따른 파워 전달 특성에 관한 연구)

  • Yoo, Ji-Woo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.17 no.1 s.118
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    • pp.55-64
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    • 2007
  • In the built-up structure consisting of a stiff beam and a flexible plate, Grice showed that the plate behaves as an energy absorber in narrow frequency bands(called plate blocking effect). This paper deals with such beam-plate coupled structures, where the plate is an energy absorber and the excited beam is an energy path. It is found that such energy dissipation can occur in the relatively broad bands, if different stiffnesses are used in the rectangular plate. It was experimentally verified by Heckl that the energies in terms of one-third octave band averages transferred to the plate(or dissipated in the plate) increase for increased plate damping. This Paper, however, shows that the energy absorption suddenly reduces at the certain narrow frequency bands where the plate damping effect upon the coupled beam is maximum. Also, in order to minimize energy transfer through the beam in terms of one-third octave band averages, it is advantageous to increase the plate damping closer to the excitation point All these results are based on the wane method.

Solvent Effects on the Solvatochromism of 7-Aminocoumarin Derivatives in Neat and Binary Solvent Mixtures: Correlation of the Electronic Transition Energies with the Solvent Polarity Parameters

  • Choi, Jin-Yeong;Park, Eun-Ju;Chang, Seung-Hyun;Kang, Tai-Jong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1452-1458
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    • 2009
  • The change in the electronic absorption and emission energy of 7-aminocoumarin derivatives in binary solvent mixtures has been studied. The electronic transition energy along with the Stokes' shift is correlated with the orientation polarizability of the solvent as well as the empirical solvent polarity parameters $E_T$ (30). It is observed that the emission peak shift traces the change of $E_T$ (30) value very closely in binary solvent mixtures. The emission transition more strongly depends on the solvent polarity than the absorption, which indicates the dipole moment gets larger on excitation. From the dependence of the Stokes’ shift of 7-aminocoumarins with the solvent polarity parameters and the ground state dipole moment obtained by the semi-empirical calculations, the excited state dipole moment was estimated. The fluorescence lifetime change of 7-aminocoumarins in binary solvent mixtures was measured and the results are explained in terms of molecular conformation and solvent polarity. The study indicates the empirical solvent polarity $E_T$ (30) is a good measure of microscopic solvent polarity and it probes in general the non-specific solvent interactions.