• 한국세라믹학회지
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• 제39권3호
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• pp.240-244
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• 2002

$Gd_2O_3,\;CeO_2$ 및 $NH_4Br$ 분말을 사용하여 GdOBr:Ce 형광체를 고상 반응으로 합성하였다. GdOBr:Ce 형광체는 370nm UV 여기 하에 410∼430nm의 영역에서 청색 발광스펙트럼을 보였으며, 2mol%의 Ce 농도에서 최대 발광특성을 나타냈다. FED용 형광체로의 응용 가능성을 알아보기 위해 GdOBr:Ce 형광체의 음극서 발광(CL)을 측정하였다. CL의 경우 PL과 동일한 영역인 410∼430nm에서 발광을 나타냈으며, Ce 농도가 1mol%일 때 발광의 최대치를 보였다. CL에서의 degradation 효과를 보기 위해 전자선을 10분간 조사하여 상용형광체와 비교하였다. 이로부터 GdOBr:Ce 형광체를 FED용 청색 형광체로 응용할 수 있는 가능성을 확인하였다.

• 한국재료학회지
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• 제21권12호
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• pp.644-649
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• 2011

[ $A_{3-2x/3}Al_{1-z}In_{z}O_4F:Eu_x^{3+}$ ](A = Ca, Sr, Ba, x = -0.15, z = 0, 0.1) oxyfluoride phosphors were simply prepared by the solid-state method at $1050^{\circ}C$ in air. The phosphors had the bright red photoluminescence (PL) spectra of an $A_{3-2x/3}Al_{1-z}In_{z}O_4F$ for $Eu^{3+}$ activator. X-ray diffraction (XRD) patterns of the obtained red phosphors were exhibited for indexing peak positions and calculating unit-cell parameters. Dynamic excitation and emission spectra of $Eu^{3+}$ activated red oxyfluoride phosphors were clearly monitored. Red and blue shifts gradually occurred in the emission spectra of $Eu^{3+}$ activated $A_3AlO_4F$ oxyfluoride phosphors when $Sr^{2+}$ by $Ca^{2+}$ and $Ba^{2+}$ ions were substituted, respectively. The concentration quenching as a function of $Eu^{3+}$ contents in $A_{3-2x/3}AlO_4F:Eu^{3+}$ (A = Ca, Sr, Ba) was measured. The interesting behaviors of defect-induced $A_{3-2x/3}Al_{1-z}In_{z}O_{4-{\alpha}}F_{1-{\delta}}$ phosphors with $Eu^{3+}$ activator are discussed based on PL spectra and CIE coordinates. Substituting $In^{3+}$ into the $Al^{3+}$ position in the $A_{3-2x/3}AlO_4F:Eu^{3+}$ oxyfluorides resulted in the relative intensity of the red emitted phosphors noticeably increasing by seven times.

• 한국전기전자재료학회논문지
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• 제14권3호
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• pp.246-250
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• 2001

ZnO thin films for light emission device have been deposited on sapphire and silicon substrates by pulsed laser deposition technique(PLD). A Nd:YAG laser was used with the wavelength of355 nm. In order to investigate the emission properties of ZnO thin films, Pl measurements with an Ar ion laser a light source using an excitation wavelength of 351 nm and a power of 100 mW are used. All spectra were taken at room temperature by using a grating spectrometer and a photomultiplier detector. ZnO exhibited Pl bands centers around 390, 510 and 640 nm, labeled near ultra-violet(UV), green and orange bands. Structural properties of ZnO thin films are analyzed with X-ray diffraction(XRD).

• 천문학회보
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• 제43권1호
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• pp.72.1-72.1
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• 2018

Recently, an analysis of 3-micron spectra of CH4 line emission from our Gemini/GNIRS observations of Jupiter's polar regions yielded an unexpected result: The homopause (~1 microbar pressure level) located directly above the long-lasting 8-micron CH4 north-polar hot spot (Great 8-micron Hot Spot: GHS) is cool compared with the temperatures of nearby auroral regions (Kim et al. 2017). Most of the 8-micron emission of the GHS originates from CH4 at the ~1 mbar level (i.e., deeper in the stratosphere, where cooling time is several years), much longer than at the altitude of the homopause. We propose a mechanism to explain the temperature difference: locally-fixed and transient, but energetic auroral particles, which can penetrate to the 1 mbar level and deposit energy there creating and maintaining the GHS. For Saturn, thus far we have not detected distinctive 8-micron nor 3-micron CH4 hot spots in the polar regions. We will present a possible implication for this difference between Jupiter and Saturn.

• 한국표면공학회지
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• 제51권5호
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• pp.271-276
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• 2018

The effects of activator ion on the structural, morphological, and optical properties of $LaNbO_4:RE^{3+}$ (RE = Dy, Dy/Sm, Sm) phosphors were investigated. X-ray diffraction patterns exhibited that all the phosphors showed a monoclinic system with a main (112) diffraction peak, irrespective of the concentration and type of activator ions. The grain size showed a slightly decreasing tendency as the concentration of $Sm^{3+}$ ions increased. The excitation spectra of the $LaNbO_4:Dy^{3+}$, $Sm^{3+}$ phosphor powders consisted of a strong charge transfer band centered at 259 nm in the range of 220-290 nm and five weak peaks. The emission spectra of the $La_{0.95}NbO_4$:5 mol% $Dy^{3+}$ phosphors exhibited two intense yellow and blue bands centered at 575 nm and 479 nm respectively, which resulted from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ and $^4F_{9/2}{\rightarrow}^6H_{15/2}$ transitions of $Dy^{3+}$. As the concentration of $Sm^{3+}$ was increased, the intensity of the yellow emission band was gradually decreased, while those of orange and red emission bands centered at 604 and 646 nm began to appear and reached maxima at 5 mol%, and then decreased rapidly with further increases in the $Sm^{3+}$ concentration. These results indicated that white light emission could be realized by controlling the concentrations of the $Dy^{3+}$ and $Sm^{3+}$ ions incorporated into the $LaNbO_4$ host crystal.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.1297-1299
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• 2009

A series of $Eu^{2+}/Mn^{2+}$ co-activated $Ba_{1.98-x}Sr_xZnS_3$ red emission phosphors was synthesized using the polymerizable complex method. The excitation spectra of the materials contain two wide bands centered at 345nm and 445nm, implicating their possible use for white LED lighting applications. In addition, substitution of Sr for Ba by 20% (x=0.4) improved drastically the emission intensity as well as the internal quantum efficiency compared to those for Sr-free $Ba_2ZnS_3:Eu^{2+}/Mn^{2+}$ phosphor.

• 한국전기전자재료학회논문지
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• 제37권3호
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• pp.274-279
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• 2024

Eu³⁺-doped BaZrO₃ (BaZrO₃:Eu³⁺) phosphor powders were prepared using a solid-state reaction by changing the molar concentration of Eu³⁺ within the range of 0.5 to 30 mol%. Irrespective of the molar concentration of Eu³⁺ ions, the crystal structures of all the phosphors were cubic. The excitation spectra of BaZrO₃:Eu³⁺ phosphors consisted of an intense broad band centered at 277 nm in the range of 230~320 nm. The emission spectra were composed of a dominant orange band at 595 nm arising from the ⁵D₀→⁷F₁ magnetic dipole transition of Eu³⁺ and two weak emission bands centered at 574 and 615 nm, respectively. As the concentration of Eu³⁺ increased from 0.5 to 10 mol%, the intensities of all the emission bands gradually increased, approached maxima at 10 mol% of Eu³⁺ ions, and then showed a decreasing tendency with further increase in the Eu³⁺ ions due to the concentration quenching. The critical distance between neighboring Eu³⁺ ions for concentration quenching was calculated to be 11.21 Å, indicating that dipole-dipole interaction was the main mechanism of concentration quenching of BaZrO₃:Eu³⁺ phosphors. The results suggest that the orange emission intensity can be modulated by doping the appropriate concentration of Eu³⁺ ions.

• 한국재료학회지
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• 제29권9호
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• pp.559-566
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• 2019

$Lu(Nb,Ta)O_4:Eu^{3+}$ powders are synthesized by a solid-state reaction process using LiCl and $Li_2SO_4$ fluxes. The photoluminescence (PL) excitation spectra of the synthesized powders consist of broad bands at approximately 270 nm and sharp peaks in the near ultraviolet region, which are assigned to the $Nb^{5+}-O^{2-}$ charge transfer of $[NbO_4]^{3-}$ niobates and the f-f transition of $Eu^{3+}$, respectively. The PL emission spectra exhibit red peaks assigned to the $^5D_0{\rightarrow}^7F_J$ transitions of $Eu^{3+}$. The strongest peak is obtained at 614 nm ($^5D_0{\rightarrow}^7F_2$), indicating that the $Eu^{3+}$ ions are incorporated into the $Lu^{3+}$ asymmetric sites. The addition of fluxes causes the increase in emission intensity, and $Li_2SO_4$ flux is more effective for enhancement in emission intensity than is LiCl flux. The substitution of $Ta^{5+}$ for $Nb^{5+}$ results in an increase or decrease in the emission intensity of $LuNb_{1-x}Ta_xO_4:Eu^{3+}$ powders, depending on amount and kind of flux. The findings are explained using particle morphology, modification of the $[NbO_4]^{3-}$ structure, formation of substructure of $LuTaO_4$, and change in the crystal field surrounding the $Eu^{3+}$ ions.

• Current Photovoltaic Research
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• 제3권3호
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• pp.71-74
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• 2015

Soluble polyaniline was synthesized by attaching titanium isoproxide ($Ti(OPr)_4$) to the amine group of the aniline. Approximately 1 to 1 molar ratio of aniline and $Ti(OPr)_4$ was mixed and polymerized with ammonium persulfate. The FTIR result showed clear difference between $TiO_2$-aniline composite ($TiO_2An$) and $TiO_2$-polyaniline composite ($TiO_2PAn$). Although the $TiO_2An$ had negligible UV-visible absorption, the $TiO_2PAn$ showed strong absorption in the UV-visible region. Photoluminescence (PL) peaks of $TiO_2An$ were shifted toward red with the reduction of the excitation energy, which could be due to the multiple emission centers. The luminescence peak shift stopped at 501 nm. The PL spectra of $TiO_2PAn$ exhibited three emission peaks at 2.88 eV (430 nm), 2.48 eV (501 nm) and 2.22 eV (558 nm). The new emission center (2.22 eV) was observed after polymerization. Field emission scanning electron microscope image showed crack-free composite film.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.411-412
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• 2007

EL (electro luminescent) is generally studied as a large size plane light emitting device and flexible light source because of it's simple manufacturing process. In this experiment, we manufactured flexible white emitting light source using Ni-foil with blue phosphor and color change materials. With increasing the thickness of color change material, the luminance of white emission is increased and the color coordinate of white color was shifted to pure white of (0.317,0.328) by strong emission of color change materials excited by blue excitation spectra. Also the luminance level was 30% higher in white emitting light device than blue only light source.