• Title/Summary/Keyword: Exchange times

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Separation and Purification for the Determination of Zirconium and Its Isotopes in PWR Spent Nuclear Fuels (PWR 사용후핵연료 중 Zr 및 Zr 동위원소 정량을 위한 분리 및 정제)

  • Kim, Jung Suk;Jeon, Young Shin;Park, Yong Joon;Lee, Chang Heon;Kim, Won Ho
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.421-428
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    • 1998
  • A method has been studied to separate Zr from various fission products in PWR spent nuclear fuels. A solution containing metal ions in place of radioactive fission products was prepared. The Zr was separated with 5 M HCl followed by eluting metal ions such as Ce, Nd, Cs, Rb, Ba, Sr, Ru, Rh, Pd, Ag and Cd with 12 M HCl on Dowex $1{\times}8$, anion exchange resin. The recovery of Zr was more than 95%. The purification of Zr was carried out on anion exchange resin, Dowex $1{\times}8$, in 5 M HCl in order to remove Mo causing isobaric effect during mass spectrometry. The method was applied to separate Zr from a spent PWR fuel. From mass spectrometric measurement, the purified Zr portion was not showed the isobars from other elements such as Mo and Sr.

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Comparative Study on 'Chim Ku' time Therapy and Energy Exchange rule of E.A.V. (침구시간치료(鍼灸時間治療)와 EAV에너지 교환법칙(交換法則)에 관(關)한 비교(比較).고찰(考察))

  • Kim, Jung-Heon;Ryu, Kyung-Joo
    • Korean Journal of Oriental Medicine
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    • v.1 no.1
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    • pp.209-244
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    • 1995
  • The time therapy in oriental medicine is to reserch physiological activity and pathological variation with time, or time with disease. In that, this therapy is to research the development of disease, progress, diagnosis, treatment, and the meaning of preventive medicine. The theory of time therapy has been developed form heaven-human corresponding principle, and fourtimes of seasons is related with human life. After that, this theory affects in yin-yang five circle principle and organ-meridian match system. The independent development was formed later, but the origin has progressed for a logn times. in relation with time therapy, traditional acupuncture therory suggested five semen. In twenty century, the doctor rheinhold voll suggested energy exchange theory, this theory is based on time therapy, but has partial differance also too. His oppinion is this´ the energy present in the body has a circulation following the acupuncture teaching, i.e., the organs and their meridians are flooded in a certain sequence by this flowing energy. This maximum times of the organs are of physiologic and pathologic significance to man. In next time, we will discuss the indivisual theory in detail, and wil have comparison, and considering too.

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Development of Nutrients and Heavy Metals Removal Technology in Saturated Zone Using Zeolite (포화 지층내 영양염류 및 중금속의 제거를 위한 제올라이트의 적용인자 도출)

  • 이승학;이재원;박준범;전연호;이채영
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.435-442
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    • 2000
  • Batch test and column test were performed to develop the design factors for permeable reactive barriers(PRBs) against ammonium and heavy metals, Clinoptilolite, a kind of natural zeolites having excellent cation exchange capacity(CEC), was choosen for the reacting materials through the ion-exchange mechanism. In the batch test, the reactivity of clinoptilolite for ammonium, lead, and copper was examined varying the initial concentration of contaminants(ammonium: 20, 40, 80 ppm, heavy metals: 10, 20, 40 ppm) and the particle size of clinoptilolites(0-0.15, 0.42-0.85, 1-1.25 mm). The reactivity is increasing as the initial concentration decrease and particle size decrease. In the column test, the permeability and the reactivity of the specimens were examined using flexible-wall permeameter. Specimens were made of clinoptilolite and Jumunjin-sand with 20 : 80 weight ratio varying particle size of clinoptilolite. The maximum permeability(1${\times}$10$\^$-4/-5${\times}$10$\^$-5/cm/s) was achieved in the specimen made of 0.42-0.85 mm clinoptilolite and sand.

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Performance Analysis of a Low-Depth Unit-Type Ground Heat Exchanger using Numerical Simulation (수치해석을 통한 저심도 유닛형 지중열교환기의 성능 검토)

  • Oh, JinHwan;Seo, JangHoo;Na, Yujin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.3
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    • pp.169-173
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    • 2015
  • Recently, ground source heat pump (GSHP) systems have attracted much attention, according to the enhanced social demand of renewable energy. GSHP systems can achieve higher coefficient of performance than the conventional air-source heat pump systems by utilizing stable underground temperature. However, the initial cost of GSHP system is higher than that of the conventional systems, especially, in the small-size buildings. Therefore, it is necessary to develop small-size ground heat exchanger with low cost and quick installation. In this study, a unit-type ground heat exchanger was developed and heat exchange rate was calculated by the numerical simulation. As a result, 27.45 W/m of heat exchange rate was acquired in the condition of $0.5m{\times}0.2m{\times}2m$ unit.

The content based standard data search technology under CALS integrated data environment (국방 CALS 통합 데이터 환경을 위한 내용 기반의 표준 데이터 검색 기술 개발)

  • Jeong, Seung-Uk;U, Hun-Sik
    • Journal of National Security and Military Science
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    • s.2
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    • pp.261-283
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    • 2004
  • To build up the military strength based on information oriented armed forces, the Korean ministry of national defense (MND) promotes the defense CALS (Continuous Acquisition and Life cycle Support) initiative for the reductions of acquisition times, improvements of system qualities, and reductions of costs. These defense CALS activities are the major component of the underlying mid and long term defense digitization program and the ultimate goal of program is to bring a quick victory by providing real-time battlefield intelligence and the economical operations of the military. The concept of defense CALS is to automate the acquisition and disposition of defense systems throughout their life cycle. For implementing defense CALS, the technology for exchange and sharing CALS standard data that is created once and used many times should be considered. In order to develop an efficient CALS information exchange and sharing system, it is required to integrate distributed and heterogeneous data sources and provide systematic search tools for those data. In this study, we developed a content based search engine technology which is essential for the construction of integrated data environments. The developed technology provides the environment of sharing the CALS standard data such as SGML(Standard Generalized Markup Language) and STEP(Standard for The Exchange of Product model data). Utilizing this technology, users can find and access distributed and heterogeneous data sources without knowing its actual location.

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Ion Exchange Separation and Spectrofluorometric Determination of Lanthanides in Nuclear Grade Material (이온 질환수지 및 형광분석법에 의한 핵급물질 중희토류원소의 분리정량)

  • Ki-Soo Cho;In-Suck Suh
    • Nuclear Engineering and Technology
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    • v.15 no.2
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    • pp.142-148
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    • 1983
  • Distribution coefficients between cation exchange resin (Dowex 50W$\times$8) and $\alpha$-hydroxyisobutric acid ($\alpha$-HIBA) are measured in order to separate traces of Sm, Eu, Gd and Dy from nuclear material. Individual separations are performed by pH gradient technique with 0.40M $\alpha$-HIBA from 3.40 to 3.60 in cation exchange resin after a group separation. Each of separated elements is determined with a fluorometric method except Gd by colorimetry. The results are applied to analyze Sm, Eu, Gd and Dy in magnesium diuranate (yellow cake).

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Preparation of NH4+-β"-alumina as a Protonic Solid Electrolyte by Ion Exchange Reaction (이온교환반응에 의한 양성자 고체 전해질 NH4+-β"-alumina의 제조)

  • Lee, Jun-Hee;Han, Choon-Soo;Lee, Sung-Tae;Lee, Ki-Moon;Lee, Dae-Han;Lim, Sung-Ki
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.255-260
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    • 2011
  • $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina which is expected to an inorganic solid electrolyte of high temperature polymer electrolyte membrane fuel cells (PEMFC) was prepared by ion-exchange reaction of $K^{+}-{\beta}^{{\prime}{\prime}}$-alumina pellet with $NH_4NO_3$ aqueous solution and molten $NH_4NO_3$ salts as an ion-exchange medium in the autoclave and the heating mentle reaction. In the autoclave reaction, the concentrations of $NH_4NO_3$ solution was chosen at 5 and 10 M. Each ion-exchange reaction was carried out at 130, 150, 170, and $200^{\circ}C$ for 2, 4, 6 and 8 h. In the heating mentle reaction, ion-exchange was performed at $200^{\circ}C$ for 2, 4, 6 and 8 h with molten $NH_4NO_3$ salts. In order to determine the effect of reaction times, each ion-exchange reaction was repeated 3 times. The phase stability and the ion-exchange rate of $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina were analyzed by XRD and ICP.

Effect of Proton Irradiation on the Magnetic Properties of Antiferromagnet/ferromagnet Structures

  • Kim, Dong-Jun;Park, Jin-Seok;Ryu, Ho Jin;Jeong, Jong-Ryul;Chung, Chang-Kyu;Park, Byong-Guk
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.159-163
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    • 2016
  • Antiferromagnet (AFM)/ferromagnet (FM) bilayer structures are widely used in the magnetic devices of sensor and memory applications, as AFM materials can induce unidirectional anisotropy of the FM material via exchange coupling. The strength of the exchange coupling is known to be sensitive to quality of the interface of the AFM/FM bilayers. In this study, we utilize proton irradiation to modify the interface structures and investigate its effect on the magnetic properties of AFM/FM structures, including the exchange bias and magnetic thermoelectric effect. The magnetic properties of IrMn/CoFeB structures with various IrMn thicknesses are characterized after they are exposed to a proton beam of 3 MeV and $1{\sim}5{\times}10^{14}ions/cm^2$. We observe that the magnetic moment is gradually reduced as the amount of the dose is increased. On the other hand, the exchange bias field and thermoelectric voltage are not significantly affected by proton irradiation. This indicates that proton irradiation has more of an influence on the bulk property of the FM CoFeB layer and less of an effect on the IrMn/CoFeB interface.

Effect of Silicotungstic Acid as Inorganic Filler on the Properties of Anion Exchange Composite Membranes (무기첨가제 규소텅스텐산이 음이온교환 복합막 특성에 미치는 영향)

  • LEE, KYU HA;YOO, DONG JIN
    • Journal of Hydrogen and New Energy
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    • v.33 no.1
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    • pp.28-37
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    • 2022
  • In this study, we synthesized a poly(pheneylene oxide) (PPO)-based organic/inorganic composite membrane having silicotungstic acid (STA) for the development of an anion exchange membrane with excellent ionic conductivity and physicochemical stability. The organic/inorganic composite membranes were prepared by introducing different STA contents (0 wt%, 10 wt%, 30 wt%, and 50 wt%) into the quaternizaed(Q)-PPO matrix. The prepared anion exchange membranes were subjected to structural analysis by proton neclear magnetic resonance and Fourier transform infrared, and thermal behavior of membranes was confirmed by thermogravimetric analysis. Among the prepared composite membranes, the ion conductivity of Q-PPO/STA-50 (40.5 mS cm-1) showed 1.46 times compared to that of the pristine membrane (27.6 mS cm-1). Therefore, these results demonstrated that organic/inorganic composite membranes are promising candidates for application of anion exchange membranes.

2-GOOD RINGS AND THEIR EXTENSIONS

  • Wang, Yao;Ren, Yanli
    • Bulletin of the Korean Mathematical Society
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    • v.50 no.5
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    • pp.1711-1723
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    • 2013
  • P. V$\acute{a}$mos called a ring R 2-good if every element is the sum of two units. The ring of all $n{\times}n$ matrices over an elementary divisor ring is 2-good. A (right) self-injective von Neumann regular ring is 2-good provided it has no 2-torsion. Some of the earlier results known to us about 2-good rings (although nobody so called at those times) were due to Ehrlich, Henriksen, Fisher, Snider, Rapharl and Badawi. We continue in this paper the study of 2-good rings by several authors. We give some examples of 2-good rings and their related properties. In particular, it is shown that if R is an exchange ring with Artinian primitive factors and 2 is a unit in R, then R is 2-good. We also investigate various kinds of extensions of 2-good rings, including the polynomial extension, Nagata extension and Dorroh extension.