• Title/Summary/Keyword: Exchange times

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Performance of Membrane Capacitive Deionization Process Using Polyvinylidene Fluoride Heterogeneous Ion Exchange Membranes Part I : Preparation and Characterization of Heterogeneous Ion Exchange Membranes (폴리비닐플루오라이드 불균질 이온교환막을 이용한 막 결합형 축전식탈염공정의 탈염 성능 Part I : 불균질 이온교환막의 제조 및 특성)

  • Park, Cheol Oh;Rhim, Ji Won
    • Membrane Journal
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    • v.27 no.1
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    • pp.84-91
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    • 2017
  • In this study, heterogeneous ion exchange membranes were prepared by mixing cation or anion exchange resins and commercial polyvinylidene fluoride (PVDF) for MCDI process. The mixing ratios of PVDF and ion exchange resins were 1 : 1, 1.4 : 1, 2 : 1, and 3 : 1. We characterized SEM, water content, ion exchange capacity, methanol permeability, and ion conductivity. In the viewpoint of membrane characterization, the blending ratio of 2 : 1 showed the best. For the blending ratio of 2 : 1, heterogeneous cation exchange membrane showed the water content 34%, ion exchange capacity 1.54 meq/g, ion conductivity 0.019 S/cm, and methanol permeability $2.28{\times}10^{-7}{\sim}8.86{\times}10^{-7}cm^2/s$ while In the case of heterogeneous anion exchange membrane, the result showed 37%, 2.18 meq/g, and 0.034 S/cm and $1.46{\times}10^{-7}{\sim}8.66{\times}10^{-7}cm^2/s$.

An influence of the exchange rate on NOE intensities of a ligand: Application to 37kDa trp-holo-repressor/operator DNA complex

  • Lee, Donghan;Lee, Weontae
    • Journal of the Korean Magnetic Resonance Society
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    • v.2 no.1
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    • pp.33-40
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    • 1998
  • The cross peak intensities versus mixing times of 2D NOESY spectrum for a corepressor L-trp were simulated for the case of a ligand exchanging between free (AX) and bound (A'X') forms in protein/DNA complex. The direct NOE (I(AX)) of the free ligand exhibited a small positive intensity indicative of the strong dominant influence of the bound ligand. The exchange-mediated NOE peak (I(AX')) was very sensitive to corepressor exchange. However, both diagonal (I(A'A')) and direct NOE (I(A'X')) intensities of the bound ligand were not affected much at initial stage. Both peaks were severely influenced by exchange at mixing times of greater than 100 ms. In conclusion, since the NOE intensity is a function of exchange rate, the exchange effect should be considered to properly extract accurate distance information for bound ligand in the presence of conformational exchange.

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Preparation of Cation Exchange Membrane using Polybenzimidazole and Its Characteristic (폴리벤지미다졸(PBI)을 이용한 양이온교환막의 제조 및 특성)

  • Kim, Joeng-Geun;Lee, Sang-Ho;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.22 no.4
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    • pp.265-271
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    • 2012
  • Polybenzimidazole (PBI) was prepared by condensation polymerization using diaminobenzidine (DAB) and isophtalic acid (IPAc). The cation exchange membrane was prepared by introduce the ion exchange group in the PBI polymer. It was confirmed from FT-IR analysis that the prepared PBI powder had same peak compared with commercial PBI power. The ionic conductivity of PBI film was $0.1{\sim}0.9{\times}10^{-2}$ S/cm. The ionic conductivity of prepared SPBI cation exchange membrane showed $3.7{\sim}4.7{\times}10^{-2}$ S/cm and had higher than Nafion117 ($2.0{\times}10^{-2}$ S/cm).

ON QB-IDEALS OF EXCHANGE RINGS

  • Chen, Huanyin
    • Bulletin of the Korean Mathematical Society
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    • v.46 no.5
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    • pp.873-884
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    • 2009
  • We characterize QB-ideals of exchange rings by means of quasi-invertible elements and annihilators. Further, we prove that every $2\times2$ matrix over such ideals of a regular ring admits a diagonal reduction by quasi-inverse matrices. Prime exchange QB-rings are studied as well.

The Social meaning and the Adaptable Effects on Marriage Life of the Honsu: A social Exchange View (혼수의 사회적 의미 및 혼수가 결혼생활에 미치는 영향 : 사회교환이론적 접근)

  • 정용선
    • Journal of the Korean Home Economics Association
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    • v.33 no.6
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    • pp.115-136
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    • 1995
  • The exploratory purpose of this study was to investigate the Honsu trend and to examine the relationships between the Honsu, marriage exchange resources and marital satisfaction from general group and also explore the differences in Honsu expenditure between the general group and the aimed group. the explanatory purpose of this study was to prove the social meaning of the Honsu as a 'productive exchange resources' using Emerson's exchange network theory. The data was collected from 800 men and women of general group and 72 men and women of aimed group within 5 years of marital duration through the questionnaire method. Major findings of the study from the general group were as follows : in general group 1. The bridegroom group expended more Honsu than bride group. Bridegroom's primary expenditure item was house expenditure, and bride's primary one was newlywed life goods. 2. The bridegroom's Honsu were influenced positively by parents'SES, bridegroom & bride's education level and bride's parents'SES. Bride's Honsu were influenced positively by parents' SES and bridegroom & bride's education level. 3. Bridegroom's marital satisfaction were influenced positively by bride's marriage need, bridegroom's marriage need, bride's physical attraction and bridegroom & bride's education level. Bride's marital satisfaction were influenced positively by bride's marriage need, bridegroom's physical attraction, bridegroom & bride's education level, bridegroom's marriage need, bridegroom's future possibilities and bridegroom's Honsu. 4. The social meaning of the Honsu was a 'productive exchange resource'. 1. The bridegrooms of aimed group expended more housing expenditure and also Honsu than the brides but there's no statistically significant differences in Honsu expenditure between the bridegrooms and the brides of aimed group. 2. The bridegrooms of aimed group expended about 3 times more money for wedding present for spouse and abut 1.2 times more for Honsu than the bridegrooms of general group. The bride of aimed group expended about 4.6 times more money for general group. the bride of aimed group expended abut 4.6 times more money about 4 times more for housing expenditure and about 3 times more for total Honsu than the brides of general group.

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Kinetics of the Bromine-Exchange Reaction of Gallium Bromide with n-Propyl Bromide in 1,2,4-Trichlorobenzene and in Nitrobenzene

  • Kwun, Oh-Cheun;Kim, Young-Cheul;Choi ,Sang-Up
    • Bulletin of the Korean Chemical Society
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    • v.2 no.3
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    • pp.86-89
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    • 1981
  • The rate of the bromine-exchange reaction between gallium bromide and n-propyl bromide in 1,2,4-trichlorobenzene and in nitrobenzene was measured at 19, 25 and $40^{\circ}C$, using n-propyl bromide labelled with Br-82. The results indicated that the exchange reaction was second order with respect to gallium bromide and first order with respect to n-propyl bromide. The third-order rate constant determined at $19^{\circ}C$ is $2.9{\times} 10^{-2}l^2{\cdot}mole^{-2}{\cdot}sec^{-1}$ in 1,2,4-trichlorobenzene and $4.5{\times}10^{-3}l^2{\cdot}mole^{-2}{\cdot}sec^{-1}$. in nitrobenzene. The activation energy, the enthalpy of activation and the entropy of activation for the exchange reaction were also determined. Reaction mechanism for the bromine exchange of n-propyl bromide seemed to be similar to those observed in earlier studies with other alkyl bromides.

Basic Study for Development of Denitrogenation Process by Ion Exchange(III) - A kinetic study in the batch reactor - (이온교환법에 의한 탈질소 공정개발의 기초연구(III) - 회분식 반응기에서의 반응속도론-)

  • 채용곤;이동환;김승일;윤태경;홍성수;이민규
    • Journal of Environmental Science International
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    • v.9 no.2
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    • pp.165-171
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    • 2000
  • A kinetic study for anion exchange was performed for commercially available Cl- type anion exchange resin in use to remove nitrate in water. The obtained results from the batch reactor were applied to the Langmuir and Freundlich models. The constants for Lagmuir model were qmax =29.82 and b=0.202, and for Freundlich model were K=5.509 and n=1.772. Langmuir model showed betterfit than Frendlich model for the experimental results. Ion exchange reaction rate was also calculated and the the approximate first-order reaction, rate constant k1 was 0.16 L/mg.hr. Effective diffusion coefficient was obtained in the range from $9.67$\times$10^{-8} cm^2/sec$ for initial concentration change, and from $6.09$\times$10^{-7} to 3.98$\times$10^{-6} cm^2/sec$ for reaction temperature change. Activation energy during the diffusion was calculated as 26 kcal/mol.

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Survey on the Regular Maintenance of Agricultural Machinery (농업기계 정기점검정비 실태조사)

  • Kang, J.W;Lee, W.Y.;Lee, S.B.;Lee, J.H.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.3 no.1
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    • pp.142-157
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    • 2001
  • This study was conducted to get the basic information for promoting farm machinery productivity by surveying the regular maintenance and repair status of major farm machinery such as power tiller, farm tractor, rice transplanter and combine harvester. The survey was carried out through 9 provinces including Cheju province by direct visiting farmers with prepared questionnaire. The results of this study can be summarized as follows : 1. The average farming carrier of the surveyed farmers was 25.3 years, and 21-30 years of farming carrier showed the highest portion as 40.7%. The average carrier of using farm machinery was 9.4 years, and that was 14.9 years for power tiller, 8.3 years for farm tractor, 9.0 years for rice transplanter, 7.9 years for combine harvester, 7.5 years for mini tiller, 9.7 years for power sprayer, and 8.2 years for binder etc. 2. The regular maintenance for farm machinery was conducted mainly at repair shop (49.5%) or dealer agency (12.0%) as 61.5%, and 34.9% of farmers conducted the regular maintenance by themselves at their house. 3. The reasons for not-fully recognizing operation manual and insufficient before-, during-, after-maintenance of farm machinery were insufficient time for them (45.8%), troublesome (22.9%), unknown maintenance method (16.3%), unknown the necessity for maintenance (12.4%), and others (2.6%) in order. 4. For the annual exchange of engine oil, 3.2 times is necessary but actually 1.7 times was exchanged for power tiller, 4.3 times is necessary but actually 1.9 times was exchanged for farm tractor, 2.7 times is necessary but actually 1.7 times was exchanged for rice transplanter, 2.2 times is necessary but actually 2.3 times was exchanged combine harvester. 5. For the annual cleanness or exchange of fuel filter, 3.2 times is necessary but actually 1.1 times was done for power tiller, 4.3 times is necessary but actually 1.6 times was done for farm tractor, 2.7 times is necessary but actually 1.7 times was done for rice transplanter, 1.9 times is necessary but actually 0.8 times was done for combine harvester. 6. For the annual cleanness or exchange of air filter, 3.2 times is necessary but actually 1.4 times was done for power tiller, 4.2 times is necessary but actually 2.4 times was done for farm tractor, 2.6 times is necessary but actually 1.6 times was done for rice transplanter, 3.9 times is necessary but actually 7.0 times was done for combine harvester. 7. For the experience of breakdown related to maintenance, 5.3% of farmers experienced breakdown due to the insufficient exchange of engine oil, 7.7% of farmers experienced breakdown due to the insufficient cleanness or exchange of fuel filter, and 2.9% of farmers experienced breakdown due to the insufficient cleanness or exchange of air filter. 8. Most farmers (76.1%) recognized the necessity for agricultural machinery training or education, and most farmers preferred about one week for the training period, simple or ease maintenance for the training level, agricultural technical center or agricultural machinery manufacturer for the training agency. 9. Complete recognition of operation manual and sufficient before-, during-, and after-maintenance for farm machinery can minimize the breakdown as well as conduct suitable period farming, enlarge the endurance, prevent the safety accidents, and promote productivity of farm machinery. Therefore, these can be accomplished by the thorough training or education for agricultural machinery.

Preparation and Characterization of ion Exchange Membrane for Direct Methanol Fuel Cell(DMFC) Using Sulfonated Polysulfone (설폰화 폴리설폰을 이용한 직접메탄올연료전지용 이온교환막의 제조 및 특성 연구)

  • 신현수;이충섭;전지현;정선영;임지원;남상용
    • Membrane Journal
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    • v.12 no.4
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    • pp.247-254
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    • 2002
  • In order to develop the ion exchange membranes which would be used in direct methanol fuel cell (DMFC), the polysulfone polymer was sulfonated using chlorosulfonic acid (CSA) and trimethylchlorosilane(TMCS). It has been characterized in terms of ion conductivities, methanol crossover, swelling degree and ion exchange capacities for the heat untreated and treated membranes at $150^{\circ}C.$ Typically, the methanol permeability and ion conductivity at the mole ratio of 1.4 between polysulfone repeating unit and sulfonating agents showed $2.87{\times}10^{-7}\; cm^2/s$(without heat treatment), $1.52{\times}10^{-7}\; cm^2/s$(with heat treatment) and $1.10{\times}10^{-2}\; S/cm$(without heat treatment), $0.87{\times}10^{-2}\;$ S/cm(with heat treatment), respectively. After the mole ration of 1.4 both values indicated mild increase.

Mass Culture of Ultra-small Rotifer, Synchaeta kitina at the Exchange Rate of Culture Water and Initial Inoculation Density (환수율 및 접종밀도에 따른 초소형 rotifer, Synchaeta kitina의 대량배양)

  • Oh, Jeong-Soo;Park, Jin-Chul;Park, Heum-Gi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.42 no.4
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    • pp.354-359
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    • 2009
  • The productivity of ultra-small rotifer, Synchaeta kitina was investigated at the exchange rate of culture water (10, 20, 30, 40 and 50%) and initial inoculation densities (250, 600 and 900 inds. per mL) in semi-continuous culture. Also, the possibility of mass culture was investigated in a 100 L culture tank. Tetraselmis suecica was used as the feed for S. kitina in all experiments. The production of S. kitina increased with an increase in exchange rate of culture water. The highest production ($82.0{\times}10^5$ inds.) was achieved at 40% exchange rate of culture water. The production of S. kitina increased with an increase of initial inoculation density during the first week and the highest total production ($17.4{\times}10^6$ inds.) was achieved at 900 inds. per mL of initial inoculation density. However, on the second week, all treatments were not significantly different in total production (P>0.05). During the two weeks, total production of S. kitina at 900 inds. per mL of initial inoculation density was higher than at 600 inds. of initial inoculation density, but there was no significant difference (P>0.05). In the 100 L culture tank, density of S. kitina was kept from 516 to 890 inds. per mL and S. kitina was daily harvested $15.5{\times}10^6$ to $26.7{\times}10^6$ during the experimental period. The production cost for 100 million rotifers in semi-continuous culture was 63,656 won. The results from this study indicate that the optimal exchange rate of culture water and initial inoculation density for the semi-continuous culture of ultra-small rotifer, S. kitina are 40% and 600 inds. per mL, respectively.