• Title/Summary/Keyword: Exchange Rate Stability

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Catalytic Biofilms on Structured Packing for the Production of Glycolic Acid

  • Li, Xuan Zhong;Hauer, Bernhard;Rosche, Bettina
    • Journal of Microbiology and Biotechnology
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    • v.23 no.2
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    • pp.195-204
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    • 2013
  • While structured packing modules are known to be efficient for surface wetting and gas-liquid exchange in abiotic surface catalysis, this model study explores structured packing as a growth surface for catalytic biofilms. Microbial biofilms have been proposed as selfimmobilized and self-regenerating catalysts for the production of chemicals. A concern is that the complex and dynamic nature of biofilms may cause fluctuations in their catalytic performance over time or may affect process reproducibility. An aerated continuous trickle-bed biofilm reactor system was designed with a 3 L structured packing, liquid recycling and pH control. Pseudomonas diminuta established a biofilm on the stainless steel structured packing with a specific surface area of 500 $m^2m^{-3}$ and catalyzed the oxidation of ethylene glycol to glycolic acid for over two months of continuous operation. A steady-state productivity of up to 1.6 $gl^{-1}h^{-1}$ was achieved at a dilution rate of 0.33 $h^{-1}$. Process reproducibility between three independent runs was excellent, despite process interruptions and activity variations in cultures grown from biofilm effluent cells. The results demonstrate the robustness of a catalytic biofilm on structured packing, despite its dynamic nature. Implementation is recommended for whole-cell processes that require efficient gas-liquid exchange, catalyst retention for continuous operation, or improved catalyst stability.

An Empirical Study on the Effect of Inflation Targeting on PPP: Evidence From 19 OECD countries (물가안정목표제가 구매력평가에 미친 영향: 19개의 OECD 국가들을 대상으로)

  • Eun-Son Lim
    • Korea Trade Review
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    • v.47 no.5
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    • pp.75-93
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    • 2022
  • Purchasing Power Parity (hereafter, PPP) means the purchasing power of two currencies is the same when one is converted into the other one. According to previous studies on PPP, as the volatility of the real exchange rate is smaller, PPP may be more likely to hold. Since New Zealand adopted the inflation targeting policy in December 1989, many countries started to adopt it as their monetary policy frame. Previous studies on inflation targeting found that inflation targeting policy has positive effects on not only achieving price stability but also reducing the volatility of nominal/ real exchange rates. Therefore, in this study, I explored whether inflation targeting policy has positive effects on purchasing power parity subject to 19 OECD countries, applying an Exponential Smooth Transition Autoregressive (ESTAR) model during the sample periods, from 1974:Q1 to 2019:Q4. Based on the ESTAR estimate results, I found limited favorable evidence of PPP for only two countries- England and Switzerland- among 9 inflation targeters, compared to non-inflation targeters, and also I found that favorable evidence of PPP only for these two countries among 9 inflation targeters during post-inflation targeting, but not during pre-inflation targeting. These findings imply that the positive effects of inflation targeting on PPP may be questionable unlike Ding and Kim (2012) and Kim (2014)'s study.

Development of New Omeprazole-lon Exchange Resin Complex (이온교환수지를 이용한 새로운 오메프라졸 복합체 개발)

  • Rhee, Gye-Ju;Lee, Ki-Myung;Kim, Eun-Young;Lee, Chang-Hyun;Hwang, Sung-Joo
    • YAKHAK HOEJI
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    • v.38 no.3
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    • pp.250-264
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    • 1994
  • Omeprazole(OMZ)-cholestyramine(CHL) and various OMZ-Dowex resin complexes were prepared by reaction between OMZ and activated resins in 0.1N NaOH solution. And their physical properties were tested by means of infrared(IR), differential scaning caloimeter(DSC), X-ray diffraction. Chemical stability of OMZ-CHL was increased markedly compared with OMZ and the decomposition of OMZ-CHL followed the pseudo first-order kinetics and the rate constants were $2.743{\times}10^{-4}/day$ at $20^{\circ}C$, $7.83{\times}10^{-3}day^{-1}$ under 80% RH and $1.68{\times}10^{-2}day^{-1}$ under UV radiation, respectively. On the other hand, the rate constants of OMZ were $2.996{\times}10^{-4}day^{-1}$ at $20^{\circ}C$, $1.17{\times}10^{-2}day^{-1}$ under 85% RH, and $4.07{\times}10^{-2}day^{-1}$ under UV radiation, respectively. The rates of dissolution of OMZ-CHL bulk and OMZ-CHL tablet were 100% and more than 85% in 15 minutes, respectively, which were increased than OMZ base and OMZ-tablet. In the acute toxicological test, the value of oral $LD_{50}$(mouse) was 4.608 g/kg. OMZ-CHL was pelletized using lactose, polyethyle neglycol(PEG), D-sorbitol, Avicel PH 101, sodium laurylsulfate and polyvinylpyrrolidone(PVP) K-30, and enteric coated with HPMCP, Myvacet, acetone, ethanol and cetanol, of which dissolution rate was found to be more than 85% in 10 minutes. From the above results, it was found that OMZ-CHL is a useful means for development of new oral dosage forms of OMZ.

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Investigation into the Thermal Stability of Fluoropolymer Coating for Heat-Resistant Application (내열성 불소수지 코팅막의 열 안정성에 관한 연구)

  • Cho, Hey-Jin;Ryu, Ju-Hwan;Byun, Doo-Jin;Choi, Kil-Yeong
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.96-101
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    • 2005
  • Fluoropolymer of PTFE and PFA etc. is a heat resistance polymeric material that it is known as that maximum continuous use temperature reaches for 260 $^{\circ}C$. It was observed that these polymers had the enough thermal stability so enough that it was kept by thermal aging of 280 $^{\circ}C$/7 weeks too in this study. However, such thermal stability means that bulk material property is kept such as mechanical strength, melting point and initial pyrolysis temperature etc. If these polymers are evaluate by coating property such as surface contact angle, surface morphology, surface scratch, thing that heat resistance is not enough was confirmed in this study. Thermal aging of flouropolymer coating was achieved by gear aging oven that the exchange rate of air was controlled, and the analysis results were indicating serious damage of surface morphology and adhesive strength on metal substrate.

Hybrid Cryptosystem Design with Authentication (인증기능을 가진 혼합형 암호시스템 설계)

  • 이선근;김영일;고영욱;송재호;김환용
    • Proceedings of the IEEK Conference
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    • 2002.06b
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    • pp.341-344
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    • 2002
  • The importance of protection for information is increasing by the rapid development of information communication and network. Asymmetric crypto-system is the mainstream in encryption system rather than symmetric cryptosystem by above reasons. But asymmetric cryptosystem is restricted in applying to application fields by the reason it takes more times to process than symmetric cryptosystem. In this paper, the proposed cryptosystem uses an algorithm that combines block cipherment with stream ciphcrment. Proposed cryptosystem has a high stability in aspect of secret rate by means of transition of key sequence according to the information of plaintext while asymmetric /symmetric cryptosystern conducts encipherment/decipherment using a fixed key Consequently, it is very difficult to crack although unauthenticator acquires the key information. So, the proposed encryption system which has a certification function of asymmetric cryptosystcm and a processing time equivalent to symmetric cryptosystcm will be highly useful to authorize data or exchange important information.

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Optimization of Wave Forms for Pulsed Amperometric Detection of Cyanide and Sulfide with Silver-Working Electrode

  • Park, Seong U;Hong, Seong Uk;Yu, Jae Hun
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.143-146
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    • 1996
  • A continuous potential pulse is applied to a silver-working electrode on a pulsed amperometric detector (PAD) for detection of free cyanide and sulfide. The moving phase is 0.1 M sodium hydroxide, 0.5 M sodium acetate and 5% (v/v) ethylenediamine mixture, and the flow rate is 0.7 mL/min. Optimized pulse conditions include a -200 mV (vs. Ag/AgCl reference electrode) detection potential(Ed) for 60 msec and 50 mV cleaning potential (Ec) for 120 msec. The silver working electrode surface is not poisoned by cyanide or sulfide, and the PAD maintains long-term stability without loss of sensitivity and reproducibility at these pulse conditions. The detection limit of cyanide and sulfide separated by ion chromatography using an anion exchange column is 0.1 ppm and 0.05 ppm, respectively.

Performance Evaluation of Free breathing Fuel Cell by using Synthetic Jet Air Blower (Synthetic Jet Air Blower를 이용한 Free Breathing 연료전지의 성능 평가)

  • Choi, Jong-Pil;Ku, Bo-Sung;Jang, Jae-Hyuk;Seo, Young-Ho;Kim, Byeong-Hee
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2834-2838
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    • 2008
  • An free breathing proton exchange membrane fuel cell (PEMFC) was developed. This paper presents a study of the several effect on the performance of a fuel cell such as air flow rate, opening ratio, and cathode structures. Especially, an air flow rate is critical condition to improve the fuel cell performance. In this paper, we developed a synthetic jet micro air blower to supply high stoichiometric air. The synthetic jet actuation is usually generated by a traditional PZT-driven actuator, which consists of a small cylindrical cavity, orifices and PZT diaphragms. In comparison with free convection fuel cells, the forced-convection fuel cell which equipped synthetic jet micro air blower brings higher performance and stability for long term test. Also, power consumption of the synthetic jet micro air blower is under 0.3W. The results show that the maximum power density was $188mW/cm^2$ at $400mA/cm^2$. The maximum power density was higher 40% than power density of free convection fuel cell.

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Factors of Successful Policy Implementation in National Projects for Technology Innovation (과학기술혁신을 위한 National Project의 성공적 정책집행의 요인)

  • Cho, Gug-Hyeon
    • Journal of Technology Innovation
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    • v.12 no.3
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    • pp.73-96
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    • 2004
  • This research began by recognizing the development of telecommunication skill in a short period of time as one achievement of launching the national research and development (R&D) project for the diversification of telephone service and for the solution of telephone holdup rate. Under this concern, this research is focusing on searching the influential elements on successful outcome by analyzing the case of Time Division Exchange R&D Project carried out by Korea. Those variables for analyzing the case is limited to 7 definite variables, which are "willingness of policy making organization", "participation of manufacturers and buyers", "support from research and development group", "economy of operating methods and selection of machinery", "rate of technology transfer", "support from Fixer", and "quality management". Summarizing the result of analysis, in order to bring about technological innovation, knowledge creation activity leading to upward efficiency through competition and cooperation making a harmony should be done in one mechanism. I.e., launching an innovative policy should be done in an arena of competition and cooperation, where stability of implementing system is achieved, the entity of "Fixer" is an adequate operator, and competition and cooperation is efficiently managed, among where agreement on purpose and professional opinions are reflected.

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Studies on the Characteristics of Mineral Diluents Affecting the Decomposition of Sumithion in the Dust formulations (Sumithion 분제의 성분 변화에 영향을 미치는 증량제의 특성에 관한 연구)

  • Wuh K. D.;Han S. S.;Keum S. S.;Ahn S. H.;Lee C. N.
    • Korean journal of applied entomology
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    • v.10 no.2
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    • pp.77-83
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    • 1971
  • In order to find out the decomposing factors of Sumithion in mineral diluents, the physical and chemical properties of the diluents such as talcs, bentonites, diatomaceous earth and other clay minerals was studied in relation to the decomposition rate of Sumithion in dust formulations. The total base, moisture adsorption capacity, pH, specific surface, water contents, active $Fe^{++}$, ignition loss and cation exchange capacity were analysed as the properties of mineral diluents, and these properties were correlated with the stability of Sumithion in dust formulations. And in hope of finding out the main factors among those properties of diluents, the decomposed products of Sumithion in dust formulations prepared with standard Sumithion were separated by the methods of column chromatography and investigated by thin layer chromatography. The following results were otbained; 1. The total base, moisture adsorption capacity, specific surface, water contents, active $Fe^{++}$ and cation exchange capacity of mineral diluents were found to be highly effective on the rate of decomposition of Sumithion in dust formulations. 2. Decomposed products of Sumithion in dust formulations were found to be dimethylphosphorothionate, 3-methyl-4-nitro phenol and its derivatives. And one fraction was not dissolved in n-hexane and ethylether, but was soluble in methylalcohol and ethylalcohol. 3. The moat highly correlated properties of diluents with the decomposition rate of Sumithion in dust were found to be the total base and water contents. 4. In regard to the kind of diluents, it was found that the rate of decomposition of Sumithion in dust formulations was higher in order of bentonite, diatomaceous earth, kaolin and talc.

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Dynamics Transition of Electroconvective Instability Depending on Confinement Effect (공간 제약 효과에 따른 전기와류 불안정성의 동역학 전이)

  • Lee, Seungha;Hyun, Cheol Heon;Lee, Hyomin
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.626-631
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    • 2021
  • One of the nonlinear electrokinetic phenomena around ion exchange membrane is electroconvective instability which can be found in various electrokinetic applications such as electrodialysis, electrochemical battery, microfluidic analysis platform, etc. Such instability acts as a positive transport mechanism for the electrodialysis via amplifying mass transport rate. On the other hands, in the electrochemical battery and the microfluidic applications, the instability provokes unwanted mass transport. In this research, to control the electroconvective instability, the onset of the instability was analyzed as a function of confinement effect as well as applied voltage. As a result, we figured out that the dynamic behavior of electroconvective instability transited as a sequence of stable regime - static regime - chaotic regime depending on the applied voltage and confinement effect. Furthermore, stability curves about the dynamic transition were numerically determined as well. Conclusively, the confinement effect on electroconvective instability can be applied for effective means to control the electrokinetic chaos.