• Title/Summary/Keyword: Excess properties

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A Goodness-of-Fit Test for the Additive Risk Model with a Binary Covariate

  • Kim, Jin-Heum;Song, Moon-Sup
    • Journal of the Korean Statistical Society
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    • v.24 no.2
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    • pp.537-549
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    • 1995
  • In this article, we propose a class of weighted estimators for the excess risk in additive risk model with a binary covariate. The proposed estimator is consistent and asymptotically normal. When the assumed model is inappropriate, however, the estimators with different weights converge to nonidentical constants. This fact enables us to develop a goodness-of-fit test for the excess assumption by comparing estimators with diffrent weights. It is shown that the proposed test converges in distribution to normal with mean zero and is consistent under the model misspecifications. Furthermore, the finite-sample properties of the proposed test procedure are investigated and two examples using real data are presented.

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Microwave Dielectric Characterization of Binary Mixtures of 3-Nitrotoluene with Dimethylacetamide, Dimethylformamide and Dimethylsulphoxide

  • Chaudhari, Ajay;Chaudhari, H.C.;Mehrotra, S.C.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1403-1407
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    • 2004
  • Dielectric relaxation measurements on 3-nitrotoluene (3-NT) mixture of dimethylacetamide (DMA), dimethylformamide (DMF) and dimethysulphoxide (DMSO) have been carried out across the entire concentration range using Time domain reflectometry technique at 15, 25, 35 and $45^{\circ}C$ over the frequency range from 10 MHz to 20 GHz. For all the mixtures, only one dielectric loss peak was observed in this frequency range and the relaxation in these mixtures can be well described by a single relaxation time using Debye model. Bilinear calibration method is used to obtain complex permittivity ${\varepsilon}^{*}({\omega})$ from complex reflection coefficient ${\rho}^{*}({\omega})$ over frequency range 10 MHz to 20 GHz. The excess permittivity, excess inverse relaxation time, Kirkwood correlation factor, molar energy of activation are also calculated for these mixtures to study the solute-solvent interaction.

Can Brand Equity Explain Excess Behavioral Loyalty?

  • Jung, Sang Uk
    • Asia Marketing Journal
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    • v.17 no.1
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    • pp.55-67
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    • 2015
  • Despite the well-known predictive power of Dirichlet model on customer loyalty, deviations of share of category requirement (SCR) predicted by Dirichlet model from actual SCR have been repeatedly reported. It has been shown that these deviations can be systematically explained by some factors such as brand's market share, product positioning strategy, purchase volume and retail marketing mix strategies. Presuming that brand equity would be additional sources of these deviations, current study assesses the incremental predictive power of brand equity by using over 4,000 brand-level observations for the consumer packaged goods industry in the U.S. Our model estimations indicate that brands that exhibit higher brand equity enjoy excess loyalty, with the primary driver being volume premium, rather than price premium. Overall, our findings support the notion that idiosyncratic brand properties can explain excess behavioral loyalty, a notion that is in stark contrast with the Dirichlet view of the world: brand equity does not exist.

Numerical analysis of vertical drains accelerated consolidation considering combined soil disturbance and visco-plastic behaviour

  • Azari, Babak;Fatahi, Behzad;Khabbaz, Hadi
    • Geomechanics and Engineering
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    • v.8 no.2
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    • pp.187-220
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    • 2015
  • Soil disturbance induced by installation of mandrel driven vertical drains decreases the in situ horizontal hydraulic conductivity of the soil in the vicinity of the drains, decelerating the consolidation rate. According to available literature, several different profiles for the hydraulic conductivity variation with the radial distance from the vertical drain, influencing the excess pore water pressure dissipation rate, have been identified. In addition, it is well known that the visco-plastic properties of the soil also influence the excess pore water pressure dissipation rate and consequently the settlement rate. In this study, a numerical solution adopting an elastic visco-plastic model with nonlinear creep function incorporated in the consolidation equations has been developed to investigate the effects of disturbed zone properties on the time dependent behaviour of soft soil deposits improved with vertical drains and preloading. The employed elastic visco-plastic model is based on the framework of the modified Cam-Clay model capturing soil creep during excess pore water pressure dissipation. Besides, nonlinear variations of creep coefficient with stress and time and permeability variations during the consolidation process are considered. The predicted results have been compared with V$\ddot{a}$sby test fill measurements. According to the results, different variations of the hydraulic conductivity profile in the disturbed zone result in varying excess pore water pressure dissipation rate and consequently varying the effective vertical stresses in the soil profile. Thus, the creep coefficient and the creep strain limit are notably influenced resulting in significant changes in the predicted settlement rate.

A Study on the Electrical and Optical Properties of CdS Thin Films Deposited with Different Conditions for Solar Cell Applications (태양전지용 CdS 박막의 제조 조건에 따른 전기적 광학적 특성에 관한 연구)

  • Lee, Jae-Hyeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.7
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    • pp.620-628
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    • 2008
  • Cadmium sulphide (CdS) thin film, which is used as a window layer of heterojunction solar cell, on the glass substrate was deposited by vacuum evaporation. Effects of deposition conditions such as the source and substrate temperature on electrical and optical properties of CdS films was investigated. As the source temperature was increased, the deposition rate of CdS films was increased. In addition, the optical transmittance and the electrical resistivity of CdS films were decreased as the source temperature was increased. This results were attributed to the increase of excess Cd amount in the film. The crystal structure of CdS films exhibited the hexagonal phase with preferential orientation of the (002) plane. As the substrate temperature was increased, the crystal structure of CdS films was improved and the resistivity of the films was increased due to the decrease of excess Cd in film.

Nd2Fe14B Synthesis: Effect of Excess Neodymium on Phase Purity and Magnetic Property

  • Jadhav, Abhijit P.;Ma, Haoxuan;Kim, Dong Soo;Baek, Youn Kyung;Choi, Chul Jin;Kang, Young Soo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.886-890
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    • 2014
  • The properties of magnetic material of Nd-Fe-B are highly affected by various factors such as particle size, magnetic anisotropy, phase purity and crystal structure. Incorporation of excess neodymium was carried out in various percentages so that it will adjust the proportion of neodymium in the host crystal after reduction treatment and finally help to improve magnetic property of a material. The interdiffusion of Nd-Fe and boron was studied for various compositions and their effect on magnetic property was understood with theoretical concepts. The factors such as amount of hard and soft phase in the reduction treated product is also responsible for the possible exchange coupling between hard and soft phase magnets for better magnetic properties.

Effect of Excess PbO Addition on Sintering and Piezoelectric Characteristics in Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3 System (PbO 과잉량이 Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3계의 소결 및 압전특성에 미치는 영향)

  • 전구락;김정주;조상희;김도연
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.568-574
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    • 1989
  • Effect of PbO addition on sintering and piezoelectric properties at 0.45Pb(Ni1/3Nb2/3)O3-0.40PbTiO3-0.15PbZrO3 composition which is tetragonal phase was investigated. In this composition, Porosity and dielectric constant were increased with excess PbO addition, but Kp and d31 was not changed. These variation of physical properties could be interpreted as composition change of solid grains from tetragonal to MPB region due to amount of PbO-rich liquid changing.

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A Study on The Glass-Ceramics Containing Fluorine (불소 함유 결정화유리에 관한 연구)

  • 박용완;현부성;김창렬
    • Journal of the Korean Ceramic Society
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    • v.29 no.10
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    • pp.815-821
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    • 1992
  • The batches having excess SiO2 to tetrasilicic mica KMg2.5 (Si4O10)F2 were melted at 1450℃. The fabricated samples were heat-treated for the nucleation and the crystallization. The crystallized samples were investigated on several properties. The tetrasilicic mica composition with excess 10 wt% SiO2 was successful both in glassifying and in crystallizing. The optimum temperatures for the nucleation and the crystallization were 680℃ and 1000-1100℃, respectively. The mica and the cristobalite crystallines were identified after heat-treatment. The properties of the samples processed appropriately were as follows, bulk density 2.64g/㎤, thermal expansion coefficient ∼80×10-7/℃, Vicker's hardness ∼105 Kgf/㎟, bending strength ∼666Kgf/㎟, dielectric constant ∼11.1, tan δ 2.5%, volume resistivity 2.35×107∼1.3×1011{{{{ OMEGA }}cm, surface roughness 6.984㎛.

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A study on the Etching and electrical Properties of PZT Thin Films (PZT(53/47) 박막의 식각 및 전기적 특성에 관한 연구)

  • 김경태;이성갑;이영희;김창일
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.39-42
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    • 2000
  • The effect of excess Pb contents on the etching of PZT thin films and their electrical properties has been investigated. Ferroelectric PZT(53/47) thin films were prepared by the metal alkoxide-based Sol-Gel method, in which they were spin-coating on P7Ti/Si02/Si substrate using the PZT(53/47) stock solutions with various excess Pb contents. Etching of PZT film was performed using planar inductively coupled Ar/Cl$_2$/BCl$_3$ plasma. The etch rate of PZT film was 2450 $\AA$/min at Ar(20)/BCl$_3$(80) gas mixing ratio and substrate temperature of 8$0^{\circ}C$.

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Luminescence of InBO3:Tb Phosphor (InBO3:Tb 형광체의 발광 특성)

  • Lee Je-Hyuk;Lee Tae-Hee;Suh Kwang-S.;Ryu Sun-Yoon;Byun Jae-Dong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.8
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    • pp.744-748
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    • 2006
  • Emission characteristics of terbium-activated $InBO_3$ under cathode-ray(c.r.) and vacuum ultra violet(v.u.v.) irradiation have been investigated as a functions of norminal compositions and firing conditions. From the x-ray analysis, it was found that some of the synthesized samples contained excess $In_2O_3$ and the amount of the excess $In_2O_3$ varied with the norminal composition and heat treatment conditions. The samples with remanent excess $In_2O_3$ showed lower luminescence intensities than the ones free of excess $In_2O_3$. The phosphors of norminal composition of $InBO_3+10mol%B_2O_3:2mol%Tb$ synthesized at $1250^{\circ}C$ showed excellent CL and PL properties.