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Improvement of anti-corrosive property for alloy plated steel sheet by UV curable organic-inorganic hybrid coatings (합금도금강판 내식성 향상을 위한 UV 경화형 유무기 하이브리드 코팅)

  • Park, Jongwon;Lee, Kyunghwang;Na, Hyunju;Park, Byungkyu;Nam, Yeungsub;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.27-33
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    • 2013
  • According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

Fabrication of High Porous Ceramic with Mullite Whisker from Fly Ash (석탄재를 이용한 뮬라이트 휘스커 고다공성 세라믹 제작)

  • Shin, Cheol;Hwang, Kwang-Taek;Kim, Ung-Soo;Han, Kyu-Sung;Choi, Jung-Hoon;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.32 no.5
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    • pp.258-263
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    • 2022
  • Porous ceramics have the advantages of low density, low thermal conductivity, and excellent mechanical properties. Among porous ceramic manufacturing methods, the replica template method allows the easy manufacturing of porous filters with the highest porosity and pores of the desired size, but it also has the disadvantage that the resulting filters have low mechanical strength. To overcome this shortcoming, mullite (3Al2O3·2SiO2) whiskers, which have excellent thermal stability and high mechanical strength, were introduced in porous ceramic structure. The mullite whiskers were synthesized using a composition of Al2O3, flyash and MoO3. The morphologies and crystal structures of the mullite whiskers with MoO3 contents were investigated in detail. When the porous ceramic with mullite whiskers was fabricated using 20 wt% MoO3 catalyst the most uniform microstructure was obtained, and the mullite whiskers showed the highest aspect ratio of 47.03. The porosity and compressive strength of the fabricated porous ceramic were 82.12 % and 0.83 MPa, respectively.

Evaluation of the Vacuum brazed stainless steel by Ni-based filler metals (Ni기 삽입금속에 의해 진공 브레이징된 stainless steel의 특성평가)

  • Chang, Se-Hun;Hong, Ji-Min;Jeong, Chang-Yeol;Choi, Se-Weon;Oh, Ik-Hyun
    • Korean Journal of Materials Research
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    • v.17 no.6
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    • pp.342-346
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    • 2007
  • Microstructure and tensile strength of the vacuum brazed stainless steel were investigated in this study. For vacuum brazing of the stainless steel 303 and 304, the BNi-2, 3, 4 and 7 were used as filler metals. Among these filler metals, the BNi-2 showed excellent wettability at $1050^{\circ}C$. Indeed, the brazed stainless steel using the BNi-2 showed the highest tensile strength (483 MPa) among all brazed specimens. This is attributed to degree of interfacial reaction between the filler metal and stainless steel. Brazed stainless steel with BNi-2, 3 filler metals showed almost elastic deformation followed by plastic yielding and strain hardening up to a peak stress. On the other hand, it is likely that the fracture of the brazed specimens with BNi-4, 7 was occurred in elastic range without plastic yielding up to a peak stress.

Fully Rod-like Aromatic Polyimides: Structure, Properties, and Chemical Modifications

  • Moonhor Ree;Shin, Tae-Joo;Lee, Seung-Woo
    • Macromolecular Research
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    • v.9 no.1
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    • pp.1-19
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    • 2001
  • Poly(p-phenylene pyromellitimide) and poly(4,4'-biphenylene pyromellitimide) are representatives of fully rod-like polyimides. Their structure and properties in thin films are reviewed. The polymers exhibit some excellent properties such as high molecular packing coefficient, high mechanical modulus, and low thermal expansion coefficient, and low interfacial stress, so that they are very attractive to both industry and academia. However, these polymers are very brittle and thus practically useless. Some chemical modifications to improve such drawback with a little sacrifice of the high modulus are described: i) incorporation of short side groups into the polymer backbone and ii) insertion of proper linkages into the polymer backbone.

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Activation of Ontact Research Using Science & Technology Knowledge Infrastructure ScienceON

  • Han, Sangjun;Shin, Jaemin;Lee, Seokhyoung;Park, Junghun
    • Journal of Information Science Theory and Practice
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    • v.10 no.spc
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    • pp.1-11
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    • 2022
  • As data-based research activities and outcomes increase and ontact or non-face-to-face activities become common, the demand for easy utilization of resources, tools, functions, and easily accessible information required for research in the R&D sector has increased accordingly. With the rapid increase in the demand for collaborative research based on online platforms, research support institutions strive to provide venues for research activities that merge various information and functions. ScienceON, an integrated science & technology (S&T) knowledge infrastructure service developed and operated by the Korea Institute of S&T Information (KISTI), supports open collaboration by connecting and merging all the information, functions, and infrastructure required for research activities. This paper describes the online research activity support tool provided by ScienceON and the remarkable results achieved through this activity. Specifically, the excellent creation of the following flow of meta-material research activities in the ontact space is elucidated. First, the papers required for a meta-material analysis are retrieved, virtual simulation is conducted with the experimental data extracted from the papers, and research data are accumulated. ScienceON's tools for supporting ontact research activity will play a role as an important service in the era of digital transformation and open science.

Electrical and Optical Characteristics of ZnO:Al Films Prepared by rf Magnetron Sputtering for Thin Film Solar Cells Application (rf 마그네트론 스파터법에 의해 제조된 태양전지용 ZnO:Al 박막의 전기 광학적 특성)

  • Jeon, Sang-Won;Lee, Jeong-Chul;Park, Byung-Ok;Song, Jin-Soo;Yoon, Kyung-Hoon
    • Korean Journal of Materials Research
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    • v.16 no.1
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    • pp.19-24
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    • 2006
  • ZnO:Al(AZO) films prepared by rf magnetron sputtering on glass substrate and textured by post-deposition chemical etching were applied as front contact and back reflectors for ${\mu}c$-Si:H thin film solar cells. For the front transparent electrode contact, AZO films were prepared at various working pressures and substrate temperature and then were chemically etched in diluted HCl(1%). The front AZO films deposited at low working pressure(1 mTorr) and low temperature ($240^{\circ}C$) exhibited uniform and high transmittance ($\geq$80%) and excellent electrical properties. The solar cells were optimized in terms of optical and electrical properties to demonstrate a high short-circuit current.

A High Voltage NMOSFET Fabricated by using a Standard CMOS Logic Process as a Pixel-driving Transistor for the OLED on the Silicon Substrate

  • Lee, Cheon-An;Jin, Sung-Hun;Kwon, Hyuck-In;Cho, Il-Whan;Kong, Ji-Hye;Lee, Chang-Ju;Lee, Myung-Won;Kyung, Jae-Woo;Lee, Jong-Duk;Park, Byung-Gook
    • Journal of Information Display
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    • v.5 no.1
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    • pp.28-33
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    • 2004
  • A high voltage NMOSFET is proposed to drive top emission organic light emitting device (OLED) used in the organic electroluminescent (EL) display on the single crystal silicon substrate. The high voltage NMOSFET can be fabricated by utilizing a simple layout technique with a standard CMOS logic process. It is clearly shown that the maximum supply voltage ($V_{DD}$) required for the pixel-driving transistor could reach 45 V through analytic and experimental methods. The high voltage NMOSFET was fabricated by using a standard 1.5 ${\mu}m$, 5 V CMOS logic process. From the measurements, we confirmed that the high voltage NMOSFET could sustain the excellent saturation characteristic up to 50 V without breakdown phenomena.

Effective Amidation of Carboxylic Acids Using (4,5-Dichloro-6-oxo-6H-pyridazin-1-yl)phosphoric Acid Diethyl Ester

  • Kang, Seung-Beom;Yim, Heung-Seop;Won, Ju-Eun;Kim, Min-Jung;Kim, Jeum-Jong;Kim, Ho-Kyun;Lee, Sang-Gyeong;Yoon, Yong-Jin
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.1025-1032
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    • 2008
  • (4,5-Dichloro-6-oxo-6H-pyridazin-1-yl)phosphoric acid diethyl ester (3a) are efficient and selective coupling agents for the amidation of carboxylic acids. Amidation of aliphatic and aromatic carboxylic acids with aliphatic and aromatic amines using 3a under mild condition gave chemoselectively the corresponding amides in good to excellent yield. Three protected-dipeptides were also synthesized from N-BOC-Phe and O-Me-amino acid hydrochlorides using 3a under mild condition.

Wind Resource Assessment of Antarctic King Sejong Station (남극 세종기지의 풍력자원 분석)

  • Bae, Jae-Sung;Jang, Moon-Seok;Ju, Young-Chul;Yoon, Jeong-Eun;Kyong, Nam-Ho
    • Journal of the Korean Solar Energy Society
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    • v.25 no.3
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    • pp.53-60
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    • 2005
  • Energy resource is very important to the survival in the polar region. Wind energy, which is one of renewable energy, can guarantee the clean, inexhaustible, natural resource in the polar region. It is essential to assess the wind energy resource of the site where wind turbines will be installed. In the present study, the wind characteristics of the antarctic King Sejong station are analysed from its meteorological observation data. The wind resource of the Sejong station is also simulated and predicted using WAsP program. From the results, the Sejong station has very excellent wind resource and the site where small wind turbines will be installed is determined.

Pervaporation separation of polyion complex composite membranes for the separation of water/alcohol mixtures: characterization of permeation behavior by using molecular modeling techniques

  • Kim, Sang-Gyun;Lee, Yoon-Gyu;Jonggeon Jegal;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.91-94
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    • 2003
  • In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

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